Sustainable soil stabilisation with ground granulated blast-furnace slag activated by olivine and sodium hydroxide
- 41 Downloads
Abstract
Ground granulated blast-furnace slag (GGBS), activated with olivine (Mg2SiO4) and sodium hydroxide (NaOH), was used to stabilise a clayey soil. Mechanical and microstructural properties of the stabilised soil were assessed through uniaxial compression strength (UCS) tests, X-ray diffraction, scanning electron microscopy and energy-dispersive X-ray spectroscopy (EDS), after curing periods of 7, 18 and 90 days. The UCS of the GGBS-treated soil (without activation with NaOH), even at the highest slag dosage (G20S), after 90 days, showed only a slight increase (142 kPa) relatively to the original soil. When olivine was added to the GGBS-treated mixture (O20G20S), the UCS increased to 444 kPa, after 90 days. However, when NaOH was used as an activator, the UCS of the olivine–GGBS-treated soil (NO20G20S) increased to more than 6000 kPa, after 90 days. This significant strength increase was attributed to the higher reaction degree provided by the NaOH, which enabled a more effective exploitation (dissolution) of the Ca and Mg present in the slag and olivine, respectively, forming a mixture of C–S–H and M–S–H gels.
Keywords
Alkaline activation Ground granulated blast-furnace slag Olivine Soil stabilisationNotes
References
- 1.Al-Tabbaa A, Liu C, Gao L et al (2015) Incorporation of reactive magnesia and quicklime in sustainable binders for soil stabilisation. Eng Geol 195:53–62. https://doi.org/10.1016/j.enggeo.2015.05.025 CrossRefGoogle Scholar
- 2.ASTM D2487-11 (2011) Standard practice for classification of soils for engineering purposes (Unified Soil Classification System). Am Soc Test MaterGoogle Scholar
- 3.Ball RJ, Pourakbar S, Huat BK et al (2016) Utilisation of carbonating olivine for sustainable soil stabilisation. Environ Geotech 4:184–198. https://doi.org/10.1680/jenge.15.00018 CrossRefGoogle Scholar
- 4.BSi 1377–4 (1990) BS 1377-4: 1990 - Methods of test for soils for civil engineering purposes, Part 4: Compaction-Related Tests. Br Stand Institution, London, p 4Google Scholar
- 5.BSi 1377–7 (1990) BS 1377-7: 1990 - Methods of test for soils for civil engineering purposes, Part 7: Shear Strength Tests (Total Stress). Br Stand Institution, London, p 7Google Scholar
- 6.Chang I, Cho GC (2019) Shear strength behavior and parameters of microbial gellan gum-treated soils: from sand to clay. Acta Geotech 14:361–375CrossRefGoogle Scholar
- 7.Cheng L, Shahin MA, Chu J (2019) Soil bio-cementation using a new one-phase low-pH injection method. Acta Geotech 14:615–626CrossRefGoogle Scholar
- 8.Du YJ, Wu J, Bo YL, Jiang NJ (2019) Effects of acid rain on physical, mechanical and chemical properties of GGBS–MgO-solidified/stabilized Pb-contaminated clayey soil. Acta Geotech. https://doi.org/10.1007/s11440-019-00793-y CrossRefGoogle Scholar
- 9.Fasihnikoutalab MH, Asadi A, Kim Huat B et al (2016) Laboratory-scale model of carbon dioxide deposition for soil stabilisation. J Rock Mech Geotech Eng 8:178–186. https://doi.org/10.1016/j.jrmge.2015.11.001 CrossRefGoogle Scholar
- 10.Fasihnikoutalab MH, Pourakbar S, Ball RJ, Huat BK (2017) The effect of olivine content and curing time on the strength of treated soil in presence of potassium hydroxide. Int J Geosynth Gr Eng 3:12. https://doi.org/10.1007/s40891-017-0089-3 CrossRefGoogle Scholar
