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Synthesis and characteristics of a novel FeNi3/SiO2/TiO2 magnetic nanocomposites and its application in adsorption of humic acid from simulated wastewater: study of isotherms and kinetics

  • Fateme Akbari
  • Maryam Khodadadi
  • Ayat Hossein PanahiEmail author
  • Ali Naghizadeh
Research Article
  • 19 Downloads

Abstract

The presence of natural organic matter such as humic acid in water creates various problems in water purification. Humic acid can react with chlorine in the disinfection step and lead to the production of trihalomethanes and haloacetic acids that these compounds have carcinogenic and mutagenic properties; therefore, they must be removed before arriving to the disinfection stage. The purpose of this research was adsorption of humic acid from simulated wastewater by synthesized FeNi3/SiO2/TiO2 magnetic nanocomposites. FeNi3/SiO2/TiO2 magnetic nanocomposites were synthesized by sol-gel procedure and its characteristics were determined by TEM, VSM, BET, FESEM, and XRD techniques. Then, the effects of such pH (3–11), FeNi3/SiO2/TiO2 dosage (0.005–0.1 g/L), contact time (0–200 min), and initial concentration (2–15 mg/L) were studied on humic acid adsorption using FeNi3/SiO2/TiO2. The results of adsorption experiments revealed that the highest percentage of humic acid removal (94.4%) was achieved at pH 3, initial concentration of 5 ppm, FeNi3/SiO2/TiO2 dose of 0.1 g/L, and contact time of 90 min. The analyses of experimental isotherm data showed that the humic acid adsorption was described by Langmuir model and also the kinetic studies represented that the process of adsorption of humic acid on FeNi3/SiO2/TiO2 was followed by the pseudo-second kinetic. According to the results, it can be concluded that FeNi3/SiO2/TiO2 magnetic nanocomposites have a high ability to absorb humic acid from simulated wastewater.

Keywords

FeNi3/SiO2/TiO2 magnetic nanocomposites Humic acid Adsorption Isotherm Kinetics 

Notes

Acknowledgments

The authors appreciate the Vice President for Research and Technology of Birjand University of Medical Sciences for funding this study.

