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Environmental Science and Pollution Research

, Volume 26, Issue 2, pp 1315–1322 | Cite as

Removal of Pb(II) from aqueous solutions by adsorption on magnetic bentonite

  • Chenglong Zou
  • Wei Jiang
  • Jiyan LiangEmail author
  • Xiaohang Sun
  • Yinyan Guan
Research Article
  • 141 Downloads

Abstract

Bentonite is a porous clay material that shows good performance for adsorbing heavy metals and other pollutants for wastewater remediation. In our previous study, magnetic bentonite (M-B) was prepared to solve the separation problem and improve the operability. In this study, we investigated the influence of various parameters on the Pb(II) adsorption of M-B, and it showed effective performance. About 98.9% adsorption removal rate was achieved within 90 min at adsorbent dose of 10 g/L for initial Pb(II) concentration of 200 mg/L at 40 °C and pH 5. The adsorption kinetic fit well by the pseudo-second-order model, and also followed the intra-particle diffusion model up to 90 min. Moreover, adsorption data were successfully reproduced by the Langmuir isotherm; the maximum adsorption capacity was calculated as 80.40 mg/g. The mechanism of interaction between Pb(II) ions and M-B was ionic exchange, surface complexation, and electro-static interactions. Thermodynamics study indicated that the reaction of Pb(II) adsorption on M-B was endothermic and spontaneous; increasing the temperature promoted adsorption. This study was expected to provide a reference and theoretical basis for the treatment of Pb-containing wastewater using bentonite materials.

Keywords

Bentonite Magnetic Pb(II) ions Adsorption Kinetics Thermodynamics Isotherms Mechanism 

Notes

Funding information

The authors are grateful for financial support from “Liaoning BaiQianWan Talents Program” and the China Environmental Protection Foundation, Geping Green Action, “123 Project” (Grant No. CEPF2014-123-1-6).

Supplementary material

11356_2018_3652_MOESM1_ESM.doc (7.9 mb)
ESM 1 (DOC 8104 kb)

