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Science China Chemistry

, Volume 62, Issue 4, pp 434–439 | Cite as

Photogenerated singlet oxygen over zeolite-confined carbon dots for shape selective catalysis

  • Qiu-Ying Yu
  • Guang-Yao Zhai
  • Tian-Lu Cui
  • Hui Su
  • Zhong-Hua Xue
  • Jun-Jun Zhang
  • Peter J. Pauzauskie
  • Shin-ichi Hirano
  • Xin-Hao Li
  • Jie-Sheng ChenEmail author
Articles
  • 35 Downloads

Abstract

Singlet oxygen as an activated oxygen species played an important role in organic synthesis. Suitable catalyst for converting ubiquitous oxygen molecule to singlet oxygen under mild conditions has attracted a wide range of attention. Herein, carbon dots have been confined into mesopores of silicalite-1 nanocrystals framework and acted as active sites for generation of singlet oxygen. The high oxygen-adsorption capacity of zeolite nanocrystals facilitated the photocatalytic generation rate of singlet oxygen, outpacing the free-standing carbon dots for 14-fold. The integrated carbon dot-zeolite nanocrystal hybrid also exhibited a special size-dependent selectivity for organic synthesis by using the in situ formed and confined singlet oxygen as active oxygen species.

Keywords

zeolite photocatalysis singlet oxygen carbon dots shape-selective 

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Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21720102002, 21722103, 21673140), Shanghai Basic Research Program (16JC1401600), SJTU-MPI partner group, Shanghai Eastern Scholar Program and Shanghai Rising-Star Program (16QA1402100). We thank Prof. Huan-Ming Xiong and his coworkers (Department of Chemistry, Fudan University, Shanghai 200433, China) for providing CD for this study.

Supplementary material

11426_2018_9417_MOESM1_ESM.pdf (2.8 mb)
Photogenerated singlet oxygen over zeolite-confined carbon dots for shape selective catalysis

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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Qiu-Ying Yu
    • 1
  • Guang-Yao Zhai
    • 1
  • Tian-Lu Cui
    • 1
  • Hui Su
    • 1
  • Zhong-Hua Xue
    • 1
  • Jun-Jun Zhang
    • 1
  • Peter J. Pauzauskie
    • 3
  • Shin-ichi Hirano
    • 2
  • Xin-Hao Li
    • 1
  • Jie-Sheng Chen
    • 1
    Email author
  1. 1.School of Chemistry and Chemical EngineeringShanghai Jiao Tong UniversityShanghaiChina
  2. 2.Hirano Institute for Materials InnovationShanghai Jiao Tong UniversityShanghaiChina
  3. 3.Department of Materials Science & EngineeringSeattleUSA

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