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Environmental Science and Pollution Research

, Volume 26, Issue 11, pp 11126–11139 | Cite as

Enhanced adsorption of cationic Pb(II) and anionic Cr(VI) ions in aqueous solution by amino-modified nano-sized illite-smectite clay

  • Zhenyuan Li
  • Zhidong Pan
  • Yanmin WangEmail author
Research Article
  • 86 Downloads

Abstract

A raw illite-smectite mixed-layered clay (RI/S) was ground for preparing nano-sized I/S clay (NI/S) and subsequently amino-functionalized via grafting of 3-aminopropyltrithoxysilane (APTES) (NH2-RI/S and NH2-NI/S, respectively). The samples were characterized by particle size analysis, specific surface area measurement, X-ray diffraction (XRD), scanning electron microscopy (SEM), thermogravimetric analysis (TGA), X-ray photoelectron spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIR), and 29Si nuclear magnetic resonance (29Si NMR). Compared to RI/S, NI/S has a narrow particle size distribution and appears in a platelet-like morphology due to the disintegration/exfoliation of RI/S after grinding. Based on the 29Si NMR spectra, the appearances of tri-silicate units indicate the chemically grafting of APTES molecules on NH2-RI/S and NH2-NI/S, respectively. NH2-NI/S can adsorb greater amounts of Pb(II) cations and Cr(VI) anions rather than NH2-RI/S since NH2-NI/S grafts more amounts of amine groups (-NH2). The isotherm data for adsorption of Pb(II) cations and Cr(VI) anions can be described by the Langmuir model at different temperatures (i.e., 10 °C, 30 °C, and 50 °C), respectively. The maximum adsorption amounts of Pb(II) cations and Cr(VI) anions onto NH2-NI/S calculated by the Langmuir isotherm model are 131.23 mg/g and 36.91 mg/g at 50 °C, respectively. The adsorptions of Pb(II) cations and Cr(VI) anions onto NH2-NI/S involve in the surface complexation of NI/S and amine groups.

Keywords

Amino-functionalization Nano-sized illite-smectite Grinding Heavy metal ions Adsorption 

Notes

Funding information

This work was supported by the Major Scientific and Technological Projects of Guangdong Province, China (No. 2015B090927002), the Fundamental Research Funds for the Central Universities (No. 2015ZM102).

Supplementary material

11356_2019_4447_MOESM1_ESM.docx (32 kb)
ESM 1 (DOCX 27 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.College of Materials Science and EngineeringSouth China University of TechnologyGuangzhouChina

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