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Improving ozonation to remove carbamazepine through ozone-assisted catalysis using different NiO concentrations

  • Claudia M. Aguilar
  • Jorge Vazquez-Arenas
  • Omar O. Castillo-Araiza
  • Julia L. RodríguezEmail author
  • Isaac Chairez
  • Eric Salinas
  • Tatiana Poznyak
Advanced Oxidation Processes: Recent Achievements and Perspectives
  • 22 Downloads

Abstract

The carbamazepine (CBZ) abatement is herein evaluated using catalytic ozonation at different NiO concentrations as catalyst: 100, 300, and 500 mg L−1, revealing its total destruction after 5 min of reaction either by conventional or catalytic ozonation. The NiO incorporation in the reactor does not increase the destruction rate, but the catalyst presence enhances the partial mineralization of the contaminant by conversion into oxalic and formic acids and the removal of total organic carbon (TOC) associated with the formation of oxidant species such as hydroxyl radical. Evidence for this behavior is the accumulation rate of the above acids which rise proportionally to the NiO concentration. The highest NiO concentration (500 mg L−1) reached a maximum TOC removal of 79.2%, which exceeds by 50% the outcome of the conventional treatment. The accumulation-decomposition profiles of oxalic and formic acids suggest the occurrence of simultaneous reaction mechanisms (hydroxyl radicals and complex formations) on the catalyst during CBZ ozonation. According to XPS analysis, the presence of nitrogen species in the NiO-ozonated was attributable to byproducts of CBZ decomposition. The toxicity bioassay based on Lactuca sativa seeds demonstrate that ozonated samples attained similar plant germination than the reference substance (water) after 120 min of treatment. This result is comparable with or without the catalyst presence, indicating the formation of non-toxic accumulated byproducts at the end of the ozonation reaction.

Keywords

Carbamazepine Catalytic ozonation Hydroxyl radicals NiO Lactuca sativa toxicity 

Notes

Acknowledgments

C. Aguilar thanks CONACYT for the economic support to pursue postdoctoral studies.

Funding information

This work is Apoyado por el Fondo Sectorial de Investigación para la Educación (CONACYT Projects: A1-S-21608, A1-S-30591) and Instituto Politécnico Nacional (SIP projects: 20191559, 20195237, 20191745).

Supplementary material

11356_2020_7883_MOESM1_ESM.docx (27 kb)
ESM 1 (DOCX 26 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2020

Authors and Affiliations

  1. 1.Laboratory of Catalytic Reactor Engineering applied to Chemical and Biological Systems (LCRE). Departamento de Ingeniería de Procesos e HidráulicaUniversidad Autónoma Metropolitana-ItzapalapaCiudad de MexicoMexico
  2. 2.Conacyt - Departamento de QuímicaUniversidad Autónoma Metropolitana - IztapalaCiudad de MexicoMexico
  3. 3.Lab. Ing. Química AmbientalESIQIE-Instituto Politécnico NacionalCiudad de MexicoMexico
  4. 4.Departamento de BioprocesosUPIBI-Instituto Politécnico NacionalCiudad de MexicoMexico

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