Abstract
Nuclear, biological, and chemical warfare (NBC) agents cause an inevitable threat to defense forces and civilians. Exposure to these toxic agents causes a lot of damage to lives. One can avoid the damage of these toxic agents by taking appropriate preventive measures. Respiratory protection is obviously necessary when military personnel or civilians get bounded by such type of noxious situation as contaminant-free air is then required for breathing and it can only be provided by means of a proper gas mask and relevant canister. In purification of contaminated atmospheres, activated carbon has so far met with outstanding success. It removes toxic chemicals either by chemical or physical adsorption from the contaminated air. When any toxic chemicals get adsorbed on the modified impregnated carbon’s surface, they usually adsorb there by means of chemical reactions. Destruction of adsorbed toxic substances is expected by such a reactive carbon. In this perspective, an attempt has been made to review the literature from past decades on the removal of toxic chemical warfare agents (CWAs) and radioactive content from air stream in case of any nuclear, biological, and chemical attack by selectively modifying or impregnating the activated carbon surface. This review also covers some important adsorption properties of materials being used in gas mask filters for effective removal of chemicals from airstream. The probable removal mechanisms of various chemical warfare agents and radioactive content have also been reviewed.
Similar content being viewed by others
References
Abha SS, Beer S, Mamta S, Suryanarayana MVS, Semwal RP, Ganesan KS (2006) In-situ degradation of sulphur mustard and its simulants on the surface of impregnated carbon systems. J Hazard Mater B 133:106–112
Altintig E, Kirkil S (2016) Preparation and properties of Ag-coated activated carbon nanocomposites produced from wild chestnut shell by ZnCl2 activation. J Taiwan Inst Chem Eng 63:180–188
Alves BR, Clark AJ (1986) An examination of the products formed on reaction of hydrogen cyanide and cyanogen with copper, chromium (6+) and copper-chromium (6+) impregnated activated carbons. Carbon 24(3):287–294
Baker FS et al (1992) Encyclopedia. 1015:4
Barker ME (1926) Gas mask development. Chem Warfare 12(7):11–15
Beer S, Prasad GK (1999) A new method of preparation of Cu, Cr and Ag impregnated carbon. In Proceedings of National Symposium on Carbon, NPL, Delhi
Beer S et al (2001) The reaction of thiodiglycol on metal impregnated carbon. Carbon 39(14):2131–2142
Beguin HPF (1993) The effects of molybdenum on stabilizing the performance of an experimental copper/zinc impregnated, activated carbon. Letters to the Editor
Biron E, Stavisky R (1995) Deactivation of ASC whetlerite charcoal upon adsorption of cyanogen chloride. Carbon 33(10):1413–1416
Blacet FE (1943) Preparation of a protective adsorbent carbon. US Patent 516314
Blacet FE (1960) Whetlerite product and process. US Patent 51960
Bradley RH (1995) Surface studies of cu/Cr/ag impregnated microporous carbons. J Appl Surf Sci 90:271–276
Burgess JA (1902) Method of purifying acetylene. US Patent 701995
Caplon (1930) Preparation of protective adsorbent carbon. US Patent 1771396
Chiang HL et al (2000) Adsorption characteristics of alkaline activated carbon exemplified by water vapor, H2S, and CH3SH gas. Sep Sci Technol 35(6):903–918
Davey J (1992) Proc. of the 4th Int. Symp. on Protection against Chemical Warfare Agents, Stockholm (Sweden)
David MH (1932) Process for the manufacture of highly actuated adsorptive carbons. US patent 1,849,503
Deitz VR (1987) Interaction of radioactive iodine gaseous species with nuclear-grade activated carbons. Carbon. 25(1):31–38
Derbyshire F, Thwaites M, Patrick JW (1995) Porosity in carbons. Edward Arnold, London
Dhawan R et al (2017) Influence of metal impregnants on adsorption of dimethylsulfide vapors by activated carbons. Mater Today 4(9):10515–10519
Dittrich (1940) Whetlerite product and process. US Patent 2212593
Doughty DT (1991) Chromium free impregnated Activated carbon for adsorption of toxic Gases US Patent 5063196
Doughty DT et al (1996) Chromium free impregnated activated universal respirator carbon for adsorption of toxic gases and/or vapors in industrial applications. US Patent 5492882
Dubinin MM (1955) Surface oxides and adsorption properties of activated carbons. Uspekhi Khim 24:3
