Dissipation Kinetics of Hexaconazole and Lambda-Cyhalothrin Residue in Soil and Potato Plant

  • Raginee DeviEmail author
  • R. P. Singh
  • A. K. Sachan


The dissipation behaviour and left-over residues of Hexaconazole fungicide and Lambda-Cyhalothrin pesticide in potato plant and soil were analysed by gas chromatography mass spectrometry (GC-MS). At fortified levels of 10, 100 and 500 μg/kg, the recoveries of Lambda-Cyhalothrin and Hexaconazole were in the range 81.66–93.25% and 76.11–93.92% with standard deviations of 0.87–8.13% and 0.88–7.68%, respectively. The half-life ranges for all matrices (tuber, stem, leaf and soil) were 13.8–17.3 days for Hexaconazole and 11.5–17.3 days for Lambda-Cyhalothrin. The final concentration of Hexaconazole and Lambda-Cyhalothrin in tuber at harvest was compared with the maximum residual limit (MRL) of CODEX (0.01 mg/kg) and EU (0.02 mg/kg) and found to be higher at dosages of 30 g/ha and 40 g/ha, respectively. There was no residual concentration of either pesticide in the control plot. The results obtained from risk evaluation showed that the risk of Lambda-Cyhalothrin at dosage of 7–15 g/ha and Hexaconazole at dosage of 5–30 g/ha was negligible to humans while a dose of 40 g/ha for Lambda-Cyhalothrin resulted in a health hazard to humans. This study may prove helpful in ascertaining the MRL and also provide direction on the appropriate use of Lambda-Cyhalothrin and Hexaconazole in potato farming as the waiting period from last application to harvest is 25 days for Hexaconazole and 38 days for Lambda-Cyhalothrin.


Fungicide residues Gas chromatography mass spectrometry Heaxaconazole residues Lambda-Cyhalothrin residues Pesticide residues Potatoes 



The authors are thankful to the director and Head of the Civil Engineering department Motilal Nehru National Institute of Technology Allahabad, India, for providing the necessary laboratory facilities for this research work.

Compliance with Ethical Standards

This study is part of Raginee Devi’s Ph. D program with support from MNNIT Allahabad, India.

Conflict of Interest

The authors declare that they have no conflict of interest.


