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A novel 58-nuclei silver nanowheel encapsulating a subvalent Ag64+ kernel

  • Zhi Wang
  • Qing-Ping Qu
  • Hai-Feng Su
  • Peng HuangEmail author
  • Rakesh Kumar Gupta
  • Qing-Yun Liu
  • Chen-Ho Tung
  • Di SunEmail author
  • Lan-Sun Zheng
Communications
  • 32 Downloads

Abstract

The combination of CrO42− anion and N,N′-dimethylformamide (DMF)-containing solvent helps to stabilize an atom-precise ultrasmall Ag6 kernel into a 52-nuclei silver shell, giving a core-shell Ag6@Ag52 wheel-like structure (SD/Ag58b). The solution behavior and photocurrent response property were investigated in details.

Keyword

silver cluster subvalent Ag64+ kernel electrospray ionisation mass spectrometry (ESI-MS) photocurrent response 

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Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21822107, 21571115, 21827801, 21671172), the Natural Science Foundation of Shandong Province (JQ201803, ZR2017MB061), the Taishan Scholar Project of Shandong Province of China, the Qilu Youth Scholar Funding of Shandong University and the Fundamental Research Funds of Shandong University (104.205.2.5).

Supplementary material

11426_2019_9638_MOESM1_ESM.pdf (1.7 mb)
A novel 58-nuclei silver nanowheel encapsulating a subvalent Ag64+ kernel
11426_2019_9638_MOESM2_ESM.pdf (270 kb)
Supplementary material, approximately 272 KB.
11426_2019_9638_MOESM3_ESM.cif (3.1 mb)
Supplementary material, approximately 3.06 MB.

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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Zhi Wang
    • 1
  • Qing-Ping Qu
    • 1
  • Hai-Feng Su
    • 3
  • Peng Huang
    • 2
    Email author
  • Rakesh Kumar Gupta
    • 1
  • Qing-Yun Liu
    • 4
  • Chen-Ho Tung
    • 1
  • Di Sun
    • 1
    Email author
  • Lan-Sun Zheng
    • 3
  1. 1.Key Laboratory of Colloid and Interface Chemistry, Ministry of Education, School of Chemistry and Chemical Engineering, State Key Laboratory of Crystal MaterialsShandong UniversityJinanChina
  2. 2.Jiangsu Key Laboratory of Green Synthetic Chemistry for Functional Materials, Department of Chemistry, School of Chemistry and Chemical EngineeringJiangsu Normal UniversityXuzhouChina
  3. 3.State Key Laboratory for Physical Chemistry of Solid Surfaces and Department of Chemistry, College of Chemistry and Chemical EngineeringXiamen UniversityXiamenChina
  4. 4.College of Chemical and Environmental EngineeringShandong University of Science and TechnologyQingdaoChina

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