Journal of Soils and Sediments

, Volume 15, Issue 7, pp 1571–1583 | Cite as

Naturally elevated metal contents of soils in northeastern North Dakota, USA, with a focus on cadmium

  • Vijaya Jyoti
  • Bernhardt Saini-Eidukat
  • David Hopkins
  • Thomas DeSutter
Soils, Sec 4 • Ecotoxicology • Research Article

Abstract

Purpose

Association of element concentrations for the escarpment soils of northeastern North Dakota formed from different geologic parent materials was determined based on geochemical data. These soils overlie the Cretaceous Pierre Formation, and parent materials consist of shale rich glacial till, residual shale, and colluvial materials.

Materials and methods

Samples were analyzed for cadmium and other trace elements using nitric acid digestion followed by optical emission spectroscopy. Morphologic and laboratory analysis of soil cores indicate high clay content, indicative of the influence of shale residuum on the parent materials of the escarpment soils.

Results and discussion

An average, cadmium concentration of 0.24 ± 0.22 mg/kg was determined for 136 samples from eight (approx. 2.4 m deep) cores. The concentration of molybdenum had a range between 0.00 and 7.99 mg/kg. Zinc levels determined in the samples had a wide range between 18.76 and 128.02 mg/kg. Principal component analysis revealed that elevated trace element concentrations for the shale-rich portion of the soils in northeastern North Dakota are linked to a variety of factors including organic matter content, pH, elevation, and electrical conductivity.

Conclusions

Results of this study suggest that erosion and transport of Cretaceous shales downslope on the escarpment have resulted in enriched trace element concentrations in the soils.

Keywords

Cadmium Elevated Natural North Dakota Soil 

Supplementary material

11368_2015_1122_MOESM1_ESM.docx (31 kb)
Table A.1(DOCX 30 kb)

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Copyright information

© Springer-Verlag Berlin Heidelberg 2015

Authors and Affiliations

  • Vijaya Jyoti
    • 1
  • Bernhardt Saini-Eidukat
    • 2
  • David Hopkins
    • 3
  • Thomas DeSutter
    • 3
  1. 1.School for the EnvironmentUniversity of Massachusetts BostonBostonUSA
  2. 2.Department of GeosciencesNorth Dakota State UniversityFargoUSA
  3. 3.Department of Soil ScienceNorth Dakota State UniversityFargoUSA

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