References

  1. Ang W, Mohammad AW et al (2015) Hybrid chitosan/FeCl3 coagulation–membrane processes: performance evaluation and membrane fouling study in removing natural organic matter. Sep Purif Technol 152:23–31CrossRefGoogle Scholar
  2. Bazrafshan E, Balarak D et al (2016) Fluoride removal from aqueous solutions by cupricoxide nanoparticles. Fluoride 49(3):233Google Scholar
  3. Bazrafshan E, Sobhanikia M et al (2017) Chromium biosorption from aqueous environments by mucilaginous seeds of Cydonia oblonga: kinetic and thermodynamic studies. Global Nest J 19(2):269–277CrossRefGoogle Scholar
  4. Dehghani MH, Faraji M, Mohammadi A, Kamani H (2017) Optimization of fluoride adsorption onto natural and modified pumice using response surface methodology: isotherm, kinetic and thermodynamic studies. Korean J Chem Eng 34(2):454–462CrossRefGoogle Scholar
  5. Derakhshani E, Naghizadeh A (2018) Optimization of humic acid removal by adsorption onto bentonite and montmorillonite nanoparticles. J Mol Liq 259:76–81CrossRefGoogle Scholar
  6. Dong C, Chen W, Liu C (2014a) Preparation of novel magnetic chitosan nanoparticle and its application for removal of humic acid from aqueous solution. Appl Surf Sci 292:1067–1076CrossRefGoogle Scholar
  7. Dong C, Chen W, Liu C, Liu Y, Liu H (2014b) Synthesis of magnetic chitosan nanoparticle and its adsorption property for humic acid from aqueous solution. Colloids Surf A Physicochem Eng Asp 446:179–189CrossRefGoogle Scholar
  8. Esmaeili H, Ebrahimi A et al (2012) Kinetic and isotherm studies of humic acid adsorption onto iron oxide magnetic nanoparticles in aqueous solutions. Int J Environ Health Eng 1(1):33CrossRefGoogle Scholar
  9. Giasuddin AB, Kanel SR et al (2007) Adsorption of humic acid onto nanoscale zerovalent iron and its effect on arsenic removal. Environ Sci Technol 41(6):2022–2027CrossRefGoogle Scholar
  10. Hamid N, Ismail A et al (2011) Morphological and separation performance study of polysulfone/titanium dioxide (PSF/TiO2) ultrafiltration membranes for humic acid removal. Desalination 273(1):85–92CrossRefGoogle Scholar
  11. Jayalath S, Wu H, Larsen SC, Grassian VH (2018) Surface adsorption of Suwannee River humic acid on TiO2 nanoparticles: a study of pH and particle size. Langmuir 34(9):3136–3145CrossRefGoogle Scholar
  12. Khodadadi M, Ehrampoush M et al (2018a) FeNi3@ SiO2 magnetic nanocomposite as a highly efficient Fenton-like catalyst for humic acid adsorption and degradation in neutral environments. Desalin Water Treat 118:258–267Google Scholar
  13. Khodadadi M, Ehrampoush M et al (2018b) Synthesis and characterizations of FeNi3@ SiO2@ TiO2 nanocomposite and its application in photo-catalytic degradation of tetracycline in simulated wastewater. J Mol Liq 255:224–232CrossRefGoogle Scholar
  14. Khodadadi M, Al-Musawi TJ, Kamranifar M et al (2019) A comparative study of using barberry stem powder and ash as adsorbents for adsorption of humic acid. Environ Sci Pollut Res 26:26159 CrossRefGoogle Scholar
  15. Korotta-Gamage SM, Sathasivan A (2017) A review: potential and challenges of biologically activated carbon to remove natural organic matter in drinking water purification process. Chemosphere 167:120–138CrossRefGoogle Scholar
  16. Lee P, Sun D et al (2007) Adsorption and photodegradation of humic acids by nano-structured TiO2 for water treatment. J Adv Oxid Technol 10(1):72–78Google Scholar
  17. Lin K-YA, Chang H-A (2015) Efficient adsorptive removal of humic acid from water using zeolitic imidazole framework-8 (ZIF-8). Water Air Soil Pollut 226(2):10CrossRefGoogle Scholar
  18. Liu J, Huang H, Huang R, Zhang J, Hao S, Shen Y, Chen H (2016) Mechanisms of CPB modified zeolite on mercury adsorption in simulated wastewater. Water Environ Res 88(6):490–499CrossRefGoogle Scholar
  19. Lu Z, Zhao X, Zhu Z, Yan Y, Shi W, Dong H, Ma Z, Gao N, Wang Y, Huang H (2015) Enhanced recyclability, stability, and selectivity of CdS/C@ Fe3O4 nanoreactors for orientation photodegradation of ciprofloxacin. Chem Eur J 21(51):18528–18533CrossRefGoogle Scholar
  20. Mahvi AH, Mohammadi M et al (2016) Sodium dodecyl sulfate modifed-zeolite as a promising adsorbent for the removal of natural organic matter from aqueous environments. Health Scope 5(1):11–18CrossRefGoogle Scholar
  21. Matilainen A, Sillanpää M (2010) Removal of natural organic matter from drinking water by advanced oxidation processes. Chemosphere 80(4):351–365CrossRefGoogle Scholar
