Optimal spectral phase control of femtosecond laser-induced up-conversion luminescence in Sm3+:NaYF4 glass

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The spectral phase of the femtosecond laser field is an important parameter that affects the upconversion (UC) luminescence efficiency of dopant lanthanide ions. In this work, we report an experimental study on controlling the UC luminescence efficiency in Sm3+:NaYF4 glass by 800-nm femtosecond laser pulse shaping using spectral phase modulation. The optimal phase control strategy efficiently enhances or suppresses the UC luminescence intensity. Based on the laser-power dependence of the UC luminescence intensity and its comparison with the luminescence spectrum under direct 266-nm femtosecond laser irradiation, we propose herein an excitation model combining non-resonant two-photon absorption with resonance-mediated three-photon absorption to explain the experimental observations.

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This work was partly supported by the National Natural Science Foundation of China (Grant Nos. 91850202, 11774094, 11727810, 11804097, and 61720106009), the Science and Technology Commission of Shanghai Municipality (Grant No. 17ZR146900), the China Postdoctoral Science Foundation (Grant No. 2018M641958), and ECNU Academic Innovation Promotion Program for Excellent Doctoral Students (Grant No. YBNLTS2019-011).

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Correspondence to Lian-Zhong Deng or Shi-An Zhang.

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Li, J., Deng, L., Zheng, Y. et al. Optimal spectral phase control of femtosecond laser-induced up-conversion luminescence in Sm3+:NaYF4 glass. Front. Phys. 15, 22603 (2020).

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  • up-conversion luminescence
  • rare earth ions
  • quantum control
  • femtosecond laser
  • spectral phase