Plasmonics

, Volume 9, Issue 2, pp 227–235 | Cite as

Aqueous Diaminsilver Hydroxide as a Precursor of Pure Silver Nanoparticles for SERS Probing of Living Erythrocytes

  • Anna A. Semenova
  • Nadezda A. Brazhe
  • Evgeniya Y. Parshina
  • Vladimir K. Ivanov
  • Georgy V. Maksimov
  • Eugene A. Goodilin
Article

Abstract

A new effective and simple preparation method of pure metallic hydrosols consisting of silver nanoparticles is proposed using aqueous diaminsilver hydroxide as a precursor freed of special reducing agents, surfactants, or anionic pollutants. The process is driven by NH3 ligand loss and silver complex dissociation followed by silver ion reduction with hydroxyl ions or ammonia itself present in the solution. Self-reduction of aqueous diaminsilver hydroxide occurs for 20–60 min at 90–100 °C in water and results in a wide range of silver nanoparticles, with their sizes dependent on silver complex concentration and reaction time. The pure silver hydrosol is found to attach to a cell membrane without its damage thus allowing measurements of SERS spectra of submembrane hemoglobin inside living erythrocytes.

Keywords

Silver Nanoparticles Soft Chemistry Ammonia SERS 

Notes

Acknowledgments

This work was supported by the Russian Foundation for Basic Research (contract 13-03-12190), the Development Program of MSU and The Danish Council for Independent Research | Natural Sciences. Authors thanks O. Sosnovtseva (Copenhagen University) and S. Savilov (MSU) for their help with the experiments and their fruitful discussions.

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Copyright information

© Springer Science+Business Media New York 2013

Authors and Affiliations

  • Anna A. Semenova
    • 1
  • Nadezda A. Brazhe
    • 2
  • Evgeniya Y. Parshina
    • 2
  • Vladimir K. Ivanov
    • 1
    • 3
  • Georgy V. Maksimov
    • 2
  • Eugene A. Goodilin
    • 1
    • 4
  1. 1.Department of Materials ScienceMoscow State UniversityMoscowRussia
  2. 2.Faculty of BiologyMoscow State UniversityMoscowRussia
  3. 3.Kurnakov Institute of General and Inorganic Chemistry of RASMoscowRussia
  4. 4.Faculty of ChemistryMoscow State UniversityMoscowRussia

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