- 11.Gartner E (2004) Industrially interesting approaches to “low-CO2” cements. Cem Concr Res 34:1489–1498. https://doi.org/10.1016/j.cemconres.2004.01.021 CrossRefGoogle Scholar
- 12.Haha MB, Lothenbach B, Le Saout G, Winnefeld F (2011) Influence of slag chemistry on the hydration of alkali-activated blast-furnace slag—Part I: effect of MgO. Cem Concr Res 41:955–963. https://doi.org/10.1016/J.CEMCONRES.2011.05.002 CrossRefGoogle Scholar
- 13.Higgins DD, Kinuthia JM, Wild S (1998) Soil stabilization using lime-activated ground granulated blast furnace slag. Spec Publ 178:1057–1074. https://doi.org/10.14359/6023 CrossRefGoogle Scholar
- 14.Horpibulsuk S, Bergado DT, Lorenzo GA (2004) Compressibility of cement-admixed clays at high water content. Géotechnique 54:151–154. https://doi.org/10.1680/geot.54.2.151.36341 CrossRefGoogle Scholar
- 15.Horpibulsuk S, Miura N, Nagaraj TS (2004) Assessment of strength development in cement-admixed high water content clays with Abrams’ law as a basis. Géotechnique 53:439–444. https://doi.org/10.1680/geot.53.4.439.37319 CrossRefGoogle Scholar
- 16.Huat BK, Ball RJ, Asadi A et al (2017) Utilization of alkali-activated olivine in soil stabilization and the effect of carbonation on unconfined compressive strength and microstructure. J Mater Civ Eng 29:06017002. https://doi.org/10.1061/(asce)mt.1943-5533.0001833 CrossRefGoogle Scholar
- 17.Jegandan S, Liska M, Osman AA-M, Al-Tabbaa A (2010) Sustainable binders for soil stabilisation. Proc Inst Civ Eng—Gr Improv 163:53–61. https://doi.org/10.1680/grim.2010.163.1.53 CrossRefGoogle Scholar
- 18.Kim Y, Worrell E (2002) CO2 emission trends in the cement industry: an international comparison. Mitig Adapt Strateg Glob Change 7:115–133. https://doi.org/10.1023/A:1022857829028 CrossRefGoogle Scholar
- 19.Konsta-Gdoutos MS, Shah SP (2003) Hydration and properties of novel blended cements based on cement kiln dust and blast furnace slag. Cem Concr Res 33:1269–1276. https://doi.org/10.1016/S0008-8846(03)00061-9 CrossRefGoogle Scholar
- 20.Lothenbach B, Scrivener K, Hooton RD (2011) Supplementary cementitious materials. Cem Concr Res 41:1244–1256. https://doi.org/10.1016/j.cemconres.2010.12.001 CrossRefGoogle Scholar
- 21.Nidzam RM, Kinuthia JM (2010) Sustainable soil stabilisation with blastfurnace slag—a review. Proc Inst Civ Eng—Constr Mater 163:157–165. https://doi.org/10.1680/coma.2010.163.3.157 CrossRefGoogle Scholar
- 22.Obuzor GN, Kinuthia JM, Robinson RB (2011) Enhancing the durability of flooded low-capacity soils by utilizing lime-activated ground granulated blastfurnace slag (GGBS). Eng Geol 123:179–186. https://doi.org/10.1016/j.enggeo.2011.07.009 CrossRefGoogle Scholar
- 23.Obuzor GN, Kinuthia JM, Robinson RB (2012) Soil stabilisation with lime-activated-GGBS-A mitigation to flooding effects on road structural layers/embankments constructed on floodplains. Eng Geol 151:112–119. https://doi.org/10.1016/j.enggeo.2012.09.010 CrossRefGoogle Scholar
- 24.Porbaha A (1998) State of the art in deep mixing technology: part I. Basic concepts and overview. Proc Inst Civ Eng—Gr Improv 2:81–92. https://doi.org/10.1680/gi.1998.020204 CrossRefGoogle Scholar
