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Photocatalytic degradation of dye by Ag/TiO2 nanoparticles prepared with different sol–gel crystallization in the presence of effluent organic matter

  • Hongyu Deng
  • Huan HeEmail author
  • Shijie Sun
  • Xintong Zhu
  • Dongxu Zhou
  • Fengxia HanEmail author
  • Bin Huang
  • Xuejun Pan
Research Article
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Abstract

TiO2 nanoparticle-doped Ag (Ag/TNPs) have good photocatalytic properties based on localized surface plasmon resonance (LSPR) effect. The effluent organic matter (EfOM) can be easily activated by photo-excitation to promote pollutant photodegradation, but excessive EfOM has an inactive effect. Herein, the purpose of this paper is to investigate the changes of photocatalytic performance by Ag/TNPs in the presence of EfOM. Three Ag/TNPs made by condensation crystallization or rotary evaporation crystallization using the sol–gel method were conducted in photocatalytic degradation of methyl orange (MO). The Ag/TNPs crystallized by condensation had greater separation rate of photogenerated electron–hole pairs and photocatalytic degradation of MO with high load rates of binding Ag and TiO2 than those formed by rotary evaporation crystallization. Indeed, EfOM could be excited to produce the active substances under illumination resulting in the promotion of MO degradation. However, contrary to previous speculation, no additive effect of MO photodegradation was observed with the addition both of EfOM and Ag/TNPs at different pH values (5~9) and ion strength (0~0.4 mol L−1). It can be explained that the EfOM changed the morphology and active sites in Ag/TNPs’ surface. Meanwhile, EfOM could be consumed and degraded by Ag/TNP photocatalysis leading to the concentration of free radicals to decrease. This study revealed a nonsynergistic effect between nanomaterial and EfOM for photocatalysis. EfOM would have a negative effect on photocatalytic degradation of organic compounds by Ag/TNPs in the aquatic environment.

Graphical abstract

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Keywords

Effluent organic matter Photocatalytic degradation Titanium dioxide Silver Water treatment Methyl orange 

Notes

Funding information

The research was sponsored by China’s National Natural Science Foundation (grants 51878321, 21866017, and 41761092), by the Applied Fundamental Research Foundation of Yunnan Province (grant 2018FA007), and by the China Scholarship Council Fund (project 201808530511).

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflicts of interest.