  1. Arias-Estévez M, López-Periago E, Martínez-Carballo E, Simal-Gándara J, Mejuto J, García-Río L (2008) The mobility and degradation of pesticides in soils and the pollution of groundwater resources. Agric Ecosyst Environ 123:247–260. CrossRefGoogle Scholar
  2. Arrebola FJ, Martínez Vidal JL, González-Rodríguez MJ, Garrido-Frenich A, Morito S (2003a) Reduction of analysis time in gas chromatography application of low pressure gas chromatography tandem mass spectrometry to the determination of pesticide residues in vegetables. J Chromatogr A 1005:131–141. CrossRefPubMedGoogle Scholar
  3. Arrebola FJ, Martínez Vidal JL, Mateu-Sánchez M, Álvarez-Castellón FJ (2003b) Determination of 81 multiclass pesticides in fresh foodstuffs by a single injection analysis using gas chromatography chemical ionization and electron ionization tendem mass spectrometry. Anal Chim Acta 484:167–180. CrossRefGoogle Scholar
  4. Australian Government (2016) Acceptable daily intakes for agricultural and veterinary chemicals. Office of Chemical Safety, Department of Health, Canberra, pp 1–119$File/ADI%20List_updated%20to%2031%20Mar%202016.pdf Google Scholar
  5. Balinova A, Mladenova R, Shtereva D (2007) Solid phase extraction on sorbents of different retention mechanisms followed by determination by gas chromatography mass spectrometric and gas chromatograpgy electron capture detection of pesticide residues in crop. J Chromatogr A 1150:136–144. CrossRefPubMedGoogle Scholar
  6. Banerjee K, Utture S, Dasgupta S, Kandaswamy C, Pradhan S, Kulkarni S, Adsule P (2012) Multiresidue determination of 375 organic contaminants including pesticides, polychlorinated biphenyls and polyaromatic hydrocarbons in fruits and vegetables by gas chromatography triple quadrupole mass spectrometry with introduction of semi quantification approach. J Chromatogr A 1270:283–295. CrossRefPubMedGoogle Scholar
  7. Barik SR, Ganguly P, Kunda SK, Kole RK, Battacharyya A (2010) Persistence behavior of thiamethoxam and Lambda Cyhalothrin in transplanted paddy. Bull Environ Contam Toxicol 85:419–422. CrossRefPubMedGoogle Scholar
  8. Codex Alimentarius Commission (2016) Pesticide residues in food, FAO/WHO food standard.
  9. Darko G, Akoto O (2008) Dietary intake of organophosphorous pesticide residues through vegetables from Kumasi, Ghana. Food Chem Toxicol 46:3703–3706. CrossRefPubMedGoogle Scholar
  10. European Commission (2012) Pesticide EU-MRLs Regulation (EU) No 899/2012.
  11. European Union (2013) Guidance document on analytical quality control and validation procedures for pesticide residues analysis in food and feed. EU, Document No. SANCO/12571/2013.
  12. FAOSTAT (2013) Potato consumption statistics in India. data retrieved on July, 2015
  13. Government of India, Indian horticulture database (2013). Ministry of Agriculture, National horticulture board.
  14. Government of India, Insecticide Act-1968 (2009) Ministry of Agriculture, Department of Agriculture & Co-operation, New Delhi.
  15. Kumar V, Ravindranath SD, Shanker A (2004) Fate of hexaconazole residues in tea and its behavior during brewing process. Chem Health Saf 11:21–25. CrossRefGoogle Scholar
  16. Liang H, Li L, Li W, Wu Y, Liu F (2012) The decline and residues of hexaconazole in tomato and soil. Environ Monit Assess 184:1573–1579. CrossRefPubMedGoogle Scholar
  17. Lofty HM, El-Aziz A, El-Aleem A, Monir HH (2013) Determination of insecticides malathion and lambda-cyhalothrin residue in zucchini by gas chromatography. Bull Fac Pharm Cairo Univ 51:255–260. CrossRefGoogle Scholar
  18. Paterio-Moure M, Arias-Estévez M, López-Periago E, Martínez-Carballo E, Simal-Gándara J (2008) Occurrence and downslope mobilization of quaternary herbicide residues in vineyard-devoted soils. Bull Environ Contam Toxicol 80:407–411. CrossRefGoogle Scholar
  19. Scott GJ, Suarez V (2011) Growth rates for potato in India and their implication for industry. Potato J 38:100–112. ISSN 0970-8235Google Scholar
  20. Srivastava AK, Trivedi P, Srivastava MK, Lohani M, Srivastava LP (2011) Monitoring of pesticide residues in market basket samples of vegetable from Lucknow city, India: QuEChERS method. Environ Monit Assess 176:465–472. CrossRefPubMedGoogle Scholar
  21. Tariq MI, Afzal S, Hussain I (2006) Degradation and persistence of cotton pesticides in sandy loam soil from Punjab, Pakistan. Environ Res 100:184–196. CrossRefPubMedGoogle Scholar
  22. Vuković G, Shtereva D, Bursić V, Mladenova R, Lazić S (2012) Application of GC-MSD and LC-MS/MS for the determination of priority pesticides in baby foods in Serbain market. LWT – Food Sci Technol 49:312–319. CrossRefGoogle Scholar
  23. Walorczyk S, Drożdżyński D (2012) Improvement and extension to new analytes of a multi-residue method for the determination of pesticides in cereals and dry animal feed using gas chromatography tandem quadrupole mass spectrometry revisited. J Chromatogr A 1251:219–231. CrossRefPubMedGoogle Scholar
  24. Walorczyk S, Drożdżyński D, Gnusowski B (2011) Multiresidue determination of 160 pesticides in wines employing mixed mode dispersive solid phase extraction and gas chromatography tandem mass spectrometry. Talanta 85:1856–1870. CrossRefPubMedGoogle Scholar
  25. Wang Y, Jin H, Ma S, Lu J, Lin R (2011) Determination of 195 pesticide residues in Chinese herbs by gas chromatography mass spectrometry using analyte protectants. J Chromatogr A 1218:334–342. CrossRefPubMedGoogle Scholar
  26. WHO (1990) Cyhalothrin, Environmental Health Criteria, 99; Geneva, SwitzerlandGoogle Scholar
  27. WHO (1997) Guidelines for predicting dietary intake of pesticide residues (revised) global environment monitoring system – food contamination monitoring and assessment programme (GEMS/Food) in collaboration with Codex Committee on pesticide residues. Programme of Food Safety and Food Aid, pp. 1–44Google Scholar
  28. Xu X, Yu S, Li R, Fan J, Chen S, Shen H, Han J, Huang B, Ren Y (2012) Distribution and migration study of pesticides between peel and pulp in grape by online gel permeation chromatography gas chromatography mass spectrometry. Food Chem 135:161–169. CrossRefGoogle Scholar
  29. Zayats MF, Leschev SM, Petrashkevich NV, Zayats MA, Kadenczki L, Szitás R, Szemán Dobrik H, Keresztény N (2013) Distribution of pesticides in n-hexane/water and n-hexane/acetonitrile system and estimation of possibilities of their extraction isolation and preconcentration from various matrices. Anal Chim Acta 774:33–43. CrossRefPubMedGoogle Scholar

Copyright information

© European Association for Potato Research 2019

Authors and Affiliations

  1. 1.Department of Civil EngineeringMNNIT, AllahabadAllahabadIndia

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