Effect of TMGa flux on GaN films deposited on Ti coated on glass substrates at low temperature
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Abstract
Highly c-axis-oriented GaN films were deposited on Ti coated glass substrates using low temperature electron cyclotron resonance plasma enhanced metal organic chemical vapor deposition system (ECR-PEMOCVD) with trimethyl gallium (TMGa) as gallium source. The influence of TMGa flux on the properties of GaN films were systematically investigated by reflection high energy electron diffraction (RHEED), X-ray diffraction analysis (XRD), atomic force microscopy (AFM) and Raman scattering. The GaN film with small surface roughness and high c-axis preferred orientation was successfully achieved at the optimized TMGa flux of 1.0 sccm. The ohmic contact characteristic between GaN and Ti layer was clearly demonstrated by the near-linear current-voltage (I–V) curve. The GaN/Ti/glass structure has great potential to dramatically improve the scalability and reduce the cost of solid-state lighting light emitting diodes.
Keywords
GaN low-temperature deposited glass substrates Ti film ECR-PEMOCVDReferences
- 1.Pearton S J, Ren F, Zhang A P, et al. Fabrication and performance of GaN electronic devices. Mater Sci Eng Rep, 2000, 30: 55–212CrossRefGoogle Scholar
- 2.Miyajima T, Tojyo T, Asano T, et al. GaN-based blue laser diodes. J Phys Cond Matter, 2001, 13: 7099–7114CrossRefGoogle Scholar
- 3.Chu C F, Lai F I, Chu J T, et al. Study of GaN light-emitting diodes fabricated by laser lift-off technique. J Appl Phys, 2004, 95: 3916–3922CrossRefGoogle Scholar
- 4.Wong W S, Kneissl M, Mei P, et al. Continuous-wave InGaN multiple-quantum-well laser diodes on copper substrates. Appl Phys Lett, 2001, 78: 1198–1200CrossRefGoogle Scholar
- 5.Inoue S, Okamoto K, Matsuki N, et al. Epitaxial growth of GaN on copper substrates. Appl Phys Lett, 2006, 88: 261910CrossRefGoogle Scholar
- 6.Mikulics M, Kocan M, Rizzi A, et al. Growth and properties of GaN and AlN layers on silver substrates. Appl Phys Lett, 2005, 87: 212109CrossRefGoogle Scholar
- 7.Zhang D, Bai Y Z, Qin F W, et al. Influence of N2 flux on the improvement of highly c-oriented GaN films on diamond substrates. Vacuum, 2011, 85: 725–729CrossRefGoogle Scholar
- 8.Feng Q H, Qin F W, Wu A M, et al. Low temperature deposition of poly-silicon thin films by ECR-PECVD. Semicond Tech, 2006, 5: 342–345Google Scholar
- 9.Hwang C Y, Schurman M J, Mayo W E, et al. Effect of structural defects and chemical impurities on hall mobilities in low pressure MOCVD grown GaN. J Electron Mater, 1997, 26: 243–251CrossRefGoogle Scholar
- 10.Akasaki I, Amano H, Koide M, et al. Conductivity control of GaN and fabrication of UV/blue GaN light emitting devices. Physica B, 1993, 185: 428–432CrossRefGoogle Scholar
- 11.Akasaki I, Amano H, Murakami H. Growth of GaN and AlGaN for UV/blue p-n junction diodes. J Cryst Growth, 1993, 128: 379–383CrossRefGoogle Scholar
- 12.Zhang D, Bai Y Z, Qin F W, et al. Deposition and properties of highly c-oriented GaN films on diamond substrates. Appl Phys A, 2011, 102: 353–358CrossRefGoogle Scholar
- 13.Patra A, Friend C S, Kapoor R, et al. Fluorescence upconversion properties of Er3+-doped TiO2 and BaTiO3 nanocrystallites. Chem Mater, 2003, 15: 3650–3655CrossRefGoogle Scholar
- 14.Perlin P, Itie J P, Miguel A S, et al. Raman scattering and X-ray-absorption spectroscopy in gallium nitride under high pressure. Phys Rev B, 1992, 45: 83–89CrossRefGoogle Scholar
- 15.Azuhata T, Sota T, Suzuki K, et al. Polarized Raman spectra in GaN. J Phys Cond Matter, 1995, 7: 129–133CrossRefGoogle Scholar
- 16.Kozawa T, Kachi T, Kano H, et al. Raman scattering from LO phonon-plasmon coupled modes in gallium nitride. J Appl Phys, 1994, 75: 1098–1101CrossRefGoogle Scholar
- 17.Yam F K, Hassan Z. Structural and optical characteristics of porous GaN generated by electroless chemical etching. Mater Lett, 2009, 63: 724–727CrossRefGoogle Scholar
- 18.Nemanich R J, Tsai C C, Connell G A N. Interference-enhanced Raman scattering of very thin titanium and titanium oxide films. Phys Rev Lett, 1980, 28: 273–276CrossRefGoogle Scholar
- 19.Foxon C T, Novikov S V, Campion R P, et al. The influence of As on the optimum nitrogen to gallium ratio required to grow high quality GaN films by molecular beam epitaxy. Phys Status Solidi b, 2001, 228: 219–222CrossRefGoogle Scholar