References

  1. Bensouici F, Souier T, Dakhe AA, Iratni A, Tala-Ighil R, Bououdina M (2015) Synthesis, characterization and photocatalytic behavior of Ag doped TiO2 thin film. Superlattice Microst 85:255–265CrossRefGoogle Scholar
  2. Brame J, Long M, Li Q, Alvarez P (2015) Inhibitory effect of natural organic matter or other background constituents on photocatalytic advanced oxidation processes: mechanistic model development and validation. Water Res 84:362–731CrossRefGoogle Scholar
  3. Chen W, Westerhoff P, Leenheer JA, Booksh K (2003) Fluorescence excitation-emission matrix regional integration to quantify spectra for dissolved organic matter. Environ Sci Technol 37:5701–5710CrossRefGoogle Scholar
  4. Chen K, Feng X, Hu R, Li Y, Xie K, Li Y, Gu H (2013) Effect of Ag nanoparticle size on the photoelectrochemical properties of Ag decorated TiO2 nanotube arrays. J Alloys Compd 554:72–79CrossRefGoogle Scholar
  5. Demirci S, Öztürk B, Yildirim S, Bakal F, Erol M, Sancakoglu O, Yigit R, Celik E, Batar T (2015) Synthesis and comparison of the photocatalytic activities off lame spray pyrolysis and sol–gel derived magnesium oxide nano-scale particles. Mater Sci Semicond Process 34:154–161CrossRefGoogle Scholar
  6. Demirci S, Dikici T, Yurddaşkal M, Gültekin S, Toparlı M, Çelik E (2016) Synthesis and characterization of Ag doped TiO2 heterojunction films and their photocatalytic performances. Appl Surf Sci 390:591–601CrossRefGoogle Scholar
  7. Dong X, Sun Z, Zhang X, Li C, Zheng S (2018) Construction of BiOCl/g-C3N4/kaolinite composite and its enhanced photocatalysis performance under visible-light irradiation. J Taiwan Inst Chem E 84:203–211CrossRefGoogle Scholar
  8. Esmaei-lizare M, Salavati-niasari M, Sobhani A (2012) Simple sonochemical synthesis and characterization of HgSe nanoparticles. Ultrason Sonochem 19:1079–1086CrossRefGoogle Scholar
  9. Gao Y, Fang P, Liu Z, Chen F, Liu Y, Wang D (2013) A facile one-pot synthesis of layered protonated titanate nanosheets loaded with silver nanoparticles with enhanced visible-light photocatalytic performance. Chem Asian J 8:204–211CrossRefGoogle Scholar
  10. Gora SL, Andrews SA (2017) Adsorption of natural organic matter and disinfection byproduct precursors from surface water on TiO2 nanoparticles: pH effects, isotherm modelling and implications for using TiO2 for drinking water treatment. Chemosphere 174:363–370CrossRefGoogle Scholar
  11. Goudarzi M, Mir N, Mousavi-Kamazani M, Bagheri S, Salavati-Niasari M (2016) Biosynthesis and characterization of silver nanoparticles prepared from two novel natural precursors by facile thermal decomposition methods. Sci Rep-UK 6:32539CrossRefGoogle Scholar
  12. Guillén-Santiago A, Mayén SA, Torres-Delgado G, Castanedo-Pérez R, Maldonado A, Olvera MDLL (2010) Photocatalytic degradation of methylene blue using undoped and Ag-doped TiO2 thin films deposited by a sol–gel process: effect of the ageing time of the starting solution and the film thickness. Mater Sci Eng B-Adv: B 174:84–87CrossRefGoogle Scholar
  13. Gupta SM, Tripathi M (2011) A review of TiO2 nanoparticles. Chin Sci Bull 56:1639CrossRefGoogle Scholar
  14. He X, Cai Y, Zhang H, Liang C (2011) Photocatalytic degradation of organic pollutants with Ag decorated free-standing TiO2 nanotube arrays and interface electrochemical response. J Mater Chem 21:475–480CrossRefGoogle Scholar
  15. He C, Yu Y, Hu X, Larbot A (2002) Influence of silver doping on the photocatalytic activity of titania films. Appl Surf Sci 200:239–247CrossRefGoogle Scholar
  16. He H, Huang B, Gu L, Xiong D, Lai C, Tang J, Pan X (2016) Stimulated dissolved organic matter by electrochemical route to produce activity substances for removing of 17α-ethinylestradiol. J Electroanal Chem 780:233–240CrossRefGoogle Scholar
  17. Hosse M, Wilkinson KJ (2001) Determination of electrophoretic mobilities and hydrodynamic radii of three humic substances as a function of pH and ionic strength. Environ Sci Technol 35:4301–4306CrossRefGoogle Scholar
  18. Jia Y, Ye L, Kang X, You H, Wang S, Yao J (2016) Photoelectrocatalytic reduction of perchlorate in aqueous solutions over Ag doped TiO2 nanotube arrays. J Photoch Photobio A 328:225–232CrossRefGoogle Scholar
