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Environmental Science and Pollution Research

, Volume 26, Issue 3, pp 3075–3090 | Cite as

Oxidation stability of yeast biodiesel using Rancimat analysis: validation using infrared spectroscopy and gas chromatography–mass spectrometry

  • Anbarasan TamilalaganEmail author
  • Jayanthi Singaram
Research Article

Abstract

Biodiesel and single cell oils obtained from oleaginous yeasts grown in industrial waste are attractive alternatives to the conventional fuels. However, there are only few articles dealing with the stability of the microbial biofuels. Hence, this study aimed at characterizing the storage time of biodiesels using Rancimat methods. The microbial oil and the biodiesel obtained from microbial oil have been characterized with storage stability due to various oxidizing and thermal damage. Here, the microbial fuels were subject to Rancimat analysis and found to have high thermal-oxidative stability of 18 and 8.78 h for biodiesel and oil, respectively. The storage stability resulting from storage conditions was extrapolated for biodiesel and oil and has been found to be 1.62 and 0.54 years, respectively. The infrared spectroscopic analysis reveals the degree of oxidation found after the induction time was reached and shows the characteristic peaks for degradation products. Gas chromatography revealed the compounds that were responsible for the stability as well as the amount of degradation products left.

Keywords

Microbial biodiesel Storage stability Thermal oxidative stability Induction time Fourier-transform infrared spectroscopy Gas chromatography–mass spectrometry 

Notes

Acknowledgements

The authors would like to thank the Centre of Excellence for environmental studies for supplying Rancimat for performing studies. Special thanks to Mechanical Research Scholar R. Sakthivel for his timely inputs on article preparation and gas chromatography interpretations.

Compliance with ethical standards

Conflict of interest

The authors declare that they have no competing interests.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Government College of TechnologyCoimbatoreIndia
  2. 2.Government College of EngineeringBodinayakkanurIndia

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