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Ionics

, Volume 25, Issue 2, pp 523–531 | Cite as

Carbon nanotubes enhanced Sb6O13 as a new anode material for sodium-ion batteries

  • Biao Shang
  • Qimeng Peng
  • Xun Jiao
  • Guocui Xi
  • Xuebu HuEmail author
Original Paper
  • 27 Downloads

Abstract

Sb6O13/carbon nanotube (Sb6O13/CNT) composite prepared via a facile method has been evaluated as anode material for sodium-ion batteries. Its physical properties were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). Its electrochemical characteristics were studied via cyclic voltammetry (CV), electrochemical impedance spectra (EIS), and galvanostatic charge/discharge. Compared with Sb6O13, Sb6O13/CNTs showed an obviously enhanced electrochemical performance with an initial discharge capacity of 1048.7 mA h g−1, a reversible capacity of 308.7 mA h g−1 at 100 mA g−1 after 350 cycles. Even at 1000 mA g−1, a capacity of 158 mA h g−1 was obtained for Sb6O13/CNTs compared to 47 mA h g−1 of Sb6O13, which showed a good rate performance of Sb6O13/CNTs. In addition, the calculated sodium-ion diffusion coefficients of Sb6O13/CNTs reached 6.70 × 10−14 cm2 s−1, which was almost 47 times as much as that of Sb6O13.

Keywords

Sb6O13 Carbon nanotubes Anode Sodium-ion batteries 

Notes

Funding information

This work was supported by key project of science and technology research program of Chongqing Education Commission of China (No.KJZD-K201801103).