  19. Kanagaraj T, Thiripuranthagan S (2017) Photocatalytic activities of novel SrTiO3–BiOBr heterojunction catalysts towards the degradation of reactive dyes. Appl Catal B Environ 207:218–232CrossRefGoogle Scholar
  20. Kim S, Cho H, Joo H, Her N, Han J, Yi K, Yoon J (2017) Evaluation of performance with small and scale-up rotating and flat reactors: photocatalytic degradation of bisphenol A, 17β-estradiol, and 17α-ethynyl estradiol under solar irradiation. J Hazard Mater 336:21–32CrossRefGoogle Scholar
  21. Lal S, Link S, Halas NJ (2007) Nano-optics from sensing to waveguiding. Nat Photonics 1:641–650CrossRefGoogle Scholar
  22. Lei XF, Xue XX, Yang H (2014) Preparation and characterization of Ag-doped TiO2 nanomaterials and their photocatalytic reduction of Cr(VI) under visible light. Appl Surf Sci 321:396–403CrossRefGoogle Scholar
  23. Li X, Hou Y, Zhao Q, Chen G (2011) Synthesis and photoinduced charge-transfer properties of a ZnFe2O4-sensitized TiO2 nanotube array electrode. Langmuir 27:3113–3120CrossRefGoogle Scholar
  24. Li H, Gao Y, Wu X, Lee PH, Shih K (2017) Fabrication of heterostructured g-C3N4/Ag-TiO2 hybrid photocatalyst with enhanced performance in photocatalytic conversion of CO2 under simulated sunlight irradiation. Appl Surf Sci 402:198–207CrossRefGoogle Scholar
  25. Li H, Shen L, Zhang K, Sun B, Ren L, Qiao P (2018) Surface plasmon resonance-enhanced solar-driven photocatalytic performance from Ag nanoparticle-decorated self-floating porous black TiO2 foams. Appl Catal B Environ 220:111–117CrossRefGoogle Scholar
  26. Lu D, Fang P, Liu X, Zhai S, Li C, Zhao X, Xiong R (2015) A facile one-pot synthesis of TiO2-based nanosheets loaded with MnxOy nanoparticles with enhanced visible light-driven photocatalytic performance for removal of Cr (VI) or RhB. Appl Catal B Environ 179:558–573CrossRefGoogle Scholar
  27. Loeb SK, Alvarez PJ, Brame JA, Cates EL, Choi W, Crittenden J, Sedlak DL (2018) The technology horizon for photocatalytic water treatment: sunrise or sunset? Environ Sci Technol 53:2937–2947CrossRefGoogle Scholar
  28. Mayer KM, Hafner JH (2011) Localized surface plasmon resonance sensors. Chem Rev 111:3828–3857CrossRefGoogle Scholar
  29. Michael-Kordatou I, Michael C, Duan X, He X, Dionysiou DD, Mills MA (2015) Dissolved effluent organic matter: characteristics and potential implications in wastewater treatment and reuse applications. Water Res 77:213–248CrossRefGoogle Scholar
  30. Mir N, Salavati-Niasari M, Davar F (2012) Preparation of ZnO nanoflowers and Zn glycerolate nanoplates using inorganic precursors via a convenient rout and application in dye sensitized solar cells. Chem Eng J 181–182:779–789CrossRefGoogle Scholar
  31. Mojgan G, Fatemeh A, Salavati-Niasari M (2016) Simple synthesis-controlled fabrication of thallium cadmium iodide nanostructures via a novel route and photocatalytic investigation in degradation of toxic dyes. Inorg Chim Acta 455:88–97Google Scholar
  32. Mostafa S, Rosario-Ortiz FL (2013) Singlet oxygen formation from wastewater organic matter. Environ Sci Technol 47:8179–8186CrossRefGoogle Scholar
  33. Mubeen S, Hernandez-Sosa G, Moses D, Lee J, Moskovits M (2011) Plasmonic photosensitization of a wide band gap semiconductor: converting plasmons to charge carriers. Nano Lett 11:5548–5552CrossRefGoogle Scholar
  34. O’Connor M, Helal SR, Latch DE, Arnold WA (2019) Quantifying photo-production of triplet excited states and singlet oxygen from effluent organic matter. Water Res 156:23–33CrossRefGoogle Scholar
  35. Prakash J, Kumarx J, Harris RA, Swart C, Neethling JH, van Vuuren AJ (2016) Synthesis, characterization and multifunctional properties of plasmonic Ag-TiO2 nanocomposites. Nanotechnology 27:355–357CrossRefGoogle Scholar
  36. Ren D, Huang B, Yang B, Chen F, Pan X, Dionysiou DD (2017) Photobleaching alters the photochemical and biological reactivity of humic acid towards 17α-ethynylestradiol. Environ Pollut 220:1386–1393CrossRefGoogle Scholar
  37. Shah MSAS, Zhang K, Park AR, Kim KS, Park NG, Park JH, Yoo PJ (2013) Single-step solvothermal synthesis of mesoporous Ag-TiO2-reduced graphene oxide ternary composites with enhanced photocatalytic activity. Nanoscale 5:5093–5101CrossRefGoogle Scholar
