Ionics

, Volume 23, Issue 6, pp 1423–1437 | Cite as

AC conductivity and dielectric behavior in mixed electronic-ionic 30Li2O–4MoO3–(66–x)TeO2–xV2O5 glass system

  • Rosdiyana Hisam
  • Ahmad Kamal Yahya
  • Halimah Mohamed Kamari
  • Zainal Abidin Talib
Original Paper
First Online:
Received:
Revised:
Accepted:

Abstract

AC conductivity, dielectric property, and electric modulus formalism of lithium molybdenum tellurite glasses containing vanadium with compositions 30Li2O–4MoO3–(66–x)TeO2–xV2O5 (x = 0.2, 0.4, 0.6, 0.8, 1.0, and 1.2) have been studied in the frequency range 10−2 Hz to 1 MHz and temperature range 323–413 K to investigate the effects of mixed ionic–electronic carriers in the glasses. The variation of AC conductivity with V2O5 showed a nonlinear increase for x ≤ 0.6 mol% before decreasing to a minimum at 0.8 mol% V2O5. The decrease in σ AC attributed to some forms of blocking effect on Li+ ions caused by the mixed ionic–electronic (MIE) effect. Meanwhile, dielectric constant showed a general increase for x ≤ 0.6 before an anomalous decrease at x = 0.8 mol% V2O5, which was followed by a large increase at x > 0.8 mol%. The decrease at x = 0.8 mol% coincided with the σ AC drop at the same location. This decrease was also suggested related to the MIE that induced a blocking effect, which caused the restricted dipole movement.

Keywords

Glasses Dielectric properties Electrical conductivity Mixed ionic–electronic effect 
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Notes

Acknowledgement

The project was financially supported by the Ministry of Higher Eduction of Malaysia and Research Management Centre (RMC), Universiti Teknologi Mara through the RAGS grant (No. RMI 600-RMI/RAGS 5/3 (141/2014)). The authors would like to express their gratitude to the Universiti Teknologi Mara and the Ministry of Higher Eduction of Malaysia for the SLAI scholarship given to Rosdiyana Hisam.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

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Copyright information

© Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  • Rosdiyana Hisam
    • 1
  • Ahmad Kamal Yahya
    • 1
  • Halimah Mohamed Kamari
    • 2
  • Zainal Abidin Talib
    • 2
  1. 1.Faculty of Applied SciencesUniversiti Teknologi MaraShah AlamMalaysia
  2. 2.Faculty of ScienceUniversiti Putra MalaysiaSerdangMalaysia

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