References

  1. 1.
    Su H, Jaffer S, Yu H (2016) Transition metal oxides for sodium-ion batteries. Energy Storage Mater 5:116–131CrossRefGoogle Scholar
  2. 2.
    Li Y, Lu Y, Zhao C, Hu YS, Titirici MM, Li H, Huang X, Chen L (2017) Recent advances of electrode materials for low-cost sodium-ion batteries towards practical application for grid energy storage. Energy Storage Mater 7:130–151CrossRefGoogle Scholar
  3. 3.
    Luo W, Shen F, Bommier C, Zhu H, Ji X, Hu L (2016) Na-ion battery anodes: materials and electrochemistry. Acc Chem Res 49:231–240CrossRefGoogle Scholar
  4. 4.
    Wang GZ, Feng JM, Dong L, Li XF, Li DJ (2017) Antimony (IV) oxide nanorods/reduced graphene oxide as the anode material of sodium-ion batteries with excellent electrochemical performance. Electrochim Acta 240:203–214CrossRefGoogle Scholar
  5. 5.
    Wang GZ, Feng JM, Dong L, Li XF, Li DJ (2017) Porous graphene anchored with Sb/SbOx as sodium-ion battery anode with enhanced reversible capacity and cycle performance. J Alloys Compd 693:141–149CrossRefGoogle Scholar
  6. 6.
    Wan F, Lü HY, Zhang XH, Liu DH, Zhang JP, He X, Wu XL (2016) The in-situ -prepared micro/nanocomposite composed of Sb and reduced graphene oxide as superior anode for sodium-ion batteries. J Alloys Compd 672:72–78CrossRefGoogle Scholar
  7. 7.
    Zhou X, Zhang Z, Xu X, Yan J, Ma G, Lei Z (2016) Anchoring Sb6O13 nanocrystals on graphene sheets for enhanced lithium storage. ACS Appl Mater Interfaces 8:35398–35406CrossRefGoogle Scholar
  8. 8.
    Hu C, Li Z, Wang Y, Gao J, Dai K, Zheng G, Liu C, Shen C, Song H, Guo Z (2017) Comparative assessment of the strain-sensing behaviors of polylactic acid nanocomposites: reduced graphene oxide or carbon nanotubes. J Mater Chem C 5:2318–2328CrossRefGoogle Scholar
  9. 9.
    Guan X, Zheng G, Dai K, Liu C, Yan X, Shen C, Guo Z (2016) Carbon nanotubes-adsorbed electrospun PA66 nanofiber bundles with improved conductivity and robust flexibility. ACS Appl Mater Interfaces 8:14150–14159CrossRefGoogle Scholar
  10. 10.
    Liu H, Huang W, Yang X, Dai K, Zheng G, Liu C, Shen C, Yan X, Guo J, Guo Z (2016) Organic vapor sensing behaviors of conductive thermoplastic polyurethane–graphene nanocomposites. J Mater Chem C 4:4459–4469CrossRefGoogle Scholar
  11. 11.
    Liu H, Li Y, Dai K, Zheng G, Liu C, Shen C, Yan X, Guo J, Guo Z (2016) Electrically conductive thermoplastic elastomer nanocomposites at ultralow graphene loading levels for strain sensor applications. J Mater Chem C 4:157–166CrossRefGoogle Scholar
  12. 12.
    Liu T, Yu K, Gao L, Chen H, Wang N, Hao L, Li T, He H, Guo Z (2017) A graphene quantum dot decorated SrRuO3 mesoporous film as an efficient counter electrode for high-performance dye-sensitized solar cells. J Mater Chem A 5:17848–17855CrossRefGoogle Scholar
  13. 13.
    Du H, Zhao CX, Lin J, Guo J, Wang B, Hu Z, Shao Q, Pan D, Wujcik EK, Guo Z (2018) Carbon nanomaterials in direct liquid fuel cells. Chem Rec 18:1365–1372CrossRefGoogle Scholar
  14. 14.
    Lin C, Hu L, Cheng C, Sun K, Guo X, Shao Q, Li J, Wang N, Guo Z (2018) Nano-TiNb2O7/carbon nanotubes composite anode for enhanced lithium-ion storage. Electrochim Acta 260:65–72CrossRefGoogle Scholar
  15. 15.
    Lee SW, Yabuuchi N, Gallant BM, Chen S, Kim BS, Hammond PT, Shao Horn Y (2010) High-power lithium batteries from functionalized carbon-nanotube electrodes. Nat Nanotechnol 5:531–537CrossRefGoogle Scholar
  16. 16.
    Wang Y, Wu M, Jiao Z, Lee JY (2009) Sn@CNT and Sn@C@CNT nanostructures for superior reversible lithium ion storage. Chem Mater 21:3210–3215CrossRefGoogle Scholar
  17. 17.
    Wang W, Kumta PN (2010) Nanostructured hybrid silicon/carbon nanotube heterostructures: reversible high-capacity lithium-ion anodes. ACS Nano 4:2233–2241CrossRefGoogle Scholar
  18. 18.
    Li WJ, Chou SL, Wang JZ, Liu HK, Dou SX (2013) Simply mixed commercial red phosphorus and carbon nanotube composite with exceptionally reversible sodium-ion storage. Nano Lett 13:5480–5484CrossRefGoogle Scholar
