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Ionics

, Volume 25, Issue 11, pp 5305–5313 | Cite as

Electrospun 3D CNF–SiO2 fabricated using non-biodegradable silica gel as prospective anode for lithium–ion batteries

  • Anbu Dinesh Jayabalan
  • Mir Mehraj Ud Din
  • M. S. Indu
  • K. Karthik
  • Veena Ragupathi
  • Ganapathi Subramaniam Nagarajan
  • Puspamitra Panigrahi
  • Ramaswamy MuruganEmail author
Original Paper
  • 206 Downloads

Abstract

An eco-friendly simple, cost-effective, and recyclable strategy was approached to fabricate high-capacity anode for lithium–ion batteries (LIBs). A non-biodegradable solid waste obtained from the used silica gel pack was pulverised and used directly as a source of silicon dioxide nanoparticles. The SiO2-incorporated carbon nanofiber (CNF–SiO2) composite was prepared via the electrospinning technique. LIB constructed with CNF–SiO2 nanocomposite electrode delivered enhanced initial discharge capacity of 900 mA h g−1 and a remarkable discharge capacity of 1000 mA h g−1 after 300 cycles of charge and discharge at a cycling rate of 0.1 C (current density ≈ 0.19 A g−1). The CNF–SiO2 electrode exhibited reduced charge transfer resistance and a higher rate capability at various cycling rates with highest reversible discharge capacity of nearly 975 mA h g−1 at 0.2 C. The excellent rate capability of CNF–SiO2 composite electrode obtained from non-indicative desiccant followed by electrospinning with improved charge discharge capacity demonstrates its potential application in LIBs.

Graphical abstract

Electrospun CNF-SiO2 nanocomposite anode fabrication and its electrochemical performance.

Keywords

Silica gel pack SiO2 nanoparticles CNF–SiO2 electrode High discharge capacity High-performance Li–ion battery 

Notes

Acknowledgments

RM acknowledges support from the SERB, Govt. of India (EMR/2017/000417). MMU Din thanks UGC-MANF Govt. of India for the fellowship support.

Author contributions

RM and PP proposed the research work. ADJ carried out the experimental work, materials characterization, data analysis and manuscript preparation. MMU Din, IMS and KK assisted in carrying out the experimental work. VR and GSN supported the research work. Major work was carried out in the High Energy Density Batteries Research Laboratory, Pondicherry University under the supervision of RM.

Compliance with ethical standards

Conflict of interest

The authors declare no competing financial interest.

Supplementary material

11581_2019_3066_MOESM1_ESM.doc (3.8 mb)
ESM 1 (DOC 3918 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Anbu Dinesh Jayabalan
    • 1
  • Mir Mehraj Ud Din
    • 2
  • M. S. Indu
    • 2
  • K. Karthik
    • 2
  • Veena Ragupathi
    • 1
  • Ganapathi Subramaniam Nagarajan
    • 1
  • Puspamitra Panigrahi
    • 1
  • Ramaswamy Murugan
    • 2
    Email author
  1. 1.Centre for Clean Energy and Nano Convergence (CENCON)Hindustan Institute of Technology and Science (Deemed to be University)ChennaiIndia
  2. 2.High Energy Density Batteries Research Laboratory, Department of PhysicsPondicherry UniversityPuducherryIndia

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