References

  1. Blázquez G, Martín-Lara MA, Dionisio-Ruiz E, Tenorio G, Calero M (2012) Copper biosorption by pine cone shell and thermal decomposition study of the exhausted biosorbent. J Ind Eng Chem 18(5):1741–1750Google Scholar
  2. Cantuaria ML, Neto AFDA, Nascimento ES, Vieira MGA (2015) Adsorption of silver from aqueous solution onto pre-treated bentonite clay: complete batch system evaluation. J Clean Prod 112:1112–1121Google Scholar
  3. Cao JL, Chen XQ, Liu XW, Tan ZY, An LJ, Zhang K (2007) Preparation and application of magnetic bentonite clean water reagent. J Tianjin Univ 40(4):457–462Google Scholar
  4. Chen L, Yu S, Huang L, Wang G (2012) Impact of environmental conditions on the removal of Ni (II) from aqueous solution to bentonite/iron oxide magnetic composites. J Radioanal Nucl Chem 292(3):1181–1191Google Scholar
  5. Chen YG, Sun Z, Ye WM, Cui YJ (2017) Adsorptive removal of Eu(III) from simulated groundwater by GMZ bentonite on the repository conditions. J Radioanal Nucl Chem 311:1839–1847Google Scholar
  6. Daneshvar E, Kousha M, Jokar M, Koutahzadeh N, Guibal E (2012) Acidic dye biosorption onto marine brown macroalgae: isotherms, kinetic and thermodynamic studies. Chem Eng J 204–206(18):225–229Google Scholar
  7. Daou I, Zegaoui O, Amachrouq A (2017) Study of the effect of an acid treatment of a natural Moroccan bentonite on its physicochemical and adsorption properties. Water Sci Technol 75(5):1098–1117Google Scholar
  8. D'Arcy M, Weiss D, Bluck M, Vilar R (2011) Adsorption kinetics, capacity and mechanism of arsenate and phosphate on a bifunctional TiO2-Fe2O3 bi-composite. J Colloid Interf Sci 364:205–212Google Scholar
  9. Farooq U, Kozinski JA, Khan MA, Athar M (2010) Biosorption of heavy metal ions using wheat based biosorbents-a review of the recent literature. Bioresour Technol 101(14):5043–5053Google Scholar
  10. Frantz TS Jr, N S, Quadro MS, Andreazza R, Barcelos AA Jr, C T, Pinto LAA (2017) Cu(II) adsorption from copper mine water by chitosan films and the matrix effects. Environ Sci Pollut Res 24(6):1–10Google Scholar
  11. Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manag 92(3):407–418Google Scholar
  12. Ghorai S, Sarkar AK, Pal S (2014) Rapid adsorptive removal of toxic Pb2+, ion from aqueous solution using recyclable, biodegradable nanocomposite derived from templated partially hydrolyzed xanthan gum and nanosilica. Bioresour Technol 170(5):578–582Google Scholar
  13. Gu L, Xu J, Lv L, Liu B, Zhang H, Yu X, Luo ZX (2011) Dissolved organic nitrogen (DON) adsorption by using Al–pillared bentonite. Desalina 269(1–3):206–213Google Scholar
  14. Hamane D, Arous O, Kaouah F, Trari M, Kerdjoudj H, Bendjama Z (2015) Adsorption/ photo–electrodialysis combination system for Pb2+, removal using bentonite/ membrane/ semiconductor. J Environ Chem Eng 3(1):60–69Google Scholar
  15. Hu B, Luo H, Chen H, Dong T (2011) Adsorption of chromate and para-nitrochlorobenzene on inorganic-organic montmorillonite. Appl Clay Sci 51(1–2):198–201Google Scholar
  16. Jin MJ, Long MC, Su HR, Pan Y, Zhang QZ, Wang J, Zhou BX, Zhang YW (2016) Magnetically separable maghemite/montmorillonite composite as an efficient heterogeneous Fenton–like catalyst for phenol degradation. Environ Sci Pollut Res 24(2):1926–1937Google Scholar
  17. Kameda T, Umetsu M, Kumagai S, Yoshioka T (2018) Equilibrium studies of the adsorption of aromatic disulfonates by Mg–Al oxide. J Physi Chem Sol 114:129–132Google Scholar
  18. Kang Q, Zhou W, Li Q, Gao B, Fan J, Shen D (2009) Adsorption of anionic dyes on poly(epicholorohydrin dimethylamine) modified bentonite in single and mixed dye solutions. Appl Clay Sci 45(4):280–287Google Scholar
  19. Kul AR, Koyuncu H (2010) Adsorption of Pb(II) ions from aqueous solution by native and activated bentonite: kinetic, equilibrium and thermodynamic study. J Hazard Mater 179(1):332–339Google Scholar
  20. Lian L, Cao X, Wu Y, Sun D, Lou D (2014) A green synthesis of magnetic bentonite material and its application for removal of microcystin-LR in water. Appl Surf Sci 289(8):245–251Google Scholar
  21. Liu M, Hou LA, Xi B, Zhao Y, Xia X (2013) Synthesis, characterization, and mercury adsorption properties of hybrid mesoporous aluminosilicate sieve prepared with fly ash. Appl Surf Sci 273(100):706–716Google Scholar
  22. Milonjic SK (2007) A consideration of the correct calculation of thermodynamic parameters of adsorption. J Serb Chem Soc 72(12):1363–1367Google Scholar
  23. Mo W, He Q, Su X, Ma S, Feng J, He Z (2017) Preparation and characterization of a granular bentonite composite adsorbent and its application for Pb2+ adsorption. Appl Clay Sci 159(6):68–73Google Scholar
  24. Mohseni-Bandpi A, Al-Musawi TJ, Ghahramani E, Zarrabi M, Mohebi S, Vahed SA (2016) Improvement of zeolite adsorption capacity for cephalexin by coating with magnetic Fe3O4 nanoparticles. J Mol Liq 218:615–624Google Scholar
  25. Monfared AD, Ghazanfari MH, Jamialahmadi M, Helalizadeh A (2015) Adsorption of silica nanoparticles onto calcite: equilibrium, kinetic, thermodynamic and DLVO analysis. Chem Eng J 281(1):334–344Google Scholar
  26. Moussout H, Ahlafi H, Aazza M, Zegaoui O, El AC (2016) Adsorption studies of Cu(II) onto biopolymer chitosan and its nanocomposite 5% bentonite/chitosan. Water Sci Technol 73(9):2199–2210Google Scholar
  27. Olu-Owolabi BI, Popoola DB, Unuabonah EI (2010) Removal of Cu2+ and Cd2+ from aqueous solution by bentonite clay modified with binary mixture of goethite and humic acid. Water Air Soil Poll 211(1–4):459–474Google Scholar
  28. Oubagaranadin JUK, Murthy ZVP, Mallapur VP (2010) Removal of Cu(II) and Zn(II) from industrial wastewater by acid-activated montmorillonite-illite type of clay. C R Chim 13(11):1359–1363Google Scholar
  29. Pan DQ, Fan QH, Li P, Liu SP, Wu WS (2011) Sorption of Th(IV) on Na-bentonite: effects of pH, ionic strength, humic substances and temperature. Chem Eng J 172(2):898–905Google Scholar
  30. Shah J, Jan MR, Muhammad M, Ara B, Fahmeeda F (2017) Kinetic and equilibrium profile of the adsorptive removal of acid red 17 dye by surfactant-modified fuller’s earth. Water Sci Technol 75(6):1410–1420Google Scholar
  31. Shi H S, Liu Y H (2006) Adsorption characteristics of bentonite to Pb2+, Zn2+, Cr(VI), Cd2+. J Build Mater 9(5):507–510Google Scholar
  32. Shi J, Zhao ZW, Liang ZJ, Sun TY (2016) Adsorption characteristics of Pb(II) from aqueous solutions onto a natural biosorbent, fallen arborvitae leaves. Water Sci Technol 73(10):2422–2429Google Scholar
  33. Shukla A, Zhang YH, Dubey P, Margrave JL, Shukla SS (2002) The role of sawdust in the removal of unwanted materials from water. J Hazard Mater 95(1):137–152Google Scholar
  34. Singanan M (2011) Removal of lead (II) and cadmium (II) ions from wastewater using activated biocarbon. Sci Asia 37115(37):115–119Google Scholar
  35. Tunali S, Akar T, Özcan AS, Kiran I, Özcan A (2006) Equilibrium and kinetics of biosorption of lead (II) from aqueous solutions by Cephalosporium aphidicola. Sep Purif Technol 47(3):105–112Google Scholar
  36. Yao QX, Xie JJ, Liu JX, Kang HM, Liu Y (2014) Adsorption of lead ions using a modified lignin hydrogel. J Poly Res 21(6):465Google Scholar
  37. Yi ZJ, Yao J, Kuang YF, Chen HL, Wang F, Yuan ZM (2015) Removal of Pb(II) by adsorption onto Chinese walnut shell activated carbon. Water Sci Technol 72(6):983–989Google Scholar
  38. Zou C, Liang J, Jiang W, Guan Y, Zhang Y (2018) Adsorption behavior of magnetic bentonite for removing (II) from aqueous solutions. RSC Adv 8(48):27587–27595Google Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.School of ScienceShenyang University of TechnologyShenyangChina
  2. 2.Department of Advanced EngineeringMuroran Institute of TechnologyMuroranJapan

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