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Syagrus oleracea–activated carbon prepared by vacuum pyrolysis for methylene blue adsorption

  • Kleber Jean Leite dos Santos
  • Grazielle Emanuella de Souza dos Santos
  • Ícaro Mychel Gomes Leite de Sá
  • Sandra Helena Vieira de Carvalho
  • João Inácio Soletti
  • Lucas MeiliEmail author
  • José Leandro da Silva Duarte
  • Mozart Daltro Bispo
  • Guilherme Luiz Dotto
Research Article
  • 27 Downloads

Abstract

This work aims to produce activated carbon from the endocarp of Syagrus oleracea by vacuum pyrolysis and evaluate its potential as an adsorbent. The effects of pyrolysis temperature (400 °C, 500 °C, 600 °C, and 700 °C), particle diameter (0.467 mm, 0.267 mm, and lower than 0.234 mm), and activation agent (H2SO4, H2PO3, and KOH) on the potential for methylene blue adsorption were investigated. In addition, kinetics and adsorption equilibrium were evaluated. The best condition found was particle diameter < 0.234 mm, final pyrolysis temperature of 700 °C, and using KOH. Adsorption kinetics followed pseudo-second order, with equilibrium reached within 20 min. Isotherms followed the Freundlich model. Values of adsorption capacity were in the order of 30 mg/g. Thermodynamic parameters indicated that adsorption occurred spontaneously with a reduction in the heterogeneity of the solid interface/solution. The results obtained demonstrate the great adsorption capacity of the activated carbon prepared from endocarp of Syagrus oleracea via vacuum pyrolysis for the removal of up to 98% methylene blue from aqueous solutions.

Keywords

Biomass Activated carbon Pyrolysis Removal Dyes 

Notes

Acknowledgements

The authors thank the National Council for Scientific and Technological Development (CNPq/Brazil), the Coordination for the Improvement of Higher Education Personnel (CAPES/Brazil), and the Foundation for Research Support of the State of Alagoas (FAPEAL/Brazil).

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Kleber Jean Leite dos Santos
    • 1
    • 2
  • Grazielle Emanuella de Souza dos Santos
    • 2
  • Ícaro Mychel Gomes Leite de Sá
    • 2
  • Sandra Helena Vieira de Carvalho
    • 1
  • João Inácio Soletti
    • 1
  • Lucas Meili
    • 2
    Email author
  • José Leandro da Silva Duarte
    • 2
    • 3
  • Mozart Daltro Bispo
    • 1
  • Guilherme Luiz Dotto
    • 4
  1. 1.Laboratorio de Sistemas de Separação e Otimização de Processos (LASSOP), Centro de TecnologiaUniversidade Federal de AlagoasMaceióBrazil
  2. 2.Laboratorio de Processos (LaPro), Centro de TecnologiaUniversidade Federal de AlagoasMaceióBrazil
  3. 3.Laboratório de Eletroquímica Aplicada, Instituto de Química e BiotecnologiaUniversidade Federal de AlagoasMaceióBrazil
  4. 4.Departamento de Engenharia Química, Centro de TecnologiaUniversidade Federal de Santa MariaSanta MariaBrazil

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