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Environmental Science and Pollution Research

, Volume 25, Issue 29, pp 28808–28828 | Cite as

Chemical characterization of atmospheric particulate matter in Friuli Venezia Giulia (NE Italy) by exploratory data analysis with multisite and multivariate approach

  • Andrea MistaroEmail author
  • Alessandro Felluga
  • Flavio Moimas
  • Anna Abatangelo
  • Tazio Asquini
  • Renata Bruno
  • Lorenzo Celic
  • Michele Guidarelli
  • Arnold Pastrello
  • Anita Semec Bertocchi
Straightforward approach in Cultural Heritage and Environment studies - Multivariate Analysis and Chemometry
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Abstract

The chemical composition of atmospheric particulate (PM10) in the Friuli Venezia Giulia (FVG) region (NE Italy) has been characterized for the first time with the help of exploratory data analysis (EDA) techniques (uni-, bi-, and multivariated, i.e., principal components analysis), molecular and elemental diagnostic ratios, and seasonal trends. Despite that the available analytical data was limited to the parameters routinely analyzed on PM10 by ARPA FVG (11 elements and 16 PAH congeners), the large number of samples and of measured chemical parameters, together with the applied techniques of data analysis, allowed us to extract useful latent information from the dataset, resulting in a greater knowledge of both regional and local features. Specifically, we succeeded in matching data patterns to the known pollution sources of some sampling stations, both industrial (two secondary fusion steelworks and one coke oven) and urban (traffic and domestic heating), and in defining the mainly urban or mainly industrial feature of some questionable sampling stations. This is of paramount importance to check for possible industrial inputs in urban stations, allowing policymakers to implement the most appropriate response.

Keywords

PM10 Chemical characterization Multivariate analysis Diagnostic ratios PCA Friuli Venezia Giulia Steelworks Coke oven 

Notes

Acknowledgments

We thank all colleagues that contributed to data sampling, collection, and validation, namely Marco Bellini, Valter Cecchin, Agostino Colla, Gianmaria Cossio, Ivano De Simon, Lorenzo Fragiacomo, Rossana Michelini, Angela Roman Rioni, and Marco Visintin. We thank Alessandro Acquavita (ARPA FVG) and Alan Colli (University of Cambridge) for useful insights on the manuscript preparation.

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Copyright information

© Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Andrea Mistaro
    • 1
    • 2
    Email author
  • Alessandro Felluga
    • 1
    • 3
  • Flavio Moimas
    • 1
    • 4
  • Anna Abatangelo
    • 1
    • 2
  • Tazio Asquini
    • 1
    • 2
  • Renata Bruno
    • 1
    • 2
  • Lorenzo Celic
    • 1
    • 2
  • Michele Guidarelli
    • 1
    • 2
  • Arnold Pastrello
    • 1
    • 2
  • Anita Semec Bertocchi
    • 1
    • 2
  1. 1.Agenzia Regionale per la Protezione dell’Ambiente (ARPA FVG) del Friuli Venezia GiuliaPalmanovaItaly
  2. 2.ARPA FVG Laboratorio Acque Marino-Costiere e Qualità dell’AriaTriesteItaly
  3. 3.ARPA FVG Direzione Tecnico ScientificaTriesteItaly
  4. 4.ARPA FVG Qualità dell’AriaPalmanovaItaly

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