  38. Shi H, Yu Y, Zhang Y, Feng X, Zhao X, Tan H (2017) Polyoxometalate/TiO2/Ag composite nanofibers with enhanced photocatalytic performance under visible light. Appl Catal B Environ 221:280–289CrossRefGoogle Scholar
  39. Sim LC, Leong KH, Ibrahim S, Saravanan P (2014) Graphene oxide and Ag engulfed TiO2 nanotube arrays for enhanced electron mobility and visible-light-driven photocatalytic performance. J Mater Chem A 2:5315–5322CrossRefGoogle Scholar
  40. Spadavecchia F, Cappelletti G, Ardizzone S, Bianchi CL, Cappelli S, Oliva C, Scardi P, Fermo P (2010) Solar photoactivity of nano-N-TiO2 from tertiary amine: role of defects and paramagnetic species. Appl Catal B 96:314–322CrossRefGoogle Scholar
  41. Sun L, Li J, Wang C, Li S, Lai Y, Chen H (2009) Ultrasound aided photochemical synthesis of Ag loaded TiO2 nanotube arrays to enhance photocatalytic activity. J Hazard Mater 171:1045–1050CrossRefGoogle Scholar
  42. Takai A, Kamat PV (2011) Shuttling photogenerated electrons across TiO2–silver interface. ACS Nano 5:7369–7376CrossRefGoogle Scholar
  43. Viana MM, Mohallem NDS, Miquita DR, Balzuweit K, Silva-Pinto E (2013) Preparation of amorphous and crystalline Ag/TiO2 nanocomposite thin films. Appl Surf Sci 265:130–136CrossRefGoogle Scholar
  44. Wang X, Blackford M, Prince K, Caruso RA (2012a) Preparation of boron-doped porous titanium networks containing gold nanoparticles with enhanced visible-light photocatalytic activity. ACS Appl Mater Interfaces 4:476–482CrossRefGoogle Scholar
  45. Wang Q, Yang X, Liu D, Zhao J (2012b) Fabrication, characterization and photocatalytic properties of Ag nanoparticles modified TiO2 NTs. J Alloys Compd 527:106–111CrossRefGoogle Scholar
  46. Wenk J, Von Gunten U, Canonica S (2011) Effect of dissolved organic matter on the transformation of contaminants induced by excited triplet states and the hydroxyl radical. Environ Sci Technol 45:1334–1340CrossRefGoogle Scholar
  47. Xie K, Sun L, Wang C, Lai Y, Wang M, Chen H, Lin C (2010) Photoelectrocatalytic properties of Ag nanoparticles loaded TiO2 nanotube arrays prepared by pulse current deposition. Electrochim Acta 55:7211–7218CrossRefGoogle Scholar
  48. Xin B, Jing L, Ren Z, Wang B, Fu H (2005) Effects of simultaneously doped and deposited Ag on the photocatalytic activity and surface states of TiO2. J Phys Cem B 109:2805–2809CrossRefGoogle Scholar
  49. Yola ML, Eren T, Atar N (2014) A novel efficient photocatalyst based on TiO2 nanoparticles involved boron enrichment waste for photocatalytic degradation of atrazine. Chem Eng J 250:288–294CrossRefGoogle Scholar
  50. Yu S, Zhang Y, Dong F, Li M, Zhang T, Huang H (2018) Readily achieving concentration tunable oxygen vacancies in Bi2O2CO3: triple-functional role for efficient visible-light photocatalytic redox performance. Appl Catal B Environ 226:441–450CrossRefGoogle Scholar
  51. Zanini GP, Avena MJ, Fiol S, Arce F (2006) Effects of pH and electrolyte concentration on the binding between a humic acid and an oxazine dye. Chemosphere 63:430–439CrossRefGoogle Scholar
  52. Zinatloo-Ajabshir S, Salavati-Niasari M (2016) Facile route to synthesize zirconium dioxide (ZrO2) nanostructures: structural, optical and photocatalytic studies. J Mol Liq 216:545–551CrossRefGoogle Scholar
  53. Zinatloo-Ajabshir S, Morassaei MS, Niasari MS (2017) Facile fabrication of Dy2Sn2O7-SnO2 nanocomposites as an effective photocatalyst for degradation and removal of organic contaminants. J Colloid Interface Sci 497:298–308CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Hongyu Deng
    • 1
  • Huan He
    • 1
    • 2
    Email author
  • Shijie Sun
    • 1
  • Xintong Zhu
    • 1
  • Dongxu Zhou
    • 1
  • Fengxia Han
    • 1
    Email author
  • Bin Huang
    • 1
    • 3
  • Xuejun Pan
    • 1
    • 3
  1. 1.Faculty of Environmental Science and EngineeringKunming University of Science and TechnologyKunmingPeople’s Republic of China
  2. 2.Environmental Engineering and Science Program, Department of Chemical and Environmental EngineeringUniversity of CincinnatiCincinnatiUSA
  3. 3.Yunnan Provincial Key Laboratory of Carbon Sequestration and Pollution Control in SoilsKunmingPeople’s Republic of China

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