Science China Chemistry

, Volume 55, Issue 9, pp 1982–1987 | Cite as

Numerical analysis and experimental study of hydrogen production from dimethyl ether steam reforming

Articles

Abstract

An experimental and theoretical study of steam reforming of dimethyl ether was carried out in a processor for fuel cell vehicles to explore the effect of temperature gradient and hydrogen content of the processor. A steady-state, laminar, two-dimensional axi-symmetric model was proposed to investigate the fluid flow, heat transfer and chemical reactions in the dimethyl ether steam reforming processor using porous medium approach. The numerical model was established with Star-CD program using SIMPLE algorithm and finite volume method. Experimental verification of the two-dimensional mathematical model was conducted. The numerical results coincided well with the experimental data. The effects of the parameters on the temperature gradient and hydrogen content of the processor were studied using the numerical model.

Keywords

hydrogen steam reforming simulation 

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    Wu GP, Chen T, Zhou GH, Zong X, Li C. H2 production with low CO selectivity from photocatalytic reforming of glucose on metal/TiO2 catalysts. Sci China Ser B: Chem, 2008, 51(2): 97–100CrossRefGoogle Scholar
  2. 2.
    Li M, Zhou Z, Li YF, Shen PW. Computational investigation and design of nanostructured hydrogen storage materials. Sci China Ser B: Chem, 2009, 39(9): 971–976Google Scholar
  3. 3.
    Takeishi K, Suuki, H. Steam reforming of dimethyl ether. Appl Catal A, 2004, 260: 111–117CrossRefGoogle Scholar
  4. 4.
    Wang SZ, Ishihara T, Takita I, Yusaku T. Partial oxidation of dimethyl ether over various supported metal catalysts. Appl Catal A, 2002, 228: 167–176CrossRefGoogle Scholar
  5. 5.
    Zhang QJ. Li XH, Kaoru F, Kenji A. Hydrogen production from partial oxidation and reforming of DME. Catal Lett, 2005, 102: 197–200CrossRefGoogle Scholar
  6. 6.
    Hemmes K, Patil A. Flexible coproduction of hydrogen and power using internal reforming solid oxide fuel cells system. J Fuel cell Sci Technol, 2008, 12(5): 1–5Google Scholar
  7. 7.
    Park J, Bae J, Lee S. Numerical analysis of a steam reformer coupled with a combustion burner. J Fuel Cell Sci Technol, 2010, 7: 1–6Google Scholar
  8. 8.
    Zhang QJ. Hydrogen production by partial oxidation and reforming of DME. Appl Catal A, 2005, 288: 169–174CrossRefGoogle Scholar
  9. 9.
    Tanaka Y, Kikuchi E, Takeguchi T, Eguchi K. Steam reforming of dimethyl ether over composite catalysts of Al2O3 and Cu-based spinel. Appl Catal B, 2005, 57: 211–222CrossRefGoogle Scholar
  10. 10.
    Galvita VV, Semin GL, Belyaev VD, Yurieva TM, Sobyanin VA. Production of hydrogen from dimethyl ether. Appl Catal A, 2001, 216: 85–90CrossRefGoogle Scholar
  11. 11.
    Semelsberger TA, Brown LF, Borup RL, Inbody MA. Equilibrium products from auto thermal processes for generating hydrogen-rich fuel-cell feeds. J Power Soures, 2004, 32(3): 1047–1064Google Scholar
  12. 12.
    Wang XL, Pan XM, Lin R, Kou SY. Dmiethyl ether steam reforming for hydrogen production over Cu-Ni/Γ-Al2O3 Bi-functional catalyst. Acta Phys-Chim Sin, 2010, 26(5): 1296–1304Google Scholar
  13. 13.
    Choi Y, Stenger HS. Kinetics, simulation and optimization of methanol steam reformer for fuel cell applications. J Power Sources, 2005, 142: 81–91CrossRefGoogle Scholar
  14. 14.
    Stamps AT. Gatzke EP. Dynamic modeling of a methanol reforming — PEMFC stack system for analysis and design. J Power Sources, 2006, 161(1): 356–370CrossRefGoogle Scholar
  15. 15.
    Lin ST, Chen YH, Yu CC, Liu YC, Lee CH. Dynamic modeling and control structure design of an experimental fuel processor. J Hydrogen Ener, 2006, 31(3):413–426CrossRefGoogle Scholar
  16. 16.
    Kawabata T, Matsuoka H, Shishido T, Li D, Tian Y, Sano T, Takehira K. Steam reforming of dimethyl ether over ZSM-5 coupled with Cu/ZnO/Al2O3 catalyst prepared by homogeneous precipitation. Appl Catal A: Gen, 2006, 308: 82–90CrossRefGoogle Scholar
  17. 17.
    Semelsberger TA, Ott KC, Borup RL, Greene HL. Generating hydrogen-rich fuel-cell feeds from dimethyl ether (DME) using physical mixtures of a commercial Cu/Zn/Al2O3 catalyst and several solid-acid catalysts. Appl Catal B: Environ, 2005, 286: 11–22CrossRefGoogle Scholar
  18. 18.
    Faungnawakij K, Tanaka Y, Shimoda N, Fukunaga T, Kikuchi R, Eguchi K. Hydrogen production from dimethyl ether steam reforming over composite catalysts of copper ferrite spinel and alumina. Appl Catal B: Environ, 2007, 74: 144–151CrossRefGoogle Scholar
  19. 19.
    Feng DM, Wang YY, Wang DZ, Wang JF. Steam reforming of dimethyl ether over CuO-ZnO-Al2O3-ZrO2/ZSM-5: A kinetic study. Chem Engin J, 2009, 146(3): 477–485CrossRefGoogle Scholar
  20. 20.
    Dokamaingam P, Assabumrungrat S, Soottitantawat A, Sramala I, Laosiripojana N. Modeling of SOFC with indirect internal reforming operation: Comparison of conventional packed-bed and catalytic coated-wall internal reformer. J Hydrogen Energy, 2009, 34: 410–421CrossRefGoogle Scholar
  21. 21.
    Joonguen P, Shinku L, Sungkang L, Joongmyeon B. Heat flux analysis of a cylindrical steam reformer by a modified Nusselt number. J Hydrogen Energy, 2009, 34(3): 1–7Google Scholar

Copyright information

© Science China Press and Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  1. 1.College of Automobile EngineeringShanghai University of Engineering ScienceShanghaiChina

Personalised recommendations