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Ionics

, Volume 25, Issue 3, pp 1223–1233 | Cite as

The effects of carbon coating on the electrochemical performance of Zn-Al layer double oxides in nickel-zinc secondary cells

  • Xiao Zeng
  • Zhanhong YangEmail author
  • Jun Long
  • Linlin Chen
  • Haigang Qin
  • Maokui Fan
Original Paper
  • 89 Downloads

Abstract

Carbon-coated Zn-Al layer double oxide (Zn-Al-LDOs) is synthesized by hydrothermal-calcined method and investigated as an anode material for the Ni-Zn cells. The as-obtained products are characterized by scanning electron microscopy (SEM), energy dispersive X-ray spectrum (EDS), and X-ray diffraction (XRD), which prove that carbon-coated Zn-Al-LDOs are well-crystallized and carbon formed on the surface of Zn-Al-LDOs is amorphous. The electrochemical performances of the carbon-coated Zn-Al-LDOs electrode with different carbon content and pure Zn-Al-LDOs electrode are investigated by the cyclic voltammograms (CV), AC electrochemical impedance spectroscopy (EIS), Tafel plot (TAFEL), and galvanostatic charge-discharge (GCD) measurements. Compared with the pure Zn-Al-LDOs electrode, the carbon-coated Zn-Al-LDOs electrode shows better reversibility, higher specific capacity, and more excellent cycling performance.

Keywords

Carbon coating Zinc-aluminum layer double oxides Zinc electrode Nickel-zinc secondary cells Electrochemical performance 

Notes

Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (no. 21371180), Doctoral Fund of Ministry of Education of China (20130162110018), and the Science and Technology Project of Changsha City (no. k1303015-11).

Supplementary material

11581_2018_2642_MOESM1_ESM.dtd (42 kb)
ESM 1 (DTD 42 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Xiao Zeng
    • 1
    • 2
  • Zhanhong Yang
    • 1
    Email author
  • Jun Long
    • 1
  • Linlin Chen
    • 1
  • Haigang Qin
    • 1
  • Maokui Fan
    • 2
  1. 1.College of Chemistry and Chemical EngineeringCentral South UniversityChangshaChina
  2. 2.Public Security Fire Forces CollegeKunmingChina

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