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Ionics

, Volume 25, Issue 2, pp 457–466 | Cite as

Effects of annealing temperature on the electrochemical characteristics of ZnO microrods as anode materials of lithium-ion battery using chemical bath deposition

  • Yoyok Dwi Setyo Pambudi
  • Rudy SetiabudyEmail author
  • Akhmad Herman Yuwono
  • Evvy Kartini
  • Joong Kee Lee
  • Chairul HudayaEmail author
Original Paper
  • 90 Downloads

Abstract

This study reports a facile synthesis of ZnO microrods using chemical bath deposition (CBD) for anode materials of lithium-ion batteries (LIB). During the synthesis, we controlled the uniformity, the density, and the diameter growth of ZnO microrods in order to find the optimum conditions. In particular, the effects of annealing temperature on the ZnO microrod morphology, structure, and electrochemical performances were further investigated. The size, alignment, and uniformity of the ZnO microrods were evaluated by scanning electron microscopy (SEM), while structural analysis was performed by X-ray diffraction (XRD) technique. The results showed that the annealing temperatures significantly influenced the ZnO microrod growth. We found the excellent experimental parameters were achieved at annealing temperature of 150 °C (ZnO_150) within 10 min and three seed layers, providing an average diameter of ~ 233.6 nm, crystallite size of 46.01 nm, and the density of 5.05 rods/μm2. Among the other samples, the ZnO_150 microrods delivered the highest initial discharge capacity of 811 mAhg−1 with relatively stable capacity retention of ~ 82% after 80 cycles and excellent rate capability performance.

Keywords

Annealing temperature Chemical bath deposition ZnO microrods Anode materials Lithium-ion batteries 

Notes

Acknowledgments

The authors thank Mr. Achmad Subhan (LIPI) and Dr. Wahyu Bambang Widayatno (LIPI) for providing technical assistance and fruitful discussion.

Funding

This work was partially supported by the USAID through Sustainable Higher Education Research Alliances (SHERA) Project for Universitas Indonesia’s SMART CITY Center for Collaborative Research, partially funded by INSINAS grant No. 04/INS-2/PPK/E/E4/2017, INSINAS grant No. IRPK-148-2018, and the 2018 KIST School Partnership Project.

