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Ionics

, Volume 25, Issue 2, pp 467–473 | Cite as

High-performance anode materials based on 3D orderly and vertically macroporous graphene-Si framework for Li-ion batteries

  • Fengjuan MiaoEmail author
  • Wanjuan Cong
  • Rui Miao
  • Na Wang
  • Wenyi Wu
  • Yu Zang
  • Cuiping Shi
  • Lei Zhu
  • Bairui TaoEmail author
  • Paul K. Chu
Original Paper
  • 62 Downloads

Abstract

Porous graphene/Si-MCP (microchannel plate) microstructures are fabricated using electrochemical exfoliation and microelectronic machining. The few-layer graphene nanosheets with a lateral size of 600–850 nm and thickness of 2–3 nm are uniformed anchored on the surface and channels of the Si-MCP substrate. The as-prepared graphene/Si-MCP is used as the anode in lithium ion batteries and demonstrated to have a higher reversible capacity, better cycling retention, and excellent higher rate cycling performance compared to graphene/Si and Si-MCP. The good properties are attributed to the large surface-to-volume ratio of the structure and the better electrical contact with graphene. This silicon-based composite has large potential as anodes in integrated batteries.

Keywords

Graphene/Si-MCP Anode Li-ion batteries Electrochemical exfoliation 

Notes

Funding information

This work was jointly supported by the Postdoctoral scientific research developmental fund of Heilongjiang Province (Grant No. LBH-Q15142, LBH-Q14157), Science and Technology Project of Qiqihar (Grant No. GYGG-201409, GYGG-201619), Higher School Science and Technology Achievements Industrialization Pre-Research and Development Foundation of Heilongjiang Province (Grant No. 1254CGZH04), University Nursing Program for Young Scholars with Creative Talents in Heilongjiang Province (Grant No. UNPYSCT-2016087), Scientific Research Foundation for the Returned Overseas Chinese Scholars in Heilongjiang Province, and Hong Kong Research Grants Council General Research Funds CityU 11301215.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Fengjuan Miao
    • 1
    Email author
  • Wanjuan Cong
    • 1
  • Rui Miao
    • 1
  • Na Wang
    • 1
  • Wenyi Wu
    • 1
  • Yu Zang
    • 2
  • Cuiping Shi
    • 1
  • Lei Zhu
    • 1
  • Bairui Tao
    • 1
    Email author
  • Paul K. Chu
    • 3
  1. 1.College of Communications and Electronics EngineeringQiqihar UniversityHeilongjiangChina
  2. 2.College of Materials Science and EngineeringQiqihar UniversityQiqiharChina
  3. 3.Department of Physics and Department of Materials Science and EngineeringCity University of Hong KongKowloonChina

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