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Science China Chemistry

, Volume 53, Issue 9, pp 1953–1956 | Cite as

One-step selective synthesis of branched 1-O-alkyl-glycerol/diglycerol monoethers by catalytic reductive alkylation of ketones

  • Yan Shi
  • Wissam Dayoub
  • Guo-Rong Chen
  • Marc Lemaire
Articles

Abstract

Branched 1-O-alkyl glycerol and diglycerol monoethers were obtained in good yields and high selectivity by a straightforward catalytic reductive alkylation of glycerol with relevant ketones in the presence of 0.5 mol% of Pd/C under 10 bar of hydrogen pressure using a Brønsted acid as the co-catalyst.

Keywords

glycerol monoether diglycerol monoether 1-O-alkylation Pd/C reduction 

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Copyright information

© Science China Press and Springer-Verlag Berlin Heidelberg 2010

Authors and Affiliations

  • Yan Shi
    • 1
    • 2
  • Wissam Dayoub
    • 2
  • Guo-Rong Chen
    • 1
  • Marc Lemaire
    • 2
  1. 1.Laboratory for Advanced Materials and Institute of Fine ChemicalsEast China University of Science and TechnologyShanghaiChina
  2. 2.Laboratoire de Catalyse Synthèse et Environnement, Institut de Chimie et Biochimie Moléculaires et Supramoléculaires (ICBMS), CNRS, UMR5246Université Lyon 1VilleurbanneFrance

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