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Black carbon: source apportionment and its implications on CCN activity over a rural region in Western Ghats, India

  • Vyoma Singla
  • Subrata MukherjeeEmail author
  • Akanksha S. Kashikar
  • Pramod D. Safai
  • Govindan Pandithurai
Research Article
  • 93 Downloads

Abstract

This study presents the characteristics of black carbon aerosol (BC) over a high-altitude site, Mahabaleshwar during the monsoon season. The mass concentration of BC exhibits a morning peak and a daytime build-up with a mean mass concentration of 303 ± 142 ng m−3. The simultaneous measurements of aerosol particle number concentration (PNC), cloud condensation nuclei concentration (CCN), and non-refractory particulate matter less than 1 μm size (NR-PM1) were also made by using a Wide-Range Aerosol Spectrometer (WRAS), CCN counter and Aerosol Chemical Speciation Monitor (ACSM) respectively. The source apportionment using wavelength-dependent light absorption model reveals the dominance by wood burning sources during morning hours and traffic sources during remaining hours of the day. The diurnal variation of PNC follows the variability of BC mass concentration. However, CCN concentrations were high during the morning hours coinciding with the increased fractional contribution of organics. The k-means clustering coupled with fuzzy algorithm highlights the effect of different sources on aerosol size distribution. On the basis of size distribution curve, the 3 clusters were attributed to wood burning (mean diameter range: 50–100 nm), traffic (30–50 nm), and background aerosols (65–95 nm). The combined analysis of k-means clustering, fractional contribution of organics, and kappa variation suggests that higher CCN concentration during morning is mainly attributed to probable emission of the water-soluble organic/inorganic compounds from wood burning.

Keywords

BC Aethalometer ACSM Wood burning Fossil fuel burning CCN 

Notes

Acknowledgments

The data used in this study are from the data repository of HACPL, part of IITM, Pune. Authors are thankful to the Director, IITM for his support and encouragement. Vyoma Singla extends special thanks to DST, SERB for N-PDF fellowship (Fellowship number: PDF/2017/002428) and Director, IITM for providing all the facilities.

Funding information

HACPL is fully funded by the Ministry of Earth Sciences (MoES) (MoES/MC4/PDTC/HACPL), Government of India, New Delhi.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no conflict of interest.

Supplementary material

11356_2019_4162_MOESM1_ESM.docx (551 kb)
ESM 1 (DOCX 550 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Vyoma Singla
    • 1
  • Subrata Mukherjee
    • 1
    Email author
  • Akanksha S. Kashikar
    • 2
  • Pramod D. Safai
    • 1
  • Govindan Pandithurai
    • 1
  1. 1.Indian Institute of Tropical MeteorologyPuneIndia
  2. 2.Savitribai Phule Pune UniversityPuneIndia

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