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A simple magnetic solid-phase extraction method based on magnetite/graphene oxide nanocomposite for pre-concentration and determination of melamine by high-performance liquid chromatography

  • Hossein Abdolmohammad-ZadehEmail author
  • Abbasali Zamani
  • Zahra Shamsi
Research Article
  • 24 Downloads

Abstract

In this study, a clean and simple magnetic solid-phase extraction (MSPE) procedure using magnetite/graphene oxide nanocomposite as an adsorbent was developed for melamine separation and preconcentration from water and dairy products. After synthesis and characterization of the adsorbent, adsorption isotherms and kinetic studies of the adsorption were carried out. The analyte quantification was performed by reversed phase high-performance liquid chromatography after elution of the preconcentrated analytes from the adsorbent surface. Several factors affecting the extraction/preconcentration procedure such as pH, adsorbent amount, extraction time, sample volume, type, and volume of eluent were investigated. The optimizing of some important parameters was assessed by employing a response surface method. The constructed calibration curve in the optimized conditions is linear in the working range of 0.10–100 μg L−1 with a correlation coefficient of 0.9999. The detection limit, limit of quantification, and enrichment factor are 0.03 μg L−1, 0.10 μg L−1, and 500, respectively. The melamine relative recoveries from different real samples are between 97.20 and 103.10% with relative standard deviations of 1.07–4.98%.

Keywords

Food analysis Magnetic adsorbent Counterfeit compounds Experimental design Magnetic extraction Water and dairy products 

Notes

Funding information

The authors are thankful to the Research Council of Azarbaijan Shahid Madani University (Grant no. ASMU/98372-19) and Department of Environmental Science of the University of Zanjan for supporting of this project.

Supplementary material

11356_2020_7681_MOESM1_ESM.docx (530 kb)
ESM 1 (DOCX 530 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2020

Authors and Affiliations

  1. 1.Analytical Spectroscopy Research Lab., Department of Chemistry, Faculty of SciencesAzarbaijan Shahid Madani UniversityTabrizIran
  2. 2.Department of Environmental Science, Faculty of SciencesUniversity of ZanjanZanjanIran

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