References

  1. 1.
    Wang P, Gao M, Pan H, Zhang J, Liang C, Wang J, Zhou P, Liu Y (2013) A facile synthesis of Fe3O4/C composite with high cycle stability as anode material for lithium-ion batteries. J Power Sources 239:466–474CrossRefGoogle Scholar
  2. 2.
    Poizot P, Laruelle S, Grugeon S, Dupont L, Tarascon J (2000) Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries. Nature 407(6803):496–499CrossRefGoogle Scholar
  3. 3.
    Xiaowei S, Yang Y (2016) ZnO nanostructures and their applications. CRC PressGoogle Scholar
  4. 4.
    Kołodziejczak-Radzimska A, Jesionowski T (2014) Zinc oxide—from synthesis to application: a review. Materials 7(4):2833–2881CrossRefGoogle Scholar
  5. 5.
    Fu Z-W, Huang F, Zhang Y, Chu Y, Qin Q-Z (2003) The electrochemical reaction of zinc oxide thin films with lithium. J Electrochem Soc 150(6):A714–A720CrossRefGoogle Scholar
  6. 6.
    Zhang C, Tu J, Yuan Y, Huang X, Chen X, Mao F (2007) Electrochemical performances of Ni-coated ZnO as an anode material for lithium-ion batteries. J Electrochem Soc 154(2):A65–A69CrossRefGoogle Scholar
  7. 7.
    Liu J, Li Y, Ding R, Jiang J, Hu Y, Ji X, Chi Q, Zhu Z, Huang X (2009) Carbon/ZnO nanorod array electrode with significantly improved lithium storage capability. J Phys Chem C 113(13):5336–5339CrossRefGoogle Scholar
  8. 8.
    YAN G-F, FANG H-S, LI G-S, LI L-P, ZHAO H-J, YANG Y (2009) Improved electrochemical performance of Mg-doped ZnO thin film as anode material for lithium ion batteries ①. 结构化学 (JIEGOU HUAXUE) 28 (4)Google Scholar
  9. 9.
    Belliard F, Irvine J (2001) Electrochemical performance of ball-milled ZnO–SnO2 systems as anodes in lithium-ion battery. J Power Sources 97:219–222CrossRefGoogle Scholar
  10. 10.
    Huang X, Xia X, Yuan Y, Zhou F (2011) Porous ZnO nanosheets grown on copper substrates as anodes for lithium ion batteries. Electrochim Acta 56(14):4960–4965CrossRefGoogle Scholar
  11. 11.
    Park KT, Xia F, Kim SW, Kim SB, Song T, Paik U, Park WI (2013) Facile synthesis of ultrathin ZnO nanotubes with well-organized hexagonal nanowalls and sealed layouts: applications for lithium ion battery anodes. J Phys Chem C 117(2):1037–1043CrossRefGoogle Scholar
  12. 12.
    Li F, Yang L, Xu G, Xiaoqiang H, Yang X, Wei X, Ren Z, Shen G, Han G (2013) Hydrothermal self-assembly of hierarchical flower-like ZnO nanospheres with nanosheets and their application in Li-ion batteries. J Alloys Compd 577:663–668CrossRefGoogle Scholar
  13. 13.
    Zhang W, Du L, Chen Z, Hong J, Yue L (2016) ZnO nanocrystals as anode electrodes for lithium-ion batteries. J Nanomater 2016:1–7Google Scholar
  14. 14.
    Zhang G, Hou S, Zhang H, Zeng W, Yan F, Li Cheng C, Duan H (2015) High-performance and ultra-stable lithium-ion batteries based on MOF-derived ZnO@ZnO quantum dots/C core–shell nanorod arrays on a carbon cloth anode. Adv Mater 27(14):2400–2405.  https://doi.org/10.1002/adma.201405222 CrossRefGoogle Scholar
  15. 15.
    Zhang G, Song Y, Zhang H, Xu J, Duan H, Liu J (2016) Radially aligned porous carbon nanotube arrays on carbon fibers: a hierarchical 3D carbon nanostructure for high-performance capacitive energy storage. Adv Funct Mater 26(18):3012–3020CrossRefGoogle Scholar
  16. 16.
    Tang Z, Zhang G, Zhang H, Wang L, Shi H, Wei D, Duan H (2018) MOF-derived N-doped carbon bubbles on carbon tube arrays for flexible high-rate supercapacitors. Energy Storage Materials 10:75–84CrossRefGoogle Scholar
  17. 17.
    Zou Y, Qi Z, Jiang W, Duan J, Ma Z (2017) MWCNTs enhanced ZnO nanoparticles as anode for lithium ion batteries. Mater Lett 199:57–60CrossRefGoogle Scholar
  18. 18.
    Huang X, Guo R, Wu J, Zhang P (2014) Mesoporous ZnO nanosheets for lithium ion batteries. Mater Lett 122:82–85CrossRefGoogle Scholar
  19. 19.
    Cao B, Lorenz M, Rahm A, Von Wenckstern H, Czekalla C, Lenzner J, Benndorf G, Grundmann M (2007) Phosphorus acceptor doped ZnO nanowires prepared by pulsed-laser deposition. Nanotechnology 18(45):455707CrossRefGoogle Scholar
  20. 20.
    Agarwal D, Chauhan R, Avasthi D, Sulania I, Kabiraj D, Thakur P, Chae K, Chawla A, Chandra R, Ogale S (2009) VLS-like growth and characterizations of dense ZnO nanorods grown by e-beam process. J Phys D Appl Phys 42(3):035310CrossRefGoogle Scholar
  21. 21.
    Liu X, Wu X, Cao H, Chang R (2004) Growth mechanism and properties of ZnO nanorods synthesized by plasma-enhanced chemical vapor deposition. J Appl Phys 95(6):3141–3147CrossRefGoogle Scholar
  22. 22.
    Zhao Y, Li C, Chen M, Yu X, Chang Y, Chen A, Zhu H, Tang Z (2016) Growth of aligned ZnO nanowires via modified atmospheric pressure chemical vapor deposition. Phys Lett A 380(47):3993–3997CrossRefGoogle Scholar
  23. 23.
    Kumar Y, Rana AK, Bhojane P, Pusty M, Bagwe V, Sen S, Shirage PM (2015) Controlling of ZnO nanostructures by solute concentration and its effect on growth, structural and optical properties. Materials Research Express 2(10):105017CrossRefGoogle Scholar
  24. 24.
    Liu B, Zeng HC (2003) Hydrothermal synthesis of ZnO nanorods in the diameter regime of 50 nm. J Am Chem Soc 125(15):4430–4431CrossRefGoogle Scholar
