Chinese Science Bulletin

, Volume 56, Issue 23, pp 2416–2418 | Cite as

MFI-type zeolite membrane on hollow fiber substrate for hydrogen separation

Open Access
Letter Inorganic Chemistry
  • 590 Downloads

Abstract

High performance MFI-type zeolite membranes on the outer surface of α-Al2O3 hollow fibers were synthesized by secondary growth method using pure silica sol without an organic template. X-ray diffraction was used to characterize the phase structure of both the seed layer and zeolite membrane. The morphologies of the seed layer and zeolite membrane were examined by scanning electron microscopy. The zeolite membrane achieved an extraordinary H2/CO2 separation factor of 10 with a high H2 permeance of 5.56×10−7 mol m−2 s−1 Pa−1 at 723 K.

Keywords

MFI membrane α-Al2O3 hollow fiber H2 permeance separation factor 

References

  1. 1.
    Zhou M, Zhang B Q, Liu X F. Chinese Sci Bull, 2008, 53: 801–816CrossRefGoogle Scholar
  2. 2.
    Dong J H, Lin Y S, Kanezashi M, et al. J Appl Phys, 2008, 104: 121301–121317CrossRefGoogle Scholar
  3. 3.
    Dong Q, Huang P, Xu N P, et al. J Chem Engin Chinese Univ, 2001, 15: 179–182Google Scholar
  4. 4.
    Liu X F, Zhang B Q, Lin Y S. Synthesis of oriented MFI zeolite films by template-free secondary growth. Chin J Inorg Chem, 2008, 24: 1679–1685Google Scholar
  5. 5.
    Yuan W H, Lin Y S, Yang W S. atJ Am Chem Soc, 2004, 126: 4776–4777CrossRefGoogle Scholar
  6. 6.
    Lai Z P, Bonilla G, Diaz I, et al. Science, 2003, 300: 456–460Google Scholar
  7. 7.
    Wang Z B, Ge Q Q, Shao J, et al. J Am Chem Soc, 2009, 131: 6910–6911CrossRefGoogle Scholar
  8. 8.
    Caro J, Noack M. Microp Mesop Mater, 2008, 115: 215–233CrossRefGoogle Scholar
  9. 9.
    Pan M, Lin Y S. Microp Mesop Mater, 2001, 43: 319–327CrossRefGoogle Scholar
  10. 10.
    Tang Z, Dong J H, Nenoff T M. Langmuir, 2009, 25: 4848–4852CrossRefGoogle Scholar

Copyright information

© The Author(s) 2011

Open Access This article is distributed under the terms of the Creative Commons Attribution License which permits any use, distribution and reproduction in any medium, provided the original author(s) and source are credited.

Authors and Affiliations

  1. 1.School of Chemistry and Chemical EngineeringSouth China University of TechnologyGuangzhouChina
  2. 2.College of Environmental Science and EngineeringSouth China University of TechnologyGuangzhouChina

Personalised recommendations