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Ionics

, Volume 25, Issue 9, pp 4523–4530 | Cite as

Surface nano-ZnO doped LiNi1/3Co1/3Mn1/3O2 for an improved elevated temperature performance by a facile low-temperature solid-state process

  • Qianqian JiangEmail author
  • Nannan Yuan
  • Yichi Zhang
  • Jianguo TangEmail author
Short Communication
  • 22 Downloads

Abstract

Surface modified with nano-ZnO LNCM power has been successfully prepared using facile low-temperature solid-state route. The experimental results show that the reaction temperature has a great influence on the structure of coating layer. ZnO@LNCM-400 shows the best electrochemical performance, which has lesser capacity loss than the others. It shows superior performance with higher capacity (216.6 mAh g−1) and significantly improved cycling stability (maintaining 97.28% of its initial discharge capacity after 100 cycles). Moreover, it has excellent rate performance especially at elevated performance, which is probably due to the faster Li+ transportation by the nano-ZnO layer. The ZnO-coated LNCM electrode showed less capacity loss about 15.8%, even at 55 °C after 100 cycles. We found that ZnO played an important role in reducing the HF content in the electrolyte solution and improving the electrical conductivity of the material, which is beneficial to the electrochemical performance of material.

Keywords

Nano-ZnO LNCM Elevated temperature performance Rates performance Li-ion batteries 

Notes

Acknowledgments

The work is supported by the National Natural Science Foundation of China (Grant No.: 51473082, 51273096 and 51603109), the programme of Introducing Talents to the Universities (111 plan) and the National One-Thousand Foreign Expert Program (No. WQ20123400111), the Natural Science Foundation of Shandong province (No. ZR2017BEM047), and the postdoctoral science foundation of China (No. 2017M610408).

Supplementary material

11581_2019_3188_MOESM1_ESM.doc (392 kb)
ESM 1 (DOC 392 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Institute of Hybrid Materials, National Center of International Research for Hybrid Materials Technology, National Base of International Science & Technology Cooperation, College of Materials Science and EngineeringQingdao UniversityQingdaoPeople’s Republic of China
  2. 2.School of Chemical and Biomedical EngineeringNanyang Technological UniversitySingaporeSingapore

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