Science Bulletin

, Volume 60, Issue 16, pp 1391–1394 | Cite as

Oxidative cross-coupling: an alternative way for C–C bond formations

Progress Chemistry

Abstract

Coupling reaction usually refers to the direct C–C bond formation between two carbon fragments. Generally, cross-coupling reactions between nucleophiles and electrophiles have been extensively studied and become the classic model for bond constructions. Another reaction model, bond formation from two nucleophiles through oxidative cross-coupling, has received more and more attention over the past few years. This paper will discuss the concept of oxidative cross-coupling and give an overview of its recent development.

Keywords

Oxidative cross-coupling C–C bond formation Oxidant Nucleophile 

氧化交叉偶联:一种新型的构筑碳碳键的反应模式

摘要

偶联反应通常是指2个碳中心分子之间直接成键构筑碳碳键的过程。亲核试剂和亲电试剂的交叉偶联反应在20世纪就得到了广泛的研究,而这种成键模式目前已经成为构筑化学键的一种经典模式。然而,另外一种反应模式:即2个亲核试剂通过氧化交叉偶联的方式直接成键,在近些年来也得到了越来越多的关注。本文将就氧化交叉偶联反应的概念进行讨论,并对其近些年的发展做一个简单的总结。

关键词

氧化交叉偶联 碳碳成键 氧化剂 亲核试剂 

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Copyright information

© Science China Press and Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  1. 1.College of Chemistry and Molecular Sciences, The Institute for Advanced Studies (IAS)Wuhan UniversityWuhanChina

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