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Decolorization and reusing of PET depolymerization waste liquid by electrochemical method with magnetic nanoelectrodes

  • Mengjuan Li
  • Yanyan Li
  • Jing Lu
  • Xiaoqiang Li
  • Yang Lu
Research Article
  • 10 Downloads

Abstract

This work is aimed at electrochemical decolorization of real waste liquid which obtained in the PET depolymerization process. Firstly, PET fabrics were glycolysized by utilizing excess ethylene glycol (EG). Then, the glycolysis product was mixed with water and purified through repeated crystallization to get bis(2-hydroxyethyl) terephthalate (BHET) crystal. At last, the waste liquid of the depolymerization process was electrochemical decolorized by utilizing chitosan/Fe3O4 nanoparticles as the dispersed electrodes under a DC voltage. The UV-Vis absorptions at 338, 531, and 635 nm which were due to the dyes in the waste liquid decreased with the electrolysis time. In contrast, slight change of absorption of EG (at 322 nm) indicated that EG was not destroyed in the electrolytic process. The variation of color removal efficiency with dosage of chitosan/Fe3O4 nanoparticles, applied voltage, concentration of electrolyte, pH and electrolytic time were investigated. The max color removal efficiency was 87.24%. PET fabrics were depolymerized by using the decolorized waste liquid or mixture of decolorized waste liquid and EG (1:1 v/v), and the yields of BHET were 72.3% and 76.6%, respectively. The products were BHET without dyes which were confirmed by DSC and FTIR spectroscopy.

Graphical abstract

Keywords

PET waste Depolymerization Waste liquid treatment Electrochemical decolorization Dispersed nanoelectrodes Chitosan/Fe3O4 nanoparticles 

Notes

Funding information

This work was financially supported by the National High-tech R&D Program of China (No. 2016YFB0302901), the Fundamental Research Funds for the Central Universities (No. JUSRP51723B), the China Scholarship Council (No. 201706795025), the Open Project Program of Fujian Key Laboratory of Novel Functional Fibers and Materials (Minjiang University) (No. FKLTFM1713), and the National Natural Science Foundation of China (No. 31501566).