Dubinin MM (1965) Contemporary state of the theory of volume filling of micropores of adsorbents on the adsorption of gases and vapours on carbon adsorbents. Zhur fiz Khim 39(6):1305–1317
Dubinin MM, Plavnik GM (1968) Microporous structures of carbonaceous adsorbents. Carbon 6(2):183–192
Dubinin MM, Zaverina ED, Timofeyev DP (1949) Sorption and structure of active carbons.VI. The structure types of active carbons. Zhur fiz Khim 23:1129–1140
Ecob CM et al (1993) Effect of humidity on the trapping of radioiodine by impregnated carbons. Sci Total Environ 131:419–427
Ehrburger PD, Dziedzinl J, Fangeat R (1990) Thermal behaviour of chromium trioxide deposited on carbons. Carbon 28(1):113–118
Emmet PH (1948) Adsorption and pore size measurements on charcoals and whetlerites. Chem Rev 43:69–148
Fortier H (2007) The science of impregnation and the optimization of the performance of impregnated activated carbons for gas mask applications. Ph.D Thesis Department of Chemistry, Dalhousie University, Halifax, Nova Scotia
Friday DK (1988) The breakthrough behaviour of a light gas in a fixed-bed adsorption reactor. AIChE Symp Ser 84(264):89–93
Frund (1998) Respirator filter system. US Patent 5714126
Gall RD (1997) Destruction of thioether of mustard analogue by divanado decamolybdophosphonic acid. Chem Abstr 126:224933
González-García CM, González JF, Román S (2011) Removal efficiency of radioactive methyl iodide on TEDA-impregnated activated carbons. Fuel Process Technol 92(2):247–252
Groose et al (1985) Sublimation of amine compounds on activated carbon pore surfaces. US Patent 4531953
Harry M (2006) Activated carbon. Elsevier Ltd, Oxford
Hinds WC (1999) Aerosol technology: properties, behaviour and measurement of airborne particles, 2nd edn. Wiley’s, New York
Ho K et al (2019a) Design of highly efficient adsorbents for removal of gaseous methyl iodide using tertiary amine-impregnated activated carbon: integrated experimental and first-principles approach. Chem Eng J 373:1003–1011
Ho K, Moon S, Lee HC, Hwang YK, Lee CH (2019b) Adsorptive removal of gaseous methyl iodide by triethylenediamine (TEDA)-metal impregnated activated carbons under humid conditions. J Hazard Mater 368:550–559
Ho K et al (2020) Adsorption mechanism of methyl iodide by triethylenediamine and quinuclidine-impregnated activated carbons at extremely low pressures. Chem Eng J 396:125215
Inagaki M, Tascon JMD (2006) Pore formation and control in carbon materials. In: T.J. Bandosz, ed. Activated Carbon Surfaces in Environmental Remediation. Interf Sci Technol Elsevier, San Diego 7:49–105
Jonas LA, Rehrmann JA (1972) The kinetics of adsorption of organo phosphorous vapours from air mixtures by activated carbons. Carbon 10:657–663
Jonas LA, Rehrmann JA (1973) Predictive equations in gas adsorption kinetics. Carbon 11(1):59–64
Jonas LA, Rehrmann JA (1974) The rate of gas adsorption by activated carbon. Carbon 12(2):95–101
Jonas LA et al (1985) The effect of moisture on the adsorption of chloroform by activated carbon. J Am Ind Hyg Assoc 46:20–23
Kaiser et al (2008) Chromium free universal respirator carbon. US Patent 7425521
Karwacki CJB et al (1999) Effect of temperature on the desorption and decomposition of mustard from activated carbon. Langmuir 8645-8650
Keith CH et al (1967) Process of impregnating adsorbent materials with metal oxides. United States, Liggett & Myers Tobacco Co
Kiani SS, Faiz Y, Farooq A, Ahmad M, Irfan N, Nawaz M, Bibi S (2020) Synthesis and adsorption behavior of activated carbon impregnated with ASZM-TEDA for purification of contaminated air. Diam Relat Mater 108:107916
Kiani SS, Farooq A, Faiz Y, Shah A, Ahmad M, Irfan N, Iqbal M, Usman AB, Mahmood A, Nawaz M, Bibi S, Aziz A (2021) Investigation of Cu/Zn/Ag/Mo-based impregnated activated carbon for the removal of toxic gases, synthesized in aqueous media. Diam Relat Mater 111:108179
Kitani S, Noro T, Kohara T (1972) Removal of methyl iodide by impregnated charcoals from flowing air under humid condition. J Nucl Sci Technol 9:197–202
Kluczka J, Trojanowska J, Zolotajkin M, Ciba J, Turek M, Dydo P (2007) Boron removal from wastewater using adsorbents. Environ Technol 28(1):105–113
Latimer (1944) Impregnated carbons and process of making the same. US Patent 519383
Liang (1995) Organic amine impregnated activated carbon. US Patent 5462908
Liu E, Sarkar B, Chen Z, Naidu R (2016) Decontamination of chlorine gas by organic amine modified copper-exchanged zeolite. Microporous Mesoporous Mater 225:450–455
