Science China Chemistry

, Volume 59, Issue 1, pp 114–121 | Cite as

Phase transitions in two organic salts based on 1,5-naphthalenedisulfonate

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Abstract

Two phase transition compounds, diethylammonium 1,5-naphthalenedisulfonate (1) and cyclohexylammonium 1,5-naphthalenedisulfonate (2), were screened from a series of organic salts based on 1,5-naphthalenedisulfonate. The phase transition behaviors were studied by differential scanning calorimetry, single-crystal X-ray analysis and dielectric measurements. Compounds 1 and 2 undergo phase transitions at about 202 and 148 K, respectively, accompanied by distinct dielectric changes. The origin of the phase transitions was ascribed to motional changes of the cations in the crystal lattices.

Keywords

phase transition dielectric constant naphthalenedisulfonate organic salt 
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Copyright information

© Science China Press and Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  1. 1.Ordered Matter Science Research CenterSoutheast UniversityNanjingChina

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