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Science China Chemistry

, Volume 62, Issue 1, pp 80–86 | Cite as

Synthesis of 4H-chromenes by silver (I)-catalyzed cycloaddition of ortho-quinone methides with N-allenamides

  • Long Kong
  • Nuligonda Thirupathi
  • Jiong JiaEmail author
  • Zhenghu XuEmail author
Articles
  • 31 Downloads

Abstract

Chromenes represent an important class of six-membered heterocycles and have drawn tremendous attention in recent years. In this article, we report a convenient and practical synthesis of this heterocycle by a silver (I)-catalyzed cycloaddition reaction between in situ generated ortho-quinone methides and N-allenamides. Diverse 4H-chromenes were synthesized in good to excellent yields under very mild conditions.

Keywords

4H-chromene ortho-quinone methide N-allenamide silver-catalysis cycloaddition 

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Notes

Acknowledgements

This work was supported by the National Natural Science Foundation of China (21572118, 21750110444), the Natural Science Foundation of Shandong Province (ZR2018MB010), subject construction funds (104.205.2.5) and Tang scholar award of Shandong University.

Supplementary material

11426_2018_9359_MOESM1_ESM.pdf (601 kb)
Supplementary material, approximately 601 KB.
11426_2018_9359_MOESM2_ESM.pdf (3.9 mb)
Synthesis of 4H-chromenes by silver(I)-catalyzed cycloaddition of ortho-quinone methides with N-allenamides

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Copyright information

© Science China Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Key Laboratory for Colloid and Interface Chemistry of Education Ministry, Department of ChemistryShandong UniversityJinanChina
  2. 2.State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic ChemistryChinese Academy of SciencesShanghaiChina

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