  19. 19.
    Bhuvaneswari R, Karthikeyan S, Selvasekarapandian S, Vinoth Pandi D, Vijaya N, Araichimani A, Sanjeeviraja C (2015) Preparation and characterization of PVA complexed with amino acid, proline. Ionics 21:387–399CrossRefGoogle Scholar
  20. 20.
    Li W, Wang KL, Cheng SJ, Jiang K (2017) Two-dimensional hybrid of SbOx nanoplates encapsulated by carbon flakes as a high performance sodium storage anode. J Mater Chem A 5:1160–1167CrossRefGoogle Scholar
  21. 21.
    Li N, Liao S, Sun Y, Song HW, Wang CX (2015) Uniformly dispersed self-assembled growth of Sb2O3/Sb@graphene nanocomposites on a 3D carbon sheet network for high Na-storage capacity and excellent stability. J Mater Chem A 3:5820–5828CrossRefGoogle Scholar
  22. 22.
    Zhou X, Liu X, Xu Y, Liu Y, Dai Z, Bao J (2014) An SbOx/reduced graphene oxide composite as a high-rate anode material for sodium-ion batteries. J Phys Chem C 118:23527–23534CrossRefGoogle Scholar
  23. 23.
    Yang Y, Yang X, Zhang Y, Hou H, Jing M, Zhu Y, Fang L, Chen Q, Ji X (2015) Cathodically induced antimony for rechargeable Li-ion and Na-ion batteries: the influences of hexagonal and amorphous phase. J Power Sources 282:358–367CrossRefGoogle Scholar
  24. 24.
    Yi Y, Shim HW, Seo SD, Dar MA, Kim DW (2016) Enhanced Li- and Na-storage in Sb-graphene nanocomposite anodes. Mater Res Bull 76:338–343CrossRefGoogle Scholar
  25. 25.
    Liu Q, Yan Y, Chu X, Zhang Y, Xue L, Zhang W (2017) Graphene-induced growth of single crystalline Sb2MoO6 sheets and their sodium storage performance. J Mater Chem A 5:21328–21333CrossRefGoogle Scholar
  26. 26.
    Hameed AS, Reddy MV, Chen JLT, Chowdari BVR, Vittal JJ (2016) RGO/stibnite nanocomposite as a dual anode for lithium and sodium ion batteries. ACS Sustain Chem Eng 4:2479–2486CrossRefGoogle Scholar
  27. 27.
    Nithya C, Gopukumar S (2014) rGO/nano Sb composite: a high performance anode material for Na+ ion batteries and evidence for the formation of nanoribbons from the nano rGO sheet during galvanostatic cycling. J Mater Chem A 2:10516–10525CrossRefGoogle Scholar
  28. 28.
    Sun Q, Ren QQ, Li H, Fu ZW (2011) High capacity Sb2O4 thin film electrodes for rechargeable sodium battery. Electrochem Commun 13:1462–1464CrossRefGoogle Scholar
  29. 29.
    Xiong D, Li X, Shan H, Yan B, Li D, Langford C, Sun X (2016) Scalable synthesis of functionalized graphene as cathodes in Li-ion electrochemical energy storage devices. Appl Energ 175:512–521CrossRefGoogle Scholar
  30. 30.
    Fan L, Li X, Cui Y, Xu H, Zhang X, Xiong D, Yan B, Wang Y, Li D (2015) Tin oxide/graphene aerogel nanocomposites building superior rate capability for lithium ion batteries. Electrochim Acta 176:610–619CrossRefGoogle Scholar
  31. 31.
    Fan L, Li X, Yan B, Feng J, Xiong D, Li D, Gu L, Wen Y, Lawes S, Sun X (2016) Controlled SnO2 crystallinity effectively dominating sodium storage performance. Adv Energy Mater 6:1502057CrossRefGoogle Scholar
  32. 32.
    Augustyn V, Come J, Lowe MA, Kim JW, Taberna PL, Tolbert SH, Abruna HD, Simon P, Dunn B (2013) High-rate electrochemical energy storage through Li+ intercalation pseudocapacitance. Nat Mater 12:518–522CrossRefGoogle Scholar
  33. 33.
    Chao D, Liang P, Chen Z, Bai L, Shen H, Liu X, Xia X, Zhao Y, Savilov SV, Lin J, Shen ZX (2016) Pseudocapacitive Na-ion storage boosts high rate and areal capacity of self-branched 2D layered metal chalcogenide nanoarrays. ACS Nano 10:10211–10219CrossRefGoogle Scholar
  34. 34.
    Brezesinski T, Wang J, Tolbert SH, Dunn B (2010) Ordered mesoporous alpha-MoO3 with iso-oriented nanocrystalline walls for thin-film pseudocapacitors. Nat Mater 9:146–151CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Biao Shang
    • 1
  • Qimeng Peng
    • 1
  • Xun Jiao
    • 1
  • Guocui Xi
    • 1
  • Xuebu Hu
    • 1
    Email author
  1. 1.College of Chemistry and Chemical EngineeringChongqing University of TechnologyChongqingChina

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