Environmental Science and Pollution Research

, Volume 26, Issue 11, pp 10767–10775 | Cite as

Preparation of hypercrosslinked amine modification resin and its adsorption properties for nitroaromatics

  • Chao XuEmail author
  • Chuanhong Wang
  • Weizhi Sun
  • Wenhao Yu
  • Chai Yin
  • Fusheng LiuEmail author
  • Mo XianEmail author
  • Shitao Yu
Research Article


A nitrosation-reduction method had been applied for the modification of DCE-4 h. It was a kind of non-polar hypercrosslinked resin and synthesized by our group. The functional resin, NR-07, exhibited good adsorption performance for NACs (Nitroaromatics). The adsorption capacity of NR-07 for p-nitrobenzoic acid was almost 1.3 times as much as that of H-103 in 24 h. The adsorption rate of NR-07 calculated by the kinetic function was 1.6 times as much as that of DCE-4h. According to the EA analysis and IR spectrum, the amine and carbonyl group were introduced onto the polymer chains of NR-07. These hydrophilic chemical groups of NR-07 contributed to a higher liquid-film diffusion rate than that of DCE-4h. Besides, the pore volume within 0.46~4.3 nm increased after the modification process, which had a positive effect on the intra-particle diffusion process.


Functional resins Nitrosation Adsorption kinetics Fixed bed adsorption 


Funding information

The research was supported by The Taishan Scholars Projects of Shandong (no. ts501511033) and Natural Science Foundation of Shandong Province (ZR2016BQ39).

Supplementary material

11356_2019_4370_MOESM1_ESM.docx (243 kb)
ESM 1 (DOCX 243 kb)


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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  1. 1.Key Laboratory of Biobased Materials, Qingdao Institute of Bioenergy and Bioprocess TechnologyChinese Academy of SciencesQingdaoChina
  2. 2.School of Chemical EngineeringQingdao University of Science & TechnologyQingdaoChina

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