Mattson JS, Mark HB (1971) Activated carbon, surface chemistry and adsorption from solution. Marcel Dekker Inc, New York
McEnaney B (1988) Adsorption and structure in microporous carbons. Carbon 26(3):267–274
Mitsumoria N (1977) Method of treating silver impregnated activated carbon. US Patent 4045553
Morrell JC (1950) Preparation of a protective adsorbent carbon. US Patent 2511288
Morrison RW (2001) Research and technology directorate. Chemical Biological Centre, USA
Muntz L (1902) Respirator. US Patent 703948
Nelson GO, Correia AN (1976) Respirator cartridge efficiency studies: VIII. Summary and conclusions. Am Ind Hyg Assoc J 37(9):514–525
Nickolov RN (2004) Comparative study on removal efficiency of impregnated carbons for hydrogen cyanide vapors in air depending on their phase composition and porous textures. J Colloid Interface Sci 273:87–94
Ninomiya N et al (1980) Removal of nitrogen oxides. United States Patent 4210628
Nishino H et al (1986) Method for removal of poisonous gases. Takeda Chemical Industries, Ltd. (Osaka, JP): United States Patent 4594231
Norris J, Fowler W (1997) NBC: nuclear, biological, and chemical warfare on the modern battlefield. Brasseys UK Limited
Noyes WAJ (1946) Military problems with aerosols and non-persistent gases. Summary Technical report of the National Defence Research Committee (NDRC), Division 10. Washington NDRC: 40-168
Oliver TCM (2005) Synthetic activated carbons for the removal of hydrogen cyanide from air. J Chem Eng Process 44:1181–1187
Park SW, Park HS, Lee WK, Moon H (1995) Effect of water vapor on adsorption of methyl iodide to triethylenediamine-impregnated activated carbons. Sep Technol 5(1):35–44
Park GI et al (2001) Effect of temperature on the adsorption and desorption characteristics of methyl iodide over TEDA-impregnated activated carbon. Carbon Lett 2(1):9–14
Peter L (2006a) Adsorption of chemical warfare agents In: T.J. Bandosz, ed. Activated Carbon Surfaces in Environmental Remediation. Interf Sci Technol Elsevier, San Diego 7:475–528
Peter L (2006b) Modelling gas phase adsorption in industrial and military applications. Springer, Dordrecht
Peterson GW, Rossin JA, Smith PB, Wagner GW (2010) Effects of water on the removal of methyl bromide using triethylene diamine impregnated carbon. Carbon. 48(1):81–88
Poziomek EJ, Mackay RA, Barrett RP (1975) Electron spin resonance studies with copper/silver/chromium impregnated charcoals. Carbon. 13(4):259–262
Prasad GK (2003) Studies on adsorption of toxic chemicals on carbon. Doctoral Thesis
Prasad GK, Beer S (2004) Reactions of sulphur mustard on impregnated carbons. J Hazard Mater 116(3):213–217
Prasad GK, Singh B (2006) Breakthrough behaviour of sulphur mustard vapour on whetlerite carbon. J Hazard Mater 137(1):277–281
Prasad GK et al (2005) Kinetics of degradation of sulphur mustard on impregnated carbons. J Hazard Mater 121(1):159–165
Prasad GK, Mahato TH, Yadav SS, Singh B (2007a) Sulphur mustard vapor breakthrough behaviour on reactive carbon systems. J Hazard Mater 143(1):150–155
Prasad GK et al (2007b) Breakthrough behaviour of sulphur mustard on activated carbon. J Sci Ind Res 143(1–2):150–155
Prasad GK, Beer S, Vijayaraghavan R (2008) Respiratory protection against chemical and biological warfare agents. Def Sci J 58:686–697
Raymundo-Piñero E, Cazorla-Amorós D, Linares-Solano A (2003) The role of different nitrogen functional groups on the removal of SO2 from flue gases by N-doped activated carbon powders and fibres. Carbon 41(10):1925–1932
Rehrmann JA, Jonas LA (1978) Dependence of gas adsorption rates on carbon granule size and linear flow velocity. Carbon 16(1):47–51
Reucroft PJ, Rao PB, Freeman GB (1983) Binary vapor adsorption by activated carbon. Carbon 21(3):171–176
Roman S (2011) Removal efficiency of radioactive iodide on TEDA impregnated activated carbon. J Fuel Process Technol 92:247–252
Romero JV et al (2013) Evolution of the SO2 and NH3 gas adsorption properties of CuO/ZnO/Mn3O4and CuO/ ZnO/NiO ternary impregnated activated carbon using combinatorial materials science methods. J. Am Chem Soc 15:101–110
Rossin JA, Morrison RW (1991) Spectroscopic analysis and performance of an experimental copper/zinc impregnated, activated carbon. Carbon 29(7):887–892
Rossin JA, Morrison RW (1993) The effects of molybdenum on stabilizing the performance of an experimental copper/zinc impregnated, activated carbon. Carbon 31(4):657–659
