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Facile construction of two-dimensional coordination polymers with a well-designed redox-active organic linker for improved lithium ion battery performance

  • Jingwei Liu
  • Lin Zhang
  • Huanhuan Li
  • Peng Zhao
  • Peng Ren
  • Wei ShiEmail author
  • Peng ChengEmail author
Articles SPECIAL ISSUE: Dedicated to the 100th Anniversary of Nankai University
  • 11 Downloads

Abstract

A well-designed redox-active organic linker, pyrazine-2,3,5,6-tetracarboxylate (H4pztc) with brimming active sites for lithium ions storage was utilized to construct coordination polymers (CPs) via a facile hydrothermal reaction. Those two isostructural two-dimensional (2D) CPs, namely [M2(pztc)(H2O)6]n (M=Co for 1 and Ni for 2), delivered excellent reversible capacities and stable cycling performance as anodes in lithium ion batteries. As demonstrated in electrochemical studies, 1 and 2 can achieve highly reversible capacities of 815 and 536 mA h g−1 at 200 mA g−1 for 150 cycles, respectively, best performed for the reported 2D-CP-based anode materials. The electrochemical mechanism studies showed that the remarkable performances can be ascribed to the synergistic Li-storage redox reactions of metal centers and organic moieties. Our work highlights the opportunities of using a well-designed organic ligand to construct low-dimensional CPs as new type of electrode materials for advanced lithium ion batteries.

Keywords

two-dimensional coordination polymers anode materials lithium ion battery 

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Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21622105, 21501071, 21421001), Shenzhen Fundamental Research Project (JCYJ20160525164227350), the Ministry of Education of China (B12015), and the Natural Science Foundation of Tianjin (18JCJQJC47200).

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Facile construction of two-dimensional coordination polymers with a well-designed redox-active organic linker for improved lithium ion battery performance
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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Department of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry of Ministry of Education, College of ChemistryNankai UniversityTianjinChina
  2. 2.School of ScienceHarbin Institute of Technology (Shenzhen)ShenzhenChina
  3. 3.Collaborative Innovation Center of Chemical Science and Engineering (Tianjin)Nankai UniversityTianjinChina

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