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A novel and green synthesis of mixed phase CoO@Co3O4@C anode material for lithium ion batteries

  • Halil Şahan
  • Hüseyin Göktepe
  • Süleyman Yıldız
  • Cafer Çaymaz
  • Şaban Patat
Original Paper
  • 49 Downloads

Abstract

CoO composite materials had attracted wide attention due to their potential application in lithium ion batteries (LIBs). We report a green and novel solution method for making pristine Co3O4 and mixed phase CoO@Co3O4@C composite anode electrodes in LIBs. The anode materials characterized by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The XRD diffraction pattern reveals that composite anode contains as a major phase of CoO and small amounts of cubic Co3O4 and Co metal peaks are found as impurity phases. The SEM micrographs showed that CoO, Co3O4, and Co phases are distributed in amorphous carbon network. The electrochemical behavior of anodes material is investigated by galvanostatic discharge/charge measurements and cyclic voltammetry. The composite anode shows a reversible specific capacity approaching 447 ± 5 mAh g−1 after 10 cycles at 100 and 107 ± 5 mAh g−1 after 50 cycles at 500 mA g−1as well as improved cyclic stability and excellent rate capability. The enhancement of the electrochemical performance is attributed to the good electric contact between the particles, easier lithium ion diffusion, and suppression of volume change of anode.

Keywords

Lithium ion batteries CoO Anode materials Capacity fade Green synthesis Electrochemical performance 

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Halil Şahan
    • 1
  • Hüseyin Göktepe
    • 3
  • Süleyman Yıldız
    • 2
    • 3
  • Cafer Çaymaz
    • 3
  • Şaban Patat
    • 2
    • 3
  1. 1.Center for Renewable Energy Technology, Department of Chemistry and Chemical BiologyNortheastern UniversityBostonUSA
  2. 2.Science Faculty, Department of ChemistryErciyes UniversityKayseriTurkey
  3. 3.Erciyes UniversityNanotechnology Research CenterKayseriTurkey

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