Ionics

, Volume 14, Issue 6, pp 477–482

Characterisation of Ba2In2 − xSnxO5 + x/2 oxide ion conductors

  • Aurélie Rolle
  • Helen Seymour
  • Pascal Roussel
  • Annick Rubbens
  • Rose-Noëlle Vannier
Original Paper

Abstract

The Ba2In2 − xSnxO5 + x/2 solid solution was confirmed up to x = 1 by solid-state reaction. X-ray diffraction at room and at elevated temperatures, Raman scattering and impedance spectroscopy were used to characterise the samples. The structure refinement of the composition x = 0.1 from neutron diffraction data reveals that tin is preferentially located in the tetrahedral layers of the brownmillerite.

Keywords

Oxide ion conductors Ba2In2 − xSnxO5 + x/2 X-ray diffraction Neutron diffraction Raman scattering 

References

  1. 1.
    Goodenough JB, Ruiz-Diaz JE, Zhen YS (1990) Solid State Ion 44:21–31CrossRefGoogle Scholar
  2. 2.
    Gregory DH, Weller MT (1993) J Solid State Chem 107(1):134–148CrossRefGoogle Scholar
  3. 3.
    Adler SB, Reimer JA, Baltisberger J, Werner U (1994) J Am Chem Soc 116:675–681CrossRefGoogle Scholar
  4. 4.
    Speakman SA, Richardson JW, Mitchell BJ, Misture ST (2002) Solid State Ion 149:247–259CrossRefGoogle Scholar
  5. 5.
    Kambe S, Shime I, Ohshima S, Okuyama K, Ohnishi N, Hiraga K (1994) Physica C 220:119–126CrossRefGoogle Scholar
  6. 6.
    Kharlanov AL, Khasanova NR, Paromova MV, Antipov EV, Lykova LN, Kovba LM (1990) Russ J Inorg Chem 35(12):1741–1743Google Scholar
  7. 7.
    Fisher CAJ, Derby B, Brook RJ (1996) Br Ceram Proc 56:25–33Google Scholar
  8. 8.
    Yamamura H, Yamada Y, Mori T, Atake T (1998) Solid State Ion 108:377–381CrossRefGoogle Scholar
  9. 9.
    Yamamura H, Hamazaki H, Kakinuma K, Mori T, Haneda H (1999) J Korean Phys Soc 35:200–204Google Scholar
  10. 10.
    Yao T, Uchimoto Y, Kinuhata M, Inagaki T, Yoshida H (2000) Solid State Ion 132:189–198CrossRefGoogle Scholar
  11. 11.
    Kakinuma K, Yamamura H, Atake T (2002) J Therm Anal Calorim 69:897–904CrossRefGoogle Scholar
  12. 12.
    Yamaji A, Kawakami K, Arai M, Adachi T (2000) Mat Res Soc Symp 575:343–348Google Scholar
  13. 13.
    Kendall KR, Navas C, Thomas JK, zur Loye HC (1995) Solid State Ion 82:215–223CrossRefGoogle Scholar
  14. 14.
    Manthiram A, Kuo JF, Goodenough JB (1993) Solid State Ion 62:225–234CrossRefGoogle Scholar
  15. 15.
    Goodenough JB, Manthiram A, Kuo JF (1993) Mater Chem Phys 35:221–224CrossRefGoogle Scholar
  16. 16.
    Berastegui P, Hull S, Garcia-Garcia J, Eriksson SG (2002) J Solid State Chem 164:119–130CrossRefGoogle Scholar
  17. 17.
    Jayaraman V, Magrez A, Caldes M, Joubert O, Ganne M, Piffard Y, Brohan L (2004) Solid State Ion 170(1–2):17–24CrossRefGoogle Scholar
  18. 18.
    Schober T (1998) Solid State Ion 109:1–11CrossRefGoogle Scholar
  19. 19.
    Shimura T, Yogo T (2004) Solid State Ion 175:345–348CrossRefGoogle Scholar
  20. 20.
    Rolle A, Giridharan NV, Vannier RN, Abraham F (2005) Solid State Ion 176:2095–2103CrossRefGoogle Scholar
  21. 21.
    Yoshinaga M, Yamaguchi M, Furuya T, Wang S, Hashimoto T (2004) Solid State Ion 169:9–13CrossRefGoogle Scholar
  22. 22.
    Kakinuma K, Yamamura H, Haneda H, Atake T (2002) Solid State Ion 154–155:571–576CrossRefGoogle Scholar
  23. 23.
    Kakinuma K, Yamamura H, Haneda H, Atake T (1999) J Therm Anal Calorim 57:737–743CrossRefGoogle Scholar
  24. 24.
    Uchimoto Y, Yao T, Takagi H, Inagaki T, Yoshida H (2000) Electrochemistry 68:531–533Google Scholar
  25. 25.
    Kakinuma K, Yamamura H, Haneda H, Atake T (2001) Solid State Ion 140:301–306CrossRefGoogle Scholar
  26. 26.
    Liu Y, Withers RL, Gerald JF (2003) J Solid State Chem 170:247–254CrossRefGoogle Scholar
  27. 27.
    Kakinuma K, Takahashi N, Yamamura H, Nomura K, Atake T (2004) Solid State Ion 168:69–74CrossRefGoogle Scholar
  28. 28.
    Goodenough JB (1997) Solid State Ion 94:17–25CrossRefGoogle Scholar
  29. 29.
    Kuramochi H, Mori T, Yamamura H, Kobayashi H, Mitamura T (1994) J Ceramic Soc Jpn 102:1160–1163Google Scholar
  30. 30.
    Petricek V, Dusek M, Palatinus L (2006) The crystallographic computing system JANA 2000. Institute of Physics, Praha, Czech RepublicGoogle Scholar
  31. 31.
    Rolle A, Roussel P, Giridharan NV, Suard E, Vannier RN (2008) Chem Mater (in press)Google Scholar

Copyright information

© Springer-Verlag 2008

Authors and Affiliations

  • Aurélie Rolle
    • 1
  • Helen Seymour
    • 1
  • Pascal Roussel
    • 1
  • Annick Rubbens
    • 1
  • Rose-Noëlle Vannier
    • 1
  1. 1.UCCS—Unité de Catalyse et Chimie du Solide, Equipe de Chimie du Solide, CNRS UMR 8181ENSCL/UST Lille 1Villeneuve d’Ascq CedexFrance

Personalised recommendations