Ionics

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Study of biopolymer I-carrageenan with magnesium perchlorate

  • S. Shanmuga Priya
  • M. Karthika
  • S. Selvasekarapandian
  • R. Manjuladevi
  • S. Monisha
Original Paper
  • 12 Downloads

Abstract

The green revolution has led to the study of biopolymer for development of polymer electrolyte for electrochemical devices. Cellulose acetate, pectin, chitosan, and carrageenan are some of the biopolymers. Biopolymer-based membrane for proton conduction and lithium ion conduction have developed and characterized by different techniques. But the study of biopolymer based on Mg2+ ion is rare in literature. So, biopolymer based on I-carrageenan with magnesium has been studied. I-carrageenan biopolymer membrane with different concentration of magnesium perchlorate has been prepared by solution casting technique. Developed biopolymer membrane have been characterized by X-ray diffraction analysis (XRD), FTIR, differential scanning calorimetry (DSC), and AC impedance techniques. Pure I-carrageenan has shown a conductivity value of 5.90 × 10−5 S/cm. I-carrageenan membrane with 0.6 wt% of magnesium perchlorate has shown a conductivity of 2.18 × 10−3 S/cm. A primary Mg2+ ion battery has been constructed and its performance is studied. XRD has been undertaken to study the amorphous/crystalline nature of the sample. I-carrageenan with 0.6 wt% of magnesium membrane has shown highest amorphous nature. FTIR study confirms the complex formation between polymer and salt. AC impedance technique has been used to study the conductivity of the samples.

Keywords

Biopolymer Magnesium salt XRD FTIR Conductivity analysis Mg-ion battery 

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • S. Shanmuga Priya
    • 1
    • 2
  • M. Karthika
    • 1
  • S. Selvasekarapandian
    • 2
    • 3
  • R. Manjuladevi
    • 2
    • 4
  • S. Monisha
    • 2
    • 5
  1. 1.Department of PhysicsNGM CollegePollachiIndia
  2. 2.Materials Research CenterCoimbatoreIndia
  3. 3.Department of PhysicsBharathiar UniversityCoimbatoreIndia
  4. 4.Department of PhysicsSNS College of EngineeringCoimbatoreIndia
  5. 5.Department of PhysicsN.M.S.S. Vellaichamy Nadar CollegeMaduraiIndia

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