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Adsorption of Cd(II) from aqueous solution by Pennisetum sp. straw biochars derived from different modification methods

  • Guangcai YinEmail author
  • Lulin Bi
  • Xiaowang Song
  • Haoyu Luo
  • Pengpeng Ji
  • Qintie Lin
  • Qianjun Liu
  • Guiyou Tang
Research Article
  • 72 Downloads

Abstract

The adsorption mechanism of Cd (II) was investigated by Pennisetum sp. straw biochars (JBC) that were modified by two different methods: KMnO4 impregnation (JMB1) and H2O2 impregnation (JMB2). A scanning electron microscope and energy-dispersive spectroscopy (SEM-EDS), X-ray diffraction (XRD), a Fourier transform infrared spectrometer (FTIR), and a Brunauer-Emmett-Teller (BET) specific surface area analysis were employed to examine the physicochemical characteristics of biochars. The Cd(II) adsorption kinetic fit, the Langmuir model well, and the maximum adsorption capacity occurred in the following order: JMB1 (90.32 mg/g) > JMB2 (45.18 mg/g) > JBC (41.79 mg/g), suggesting that JMB1 had an excellent adsorption performance. Finally, X-ray photoelectron spectroscopy (XPS) was used to explore the main adsorption mechanism. Our results showed that JMB1 was an excellent adsorbent in removing Cd(II) from aqueous solution.

Keywords

Biochar Potassium permanganate Hydrogen peroxide Cd(II) Adsorption 

Notes

Funding information

This work was financially supported by the National Natural Science Foundation of China (21677041, 41371317), the Science and Technology Project of Guangzhou (201604030017, 201604020077), and the Science and Technology Project of Guangdong Province (2016A04040311).

Supplementary material

11356_2019_4158_MOESM1_ESM.pdf (2.5 mb)
Fig. S1 EDS spectrum with the element ratio: (a) pristine biochar (JBC), (b) KMnO4-impregnated Biochar (JMB1) and (c) H2O2-impregnated Biochar (JMB2). (PDF 2571 kb)
11356_2019_4158_MOESM2_ESM.pdf (4.6 mb)
Fig. S2 N2 adsorption-desorption isotherms and pore size distribution of JBC (a, d), JMB1 (b, e) and JMB2 (c, f). (PDF 4740 kb)
11356_2019_4158_MOESM3_ESM.pdf (1.2 mb)
Fig. S3 X-ray diffraction pattern of JBC, JMB1, JMB2. Crystallites were detected with peaks labeled G for graphite. (PDF 1262 kb)
11356_2019_4158_MOESM4_ESM.pdf (177 kb)
Fig. S4 Zeta potentials of JBC (a), JMB1(b) and JMB2 (c) at various pH values. (PDF 177 kb)

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2019

Authors and Affiliations

  • Guangcai Yin
    • 1
    Email author
  • Lulin Bi
    • 1
  • Xiaowang Song
    • 1
  • Haoyu Luo
    • 1
  • Pengpeng Ji
    • 2
  • Qintie Lin
    • 1
  • Qianjun Liu
    • 1
  • Guiyou Tang
    • 1
  1. 1.School of Environmental Science and EngineeringGuangdong University of TechnologyGuangzhouChina
  2. 2.CEPREI Environmental Assessment and Monitoring CenterThe 5th Electronics Research Institute of the Ministry of Industry and Information TechnologyGuangzhouChina

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