- 25.Pourakbar S, Asadi A, Huat BBK, Fasihnikoutalab MH (2015) Stabilization of clayey soil using ultrafine palm oil fuel ash (POFA) and cement. Transp Geotech 3:24–35. https://doi.org/10.1016/j.trgeo.2015.01.002 CrossRefGoogle Scholar
- 26.Provis JL (2014) Geopolymers and other alkali activated materials: why, how, and what? Mater Struct Constr 47:11–25CrossRefGoogle Scholar
- 27.Richardson IG, Brough AR, Groves GW, Dobson CM (1994) The characterization of hardened alkali-activated blast-furnace slag pastes and the nature of the calcium silicate hydrate (C-S-H) phase. Cem Concr Res 24:813–829. https://doi.org/10.1016/0008-8846(94)90002-7 CrossRefGoogle Scholar
- 28.Riemer P, Hendriks C, Ozawa Meida L et al (2007) Emission reduction of greenhouse gases from the cement industry. Greenhouse Gas Control Technol 4:939–944Google Scholar
- 29.Shi C, Day RL (1993) Chemical activation of blended cements made with lime and natural pozzolans. Cem Concr Res 23:1389–1396. https://doi.org/10.1016/0008-8846(93)90076-L CrossRefGoogle Scholar
- 30.Wang X, Tao J (2019) Polymer-modified microbially induced carbonate precipitation for one-shot targeted and localized soil improvement. Acta Geotech 14:657–671CrossRefGoogle Scholar
- 31.Wild S, Kinuthia JM, Jones GI, Higgins DD (1998) Effects of partial substitution of lime with ground granulated blast furnace slag (GGBS) on the strength properties of lime-stabilised sulphate-bearing clay soils. Eng Geol 51:37–53. https://doi.org/10.1016/S0013-7952(98)00039-8 CrossRefGoogle Scholar
- 32.Wild S, Kinuthia JM, Robinson RB, Humphreys I (2006) Effects of ground granulated blast furnace slag (GGBS) on the strength and swelling properties of lime-stabilized kaolinite in the presence of sulphates. Clay Miner 31:423–433. https://doi.org/10.1180/claymin.1996.031.3.12 CrossRefGoogle Scholar
- 33.Wu C, Chu J, Wu S et al (2019) Microbially induced calcite precipitation along a circular flow channel under a constant flow condition. Acta Geotech 14:673–683CrossRefGoogle Scholar
- 34.Yi Y, Liska M, Al-Tabbaa A (2013) Properties and microstructure of GGBS–magnesia pastes. Adv Cem Res 26:114–122. https://doi.org/10.1680/adcr.13.00005 CrossRefGoogle Scholar
- 35.Yi Y, Li C, Liu S, Al-Tabbaa a A (2014) Resistance of MgO–GGBS and CS–GGBS stabilised marine soft clays to sodium sulfate attack. Géotechnique 64:673–679. https://doi.org/10.1680/geot.14.t.012 CrossRefGoogle Scholar
- 36.Yi Y, Liska M, Al-Tabbaa A (2014) Properties of two model soils stabilized with different blends and contents of GGBS, MgO, lime, and PC. J Mater Civ Eng 26:267–274CrossRefGoogle Scholar
- 37.Yi Y, Gu L, Liu S, Puppala AJ (2015) Carbide slag–activated ground granulated blastfurnace slag for soft clay stabilization. Can Geotech J 52:656–663CrossRefGoogle Scholar
- 38.Yi Y, Zheng X, Liu S, Al-Tabbaa A (2015) Comparison of reactive magnesia- and carbide slag-activated ground granulated blastfurnace slag and Portland cement for stabilisation of a natural soil. Appl Clay Sci 111:21–26. https://doi.org/10.1016/j.clay.2015.03.023 CrossRefGoogle Scholar
- 39.Yi Y, Gu L, Liu S (2015) Microstructural and mechanical properties of marine soft clay stabilized by lime-activated ground granulated blastfurnace slag. Appl Clay Sci 103:71–76CrossRefGoogle Scholar