Science China Chemistry

, Volume 59, Issue 4, pp 482–486 | Cite as

A simple catalyst for aqueous phase Suzuki reactions based on palladium nanoparticles immobilized on an ionic polymer

  • Saeideh Ghazali-Esfahani
  • Emilia Păunescu
  • Mojtaba Bagherzadeh
  • Zhaofu Fei
  • Gabor Laurenczy
  • Paul J. Dyson
Articles
  • 138 Downloads

Abstract

Palladium nanoparticles immobilized on a cross-linked imidazolium-containing polymer were evaluated as a catalyst for Suzuki carbon-carbon cross-coupling reactions using water as the solvent. The nanocatalysts show good catalytic activities for aryl iodides and aryl bromides and moderate activity with aryl chloride substrates. Coupling of sterically hindered substrates could also be achieved in reasonable yields. The heterogeneous catalyst is stable, can be stored without precautions to exclude air or moisture, and can be easily recycled and reused.

Keywords

catalysis biphasic catalysis polymeric ionic liquids nanoparticles aqueous phase catalysis Suzuki reaction 

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Copyright information

© Science China Press and Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  • Saeideh Ghazali-Esfahani
    • 1
    • 2
  • Emilia Păunescu
    • 1
  • Mojtaba Bagherzadeh
    • 2
  • Zhaofu Fei
    • 1
  • Gabor Laurenczy
    • 1
  • Paul J. Dyson
    • 1
  1. 1.Institut des Sciences et Ingénierie ChimiquesEcole Polytechnique Fédérale de LausanneLausanneSwitzerland
  2. 2.Chemistry DepartmentSharif University of TechnologyTehranIran

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