  25. 25.
    Yang J, Zheng J, Zhai H, Yang X, Yang L, Liu Y, Lang J, Gao M (2010) Oriented growth of ZnO nanostructures on different substrates via a hydrothermal method. J Alloys Compd 489(1):51–55CrossRefGoogle Scholar
  26. 26.
    Yin Y, Que W, Kam C (2010) ZnO nanorods on ZnO seed layer derived by sol–gel process. J Sol-Gel Sci Technol 53(3):605–612CrossRefGoogle Scholar
  27. 27.
    Poornajar M, Marashi P, Fatmehsari DH, Esfahani MK (2016) Synthesis of ZnO nanorods via chemical bath deposition method: the effects of physicochemical factors. Ceram Int 42 ((1):173–184CrossRefGoogle Scholar
  28. 28.
    Cao B, Cai W (2008) From ZnO nanorods to nanoplates: chemical bath deposition growth and surface-related emissions. J Phys Chem C 112(3):680–685CrossRefGoogle Scholar
  29. 29.
    Sholehah A, Yuwono AH (2015) The effects of annealing temperature and seed layer on the growth of ZnO Nanorods in a chemical bath deposition process. International Journal of Technology 6(4):565–572CrossRefGoogle Scholar
  30. 30.
    Monshi A, Foroughi MR, Monshi MR (2012) Modified Scherrer equation to estimate more accurately nano-crystallite size using XRD. World Journal of Nano Science and Engineering 2(03):154–160CrossRefGoogle Scholar
  31. 31.
    Wahid KA, Lee WY, Lee HW, Teh AS, Bien DC, Azid IA (2013) Effect of seed annealing temperature and growth duration on hydrothermal ZnO nanorod structures and their electrical characteristics. Appl Surf Sci 283:629–635CrossRefGoogle Scholar
  32. 32.
    Vayssieres L (2003) Growth of arrayed nanorods and nanowires of ZnO from aqueous solutions. Adv Mater 15(5):464–466CrossRefGoogle Scholar
  33. 33.
    Thein MT, Pung S-Y, Aziz A, Itoh M (2015) Stacked ZnO nanorods synthesized by solution precipitation method and their photocatalytic activity study. J Sol-Gel Sci Technol 74(1):260–271CrossRefGoogle Scholar
  34. 34.
    Babapour A, Yang B, Bahang S, Cao W (2011) Low-temperature sol-gel-derived nanosilver-embedded silane coating as biofilm inhibitor. Nanotechnology 22(15):155602CrossRefGoogle Scholar
  35. 35.
    Samsuri S, Rahman M, Umar A, Salleh M (2017) Influence of ZnO growth temperature on the performance of dye-sensitized solar cell utilizing TiO 2-ZnO composite film photoanode. Ionics 23(12):3533–3544CrossRefGoogle Scholar
  36. 36.
    Park GC, Hwang SM, Lee SM, Choi JH, Song KM, Kim HY, Kim H-S, Eum S-J, Jung S-B, Lim JH (2015) Hydrothermally grown In-doped ZnO nanorods on p-GaN films for color-tunable heterojunction light-emitting-diodes. Sci Rep 5Google Scholar
  37. 37.
    Lupan O, Pauporté T, Chow L, Viana B, Pellé F, Ono L, Cuenya BR, Heinrich H (2010) Effects of annealing on properties of ZnO thin films prepared by electrochemical deposition in chloride medium. Appl Surf Sci 256(6):1895–1907CrossRefGoogle Scholar
  38. 38.
    Shang C, Barnabé A (2013) Structural study and phase transition investigation in a simple synthesis of porous architected-ZnO nanopowder. Mater Charact 86:206–211CrossRefGoogle Scholar
  39. 39.
    Vyas RN, Wang B (2010) Electrochemical analysis of conducting polymer thin films. Int J Mol Sci 11(4):1956–1972CrossRefGoogle Scholar
  40. 40.
    Zhou G, Wang D-W, Li F, Zhang L, Li N, Wu Z-S, Wen L, Lu GQ, Cheng H-M (2010) Graphene-wrapped Fe3O4 anode material with improved reversible capacity and cyclic stability for lithium ion batteries. Chem Mater 22(18):5306–5313CrossRefGoogle Scholar
  41. 41.
    Wang H, Pan Q, Cheng Y, Zhao J, Yin G (2009) Evaluation of ZnO nanorod arrays with dandelion-like morphology as negative electrodes for lithium-ion batteries. Electrochim Acta 54(10):2851–2855CrossRefGoogle Scholar
  42. 42.
    Hudaya C, Kang B, Jung H-G, Choi W, Jeon BJ, Lee JK (2015) Plasma-polymerized C60 as a functionalized coating layer on fluorine-doped tin oxides for anode materials of lithium-ion batteries. Carbon 81:835–838CrossRefGoogle Scholar
  43. 43.
    He B-L, Dong B, Li H-L (2007) Preparation and electrochemical properties of Ag-modified TiO2 nanotube anode material for lithium–ion battery. Electrochem Commun 9(3):425–430CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Yoyok Dwi Setyo Pambudi
    • 1
    • 2
  • Rudy Setiabudy
    • 1
    Email author
  • Akhmad Herman Yuwono
    • 3
  • Evvy Kartini
    • 4
  • Joong Kee Lee
    • 5
  • Chairul Hudaya
    • 1
    • 6
    Email author
  1. 1.Department of Electrical EngineeringFaculty of Engineering Universitas IndonesiaDepokIndonesia
  2. 2.Center for Nuclear Reactor Technology and SafetyBATANTangerang SelatanIndonesia
  3. 3.Department of Metallurgical and Materials EngineeringFaculty of Engineering Universitas IndonesiaDepokIndonesia
  4. 4.Center for Science and Technology of Advanced MaterialsBATANTangerangIndonesia
  5. 5.Center for Energy Convergence Research, Green City Research InstituteKorea Institute of Science and Technology (KIST)SeoulRepublic of Korea
  6. 6.Energy System EngineeringFaculty of Engineering Universitas IndonesiaDepokIndonesia

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