Science China Chemistry

, Volume 59, Issue 4, pp 436–441 | Cite as

Visible and near-infrared luminescence of polycatenated cationic pyridinone lanthanide networks

Articles

Abstract

A series of isomorphic lanthanide coordination polymers [Ln(III)(MBP)2(NO3)2(Br)·2C3H6O] [Ln=Eu, Tb, Er, Yb, and Gd; MBP=N,N′-methylene-bis(pyridin-4-one)] featuring polycatenated sql cationic network and incorporated bromide counter ion were prepared. Their visible and near-infrared (NIR) luminescence properties were characterized by steady-state excitation and emission spectra, as well as luminescence lifetimes and quantum yields. The D2d dodecahedron coordination geometry causes visible light excitations and strongly monochromatic emissions. The external heavy-atom environment induces remarkable enhancement on the NIR emissions. The sensitization processes are revealed by analyzing the electronic properties of MBP ligand.

Keywords

coordination network lanthanide pyridinone luminescence 

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References

  1. 1.
    Bünzli JCG, Piguet C. Soc Rev, 2005, 34: 1048–1077CrossRefGoogle Scholar
  2. 2.
    Woodruff DN, Winpenny REP, Layfield RA. Chem Rev, 2013, 113: 5110–5148CrossRefGoogle Scholar
  3. 3.
    Long DL, Blake AJ, Champness NR, Schröder M. Chem Commun, 2000, 1369–1370Google Scholar
  4. 4.
    Reineke TM, Eddaoudi M, Moler D, O’Keeffe M, Yaghi OM. J Am Chem Soc, 2000, 122: 4843–4844CrossRefGoogle Scholar
  5. 5.
    Allendorf MD, Bauer CA, Bhakta RK, Houk RJT. Chem Soc Rev, 2009, 38: 1330–1352CrossRefGoogle Scholar
  6. 6.
    Alexandrov EV, Blatov VA, Proserpio DM. Acta Cryst, 2012, A68: 484–493CrossRefGoogle Scholar
  7. 7.
    Eliseevaa SV, Bünzli JCG. Chem Soc Rev, 2010, 39: 189–227CrossRefGoogle Scholar
  8. 8.
    Eliseevaa SV, Bünzli JCG. New J Chem, 2011, 35: 1165–1176CrossRefGoogle Scholar
  9. 9.
    Rocha J, Carlos LD, Almeida Paz FA, Ananias D. Chem Soc Rev, 2011, 40: 926–940CrossRefGoogle Scholar
  10. 10.
    Artizzu F, Mercuri ML, Serpe A, Deplano P. Coord Chem Rev, 2011, 255: 2514–2529CrossRefGoogle Scholar
  11. 11.
    Shu YB, Tang XL, Liu WS. Inorg Chem Front, 2014, 1: 226–230CrossRefGoogle Scholar
  12. 12.
    King RB. J Am Chem Soc, 1969, 91: 7211–7216CrossRefGoogle Scholar
  13. 13.
    Bünzli JCG, Eliseeva SV. Basics of lanthanide photophysics. In: Hänninen P, Härmä H. Lanthanide Luminescence: Photophysical, Analytical and Biological Aspects. Berlin Heidelberg: Springer, 2011. 1–46Google Scholar
  14. 14.
    Miyata K, Nakagawa T, Kawakami R, Kita Y, Sugimoto K, Nakashima T, Harada T, Kawai T, Hasegawa Y. Chem Eur J, 2011, 17: 521–528CrossRefGoogle Scholar
  15. 15.
    Liu F, Fang Y, Zhang N, Hou J, Ma Z, Zhao G. Ceram Int, 2014, 40: 14781–14786CrossRefGoogle Scholar
  16. 16.
    Peng Y, Ye H, Li Z, Motevalli M, Hernández I, Gillin WP, Wyatt PB. J Phys Chem Lett, 2014, 5: 1560–1563CrossRefGoogle Scholar
  17. 17.
    Werts MHV, Duin MA, Hofstraat JW, Verhoeven JW. Chem Commun, 1999: 799–800Google Scholar
  18. 18.
    Park OH, Seo SY, Bae BS, Shin JH. Appl Phys Lett, 2003, 82: 2787–2789CrossRefGoogle Scholar
  19. 19.
    Deun RV, Fias P, Driesen K, Binnemans K, Görller-Walrand C. Phys Chem Chem Phys, 2003, 5: 2754–2757CrossRefGoogle Scholar
  20. 20.
    McGlynn SP, Sunseri R, Christodouleas N. J Chem Phys, 1962, 37: 1818–1824CrossRefGoogle Scholar
  21. 21.
    McGlynn SP, Daigre J, Smith FJ. J Chem Phys, 1963, 39: 675–679CrossRefGoogle Scholar
  22. 22.
    Yang C, Fu LM, Wang Y, Zhang JP, Wong WT, Ai XC, Qiao YF, Zou BS, Gui LL. Angew Chem Int Ed, 2004, 43: 5010–5013CrossRefGoogle Scholar
  23. 23.
    Dexter DL. J Chem Phys, 1953, 21: 836–850CrossRefGoogle Scholar
  24. 24.
    Latva M, Takalo H, Mukkala VM, Matachescu C, Rodriguez-Ubis JC, Kankare J. J Lumin, 1997, 75: 149–169CrossRefGoogle Scholar
  25. 25.
    Arnaud N, Georges J. Spectrochim Acta, Part A, 2003, 59: 1829–1840CrossRefGoogle Scholar
  26. 26.
    Klink SI, Grave L, Reinhoudt DN, van Veggel FCJM. J Phys Chem A, 2000, 104: 5457–5468CrossRefGoogle Scholar

Copyright information

© Science China Press and Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  1. 1.Key Laboratory of Nonferrous Metals Chemistry and Resources Utilization of Gansu Province; State Key Laboratory of Applied Organic Chemistry; College of Chemistry and Chemical EngineeringLanzhou UniversityLanzhouChina

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