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An electrochemical study on the substituted spinel LiMn1.95Cr0.05O4

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Abstract

Cyclic voltammetry, galvanostatic charge–discharge technique, potentiostatic intermittent titration technique (PITT), and electrochemical impedance spectroscopy (EIS) were used to study the behavior of a LiMn1.95Cr0.05O4 (substituted lithium–manganese spinel) electrode in nonaqueous electrolytes at 25 °C. Quantitative and qualitative changes of the electrode transport parameters as functions of lithium concentration were analyzed. Several equivalent circuits are discussed; the results obtained by different methods are compared. The PITT and EIS results are in good agreement; the chemical diffusion coefficient D varies within 10−14–10−9 cm2 s−1 depending on the lithium content in the LixMn1.95Cr0.05O4 electrode.

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Acknowledgments

The authors would like to gratefully acknowledge the Russian Foundation for Basic Research (project #10-03-00301).

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Authors and Affiliations

  1. Institute of Chemistry, Saratov State University, 83 Astrakhanskaya Str., Saratov, 410012, Russian Federation

    Alexei V. Churikov & Veronica O. Romanova

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  1. Alexei V. Churikov
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  2. Veronica O. Romanova
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Correspondence to Alexei V. Churikov.

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Churikov, A.V., Romanova, V.O. An electrochemical study on the substituted spinel LiMn1.95Cr0.05O4 . Ionics 18, 837–844 (2012). https://doi.org/10.1007/s11581-012-0741-9

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  • DOI: https://doi.org/10.1007/s11581-012-0741-9

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