References

  1. Abdelaal MY, Sobahi TR, Makki MSI (2011) Chemical transformation of pet waste through glycolysis. Constr Build Mater 25:3267–3271CrossRefGoogle Scholar
  2. Awaja F, Pavel D (2005) Recycling of pet. Eur Polym J 41:1453–1477CrossRefGoogle Scholar
  3. Bartolome L, Imran M, Cho BG, Al-Masry WA, Kim DH (2012) Recent developments in the chemical recycling of PET. In: Achilias DS (ed) Material recycling-trends and perspectives. Intech, Rijeka, pp 65–84Google Scholar
  4. Dullius J, Ruecker C, Oliveira V, Ligabue R, Einloft S (2006) Chemical recycling of post-consumer pet: alkyd resins synthesis. Prog Org Coat 57:123–127CrossRefGoogle Scholar
  5. Eldesoky HS, Ghoneim MM, Zidan NM (2010) Decolorization and degradation of Ponceau S azo-dye in aqueous solutions by the electrochemical advanced Fenton oxidation. Desalination 264:143–150CrossRefGoogle Scholar
  6. George N, Kurian T (2014) Recent developments in the chemical recycling of postconsumer poly(ethylene terephthalate) waste. Ind Eng Chem Res 53:14185–14198CrossRefGoogle Scholar
  7. Ghaemy M, Mossaddegh K (2005) Depolymerisation of poly(ethylene terephthalate) fibre wastes using ethylene glycol. Polym Degrad Stab 90:570–576CrossRefGoogle Scholar
  8. Haber F, Weiss J (1934) The catalytic decomposition of hydrogen peroxide by iron salts. Proc R Soc Lond 147:332–351CrossRefGoogle Scholar
  9. Hassan H, Hameed BH (2011) Fe-clay as effective heterogeneous Fenton catalyst for the decolorization of Reactive Blue 4. Chem Eng J 171:912–918CrossRefGoogle Scholar
  10. He Z, Chao G, Qian M, Shi Y, Chen J, Shuang S (2014) Electro-Fenton process catalyzed by Fe3O4 magnetic nanoparticles for degradation of C.I. Reactive Blue 19 in aqueous solution: operating conditions, influence, and mechanism. Ind Eng Chem Res 53:3435–3447CrossRefGoogle Scholar
  11. Iyer SD, Joshi PV, Klein MT (2010) Automated model building and modeling of alcohol oxidation in high temperature water. Environ Prog Sustain Energy 17(4):221–233Google Scholar
  12. Li GY, Jiang YR, Huang KL, Ding P, Chen J (2008) Preparation and properties of magnetic Fe3O4 –chitosan nanoparticles. J Alloys Compd 466:451–456CrossRefGoogle Scholar
  13. Li M, Huang Y, Ju A, Yu T, Ge M (2014a) Synthesis and characterization of azo dyestuff based on bis(2-hydroxyethyl) terephthalate derived from depolymerized waste poly(ethylene terephthalate) fibers. Chin Chem Lett 25:1550–1554CrossRefGoogle Scholar
  14. Li M, Huang Y, Yu T, Chen S, Ju A, Ge M (2014b) Chemical recycling of waste poly(ethylene terephthalate) fibers into azo disperse dyestuffs. RSC Adv 4:46476–46480CrossRefGoogle Scholar
  15. Li M, Luo J, Huang Y, Li X, Yu T, Ge M (2014c) Recycling of waste poly(ethylene terephthalate) into flame-retardant rigid polyurethane foams. J Appl Polym Sci 131:5829–5836Google Scholar
  16. Lin YH, Leu JY (2008) Kinetics of reactive azo-dye decolorization by pseudomonas luteola in a biological activated carbon process. Biochem Eng J 39:457–467CrossRefGoogle Scholar
  17. López-Fonseca R, Duque-Ingunza I, Rivas BD, Arnaiz S, Gutiérrez-Ortiz JI (2010) Chemical recycling of post-consumer pet wastes by glycolysis in the presence of metal salts. Polym Degrad Stab 95:1022–1028CrossRefGoogle Scholar
  18. Luo X, Li Y (2014) Synthesis and characterization of polyols and polyurethane foams from pet waste and crude glycerol. J Polym Environ 22:318–328CrossRefGoogle Scholar
  19. Luo M, Yuan S, Man T, Peng L, Xie W, Xu X (2014) An integrated catalyst of Pd supported on magnetic Fe3O4, nanoparticles: simultaneous production of H2O2, and Fe2+, for efficient electro-Fenton degradation of organic contaminants. Water Res 48:190–199CrossRefGoogle Scholar
  20. Mahmoodi NM, Najafi F, Khorramfar S, Amini F, Arami M (2011) Synthesis, characterization and dye removal ability of high capacity polymeric adsorbent: polyaminoimide homopolymer. J Hazard Mater 198:87–94CrossRefGoogle Scholar
  21. Moral A, Irusta R, Martín JM, Martínez L (2007) Depolimerization of pet bottle wastes to produce high-value BHET monomer using ethylenglycol. Chem Eng Trans 11:479–484Google Scholar
  22. Namasivayam C, Kavitha D (2002) Removal of Congo Red from water by adsorption onto activated carbon prepared from coir pith, an agricultural solid waste. Dyes Pigments 54:47–58CrossRefGoogle Scholar
  23. Pardal F, Tersac G (2006) Comparative reactivity of glycols in pet glycolysis. Polym Degrad Stab 91:2567–2578CrossRefGoogle Scholar
  24. Radha KV, Sridevi V, Kalaivani K, Raj M (2009) Electrochemical decolorization of the dye acid orange 10. Desalin Water Treat 7:6–11CrossRefGoogle Scholar
  25. Rusevova K, Kopinke FD, Georgi A (2012) Nano-sized magnetic iron oxides as catalysts for heterogeneous Fenton-like reactions-influence of Fe(II)/Fe(III) ratio on catalytic performance. J Hazard Mater 241-242(1):433–440CrossRefGoogle Scholar
  26. Shukla SR, Harad AM, Jawale LS (2008) Recycling of waste pet into useful textile auxiliaries. Waste Manag 28:51–56CrossRefGoogle Scholar
  27. Sohrabnezhad S, Pourahmad A (2010) Comparison absorption of new methylene blue dye in zeolite and nanocrystal zeolite. Desalination 256:84–89CrossRefGoogle Scholar
  28. Wang CT, Chou WL, Chung MH, Kuo YM (2010) COD removal from real dyeing wastewater by electro-Fenton technology using an activated carbon fiber cathode. Desalination 253:129–134CrossRefGoogle Scholar
  29. Wasti A, Awan MA (2016) Adsorption of textile dye onto modified immobilized activated alumina. J Assoc Arab Univ Basic Appl Sci 20:26–31Google Scholar
  30. Welle F (2011) Twenty years of pet bottle to bottle recycling—an overview. Resour Conserv Recycl 55:865–875CrossRefGoogle Scholar
  31. Yue QF, Wang CX, Zhang LN, Ni Y, Jin YX (2011) Glycolysis of poly(ethylene terephthalate) (pet) using basic ionic liquids as catalysts. Polym Degrad Stab 96:399–403CrossRefGoogle Scholar

Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Key Laboratory of Eco-Textiles, Ministry of EducationJiangnan UniversityWuxiChina
  2. 2.College of Textile & ClothingJiangnan UniversityWuxiChina
  3. 3.Key Laboratory of Food Nutrition and Safety, Ministry of Education, School of Food Engineering and BiotechnologyTianjin University of Science & TechnologyTianjinChina

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