Rossin JA, Petersen E, Tevault D, Lamontagne R, Isaacson L (1991) Effects of environmental weathering on the properties of ASC-whetlerite. Carbon 29(2):197–205
Schwenk M (2018) Chemical warfare agents. Classes and targets. Toxicol Lett 293:253–263
Sharma A, Saxena A, Singh B, Suryanarayana MVS, Ganeshan K, Sekhar K, Dwivedi KK (2006) Development and evaluation of modified whetlerite, an adsorbent material for in situ degradation of sulphur mustard. Carbon 44(5):907–912
Sing KS (1989) The use of physisorption for the characterization of microporous carbons. Carbon 27(1):5–11
Smisek M, Cerny S (1970) Active carbon, manufacture,properties and applications. Elsevier Publishing Co, New York
Smith SJ, Hern JA (2002) Broad spectrum filter system for filtering contaminants from air or other gases. US Patent 6344071
Smith JWH, Westreich P, Croll LM, Reynolds JH, Dahn JR (2009) Understanding the role of each ingredient in a basic copper carbonate based impregnation recipe for respirator carbons. J Colloid Interface Sci 337(2):313–321
Smith JWH, Westreich P, Abdellatif H, Filbee-Dexter P, Smith AJ, T.E.Wood, Croll LM, Reynolds JH, Dahn JR (2010) The investigation of copper-based impregnated activated carbons prepared from water-soluble materials for broad spectrum respirator applications. J Hazard Mater 180(1):419–428
Smith JWH, Romero JV, Dahn TR, Dunphy K, Sullivan B, Mallay M, Croll LM, Reynolds JH, Andress C, Dahn JR (2011) The effect of heating temperature and nitric acid treatments on the performance of Cu- and Zn-based broad spectrum respirator carbons. J Colloid Interface Sci 364(1):178–194
Stoeckli HF (1990) Microporous carbons and their characterization: the present state of the art. Carbon 28(1):1–6
Tolles (1989) Method and apparatus for removal HCN, CNCl and CN2 from air. US Patent 4801311
Van Der S (1987) Air cleaning material for use in air filters. US patent 4677096
Waitt AH (1941) Gas warfare. In The chemical weapon, its use, and protection against it. Little & Ives Company, New York
Waters WA, Williams JH (1950) Hydrolyses and derivatives of some vesicant arsenicals. J Chem Soc (Resumed) 18-22
Wigg EO, Morse NL (1960) Whetlerite product and process. US Patent 2920051
Williams MC, Steel RJ (1985) Gas! The battle for Ypres. Vanwell Publishing company Limited, Deyell Co, Canada
Wilson RE, Whetzel JC (1924) US Patent 1519470
Wood GO (1981) Respirator canister testing for radioiodine. Am Ind Hyg Assoc J 42(8):570–578
Wood GO (1985) Effects of air temperatures and humidities on efficiencies and lifetimes of air purifying chemical respirator cartridges tested against methyl iodide. Am Ind Hyg Assoc J 46(5):251–256
Wu LC, Chung YC (2009) Replacement of hazardous chromium impregnating agent from silver/copper/chromium impregnated active carbon using tri-ethylene diamine to remove hydrogen sulfide, trichloro methane, ammonia and sulfur dioxide. J Air Waste Manage Assoc 59(3):258–262
Wu LC, Chang TH, Chung YC (2007) Removal of hydrogen sulfide and sulfur dioxide by carbons impregnated with TEDA. J Air Waste Manage Assoc 57:1461–1468
Zeng H, Jin F, Guo J (2004) Removal of elemental mercury from coal combustion flue gas by chloride-impregnated activated carbon. Fuel 83(1):143–146
Zhou J, Hao S, Gao L, Zhang Y (2014) Study on adsorption performance of coal based activated carbon to radioactive iodine and stable iodine. J Ann Nuclear Energy 72:237–241
Author information
Authors and Affiliations
Contributions
Sidra Shaoor Kiani: data collection, writing-original draft preparation
Amjad Farooq: idea of writing review paper, full guidance, literature review
Masroor Ahmad: instructions
Naseem Irfan: instructions
Mohsan Nawaz: instructions
Muhammad Asim Irshad: assistance
Corresponding author
Ethics declarations
Ethics approval and consent to participate
Not applicable.
Consent for publication
Not applicable.
Conflict of interest
The authors declare no competing interests.
Additional information
Responsible Editor: Philippe Garrigues
Publisher’s note
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.
Rights and permissions
About this article
Cite this article
Kiani, S.S., Farooq, A., Ahmad, M. et al. Impregnation on activated carbon for removal of chemical warfare agents (CWAs) and radioactive content. Environ Sci Pollut Res 28, 60477–60494 (2021). https://doi.org/10.1007/s11356-021-15973-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-021-15973-1