  22. Naghizadeh A, Ghafouri M (2017) Synthesis and performance evaluation of chitosan prepared from Persian Gulf shrimp shell in removal of reactive blue 29 dye from aqueous solution (isotherm, thermodynamic and kinetic study). Iran J Chem Chem Eng (IJCCE) 36(3):25–36Google Scholar
  23. Naghizadeh A, Ghafouri M, Jafari A (2017) Investigation of equilibrium, kinetics and thermodynamics of extracted chitin from shrimp shell in reactive blue 29 (RB-29) removal from aqueous solutions. Desalin Water Treat 70:355–363CrossRefGoogle Scholar
  24. Nasseh N, Taghavi L, Barikbin B, Nasseri MA (2018) Synthesis and characterizations of a novel FeNi3/SiO2/CuS magnetic nanocomposite for photocatalytic degradation of tetracycline in simulated wastewater. J Clean Prod 179:42–54CrossRefGoogle Scholar
  25. Panahi AH, Ashrafi SD, Kamani H, Khodadadi M, Lima EC, Mostafapour FK, Mahvi AH (2019) Removal of cephalexin from artificial wastewater by mesoporous silica materials using Box-Behnken response surface methodology. Desalin Water Treat 159:169–180CrossRefGoogle Scholar
  26. Paul B, Parashar V et al (2015) Graphene in the Fe 3 O 4 nano-composite switching the negative influence of humic acid coating into an enhancing effect in the removal of arsenic from water. Environ Sci 1(1):77–83Google Scholar
  27. Qin J-J, Oo MH et al (2006) Impact of coagulation pH on enhanced removal of natural organic matter in treatment of reservoir water. Sep Purif Technol 49(3):295–298CrossRefGoogle Scholar
  28. Rao P, Lo IM et al (2011) Removal of natural organic matter by cationic hydrogel with magnetic properties. J Environ Manag 92(7):1690–1695CrossRefGoogle Scholar
  29. Shekari H, Sayadi M et al (2017) Synthesis of nickel ferrite/titanium oxide magnetic nanocomposite and its use to remove hexavalent chromium from aqueous solutions. Surf Interf 8:199–205CrossRefGoogle Scholar
  30. Shen J, Schäfer AI (2015) Factors affecting fluoride and natural organic matter (NOM) removal from natural waters in Tanzania by nanofiltration/reverse osmosis. Sci Total Environ 527:520–529CrossRefGoogle Scholar
  31. Song W, Shao D, Lu SS, Wang XK (2014) Simultaneous removal of uranium and humic acid by cyclodextrin modified graphene oxide nanosheets. SCIENCE CHINA Chem 57(9):1291–1299CrossRefGoogle Scholar
  32. Tang Y, Liang S, Yu S, Gao N, Zhang J, Guo H, Wang Y (2012) Enhanced adsorption of humic acid on amine functionalized magnetic mesoporous composite microspheres. Colloids Surf A Physicochem Eng Asp 406:61–67CrossRefGoogle Scholar
  33. Wang X, Wu Z, Wang Y, Wang W, Wang X, Bu Y, Zhao J (2013) Adsorption–photodegradation of humic acid in water by using ZnO coupled TiO2/bamboo charcoal under visible light irradiation. J Hazard Mater 262:16–24CrossRefGoogle Scholar
  34. Wang J, Tian H, Ji Y (2015) Adsorption behavior and mechanism of humic acid on aminated magnetic nanoadsorbent. Sep Sci Technol 50(9):1285–1293CrossRefGoogle Scholar
  35. Yang S, Hu J, Chen C, Shao D, Wang X (2011) Mutual effects of Pb (II) and humic acid adsorption on multiwalled carbon nanotubes/polyacrylamide composites from aqueous solutions. Environ Sci Technol 45(8):3621–3627CrossRefGoogle Scholar
  36. Zazouli MA, Kalankesh LR (2017) Removal of precursors and disinfection by-products (DBPs) by membrane filtration from water; a review. J Environ Health Sci Eng 15(1):25CrossRefGoogle Scholar
  37. Zhang X, Minear RA (2006) Formation, adsorption and separation of high molecular weight disinfection byproducts resulting from chlorination of aquatic humic substances. Water Res 40(2):221–230CrossRefGoogle Scholar
  38. Zularisam A, Ismail A et al (2006) Behaviours of natural organic matter in membrane filtration for surface water treatment—a review. Desalination 194(1–3):211–231CrossRefGoogle Scholar
  39. Zulfikar M, Suri F et al (2016) Fe3O4 nano-particles prepared by co-precipitation method using local sands as a raw material and their application for humic acid removal. Int J Environ Stud 73(1):79–94CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Fateme Akbari
    • 1
  • Maryam Khodadadi
    • 2
  • Ayat Hossein Panahi
    • 3
    Email author
  • Ali Naghizadeh
    • 2
  1. 1.Student Research CommitteeBirjand University of Medical Sciences (BUMS)BirjandIran
  2. 2.Medical Toxicology and Drug abuse Research Center (MTDRC)Birjand University of Medical Sciences (BUMS)BirjandIran
  3. 3.Social Determinants of Health Research CenterBirjand University of Medical ScienceBirjandIran

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