Abstract
The presence of residual color in treated textile wastewater above the regulation limits is still a critical issue in many textile districts. Innovative, polymer-derived ceramics of the Si–C–O system were here synthesized in order to obtain porous nanocomposite materials where a free carbon phase is dispersed into a silicon carbide/silicon oxycarbide network. The sorbents were comprehensively characterized for the removal of two model water-soluble dyes (i.e., the cation methylene blue and the zwitterion rhodamine B). Adsorption is very rapid and controlled by intra-particle and/or film diffusion, depending on dye concentration. Among the nanocomposites studied, the SiOC aerogel (total capacity about 45 mg/g, is easily regenerated under mild treatment (250 °C, 2 h). Adsorption of dyes is not affected by the matrix composition: removals of 150 mg/L methylene blue from river water and simulated textile wastewater with high content of metal ions (2–50 mg/L) and chemical oxygen demand (800 mg/L) were higher than 92% and quantitative for a dye concentration of 1 mg/L.
Similar content being viewed by others
References
Al-Degs Y, Khraisheh M, Allen S, Ahmad M (2001) Sorption behavior of cationic and anionic dyes from aqueous solution on different types of activated carbons. Sep Sci Technol 36(1):91–102. https://doi.org/10.1081/SS-100000853
Baldev E, MubarakAli D, Ilavarasi A, Pandiaraj D, Ishack KSS, Thajuddin N (2013) Degradation of synthetic dye, rhodamine B to environmentally non-toxic products using microalgae. Colloids Surf B: Biointerfaces 105:207–214. https://doi.org/10.1016/j.colsurfb.2013.01.008
Banerjee S, Dastidar MG (2005) Use of jute processing wastes for treatment of wastewater contaminated with dye and other organics. Bioresour Technol 96(17):1919–1928. https://doi.org/10.1016/j.biortech.2005.01.039
Bhattacharyya KG, Sharma A (2005) Kinetics and thermodynamics of methylene blue adsorption on neem (Azadirachta indica) leaf powder. Dyes Pigments 65(1):51–59. https://doi.org/10.1016/j.dyepig.2004.06.016
Bruzzoniti MC, De Carlo R, Rivoira L, Del Bubba M, Pavani M, Riatti M, Onida B (2016) Adsorption of bentazone herbicide onto mesoporous silica: application to environmental water purification. Environ Sci Pollut R 23(6):5399–5409. https://doi.org/10.1007/s11356-015-5755-1
Bruzzoniti MC, Appendini M, Rivoira L, Onida B, Del Bubba M, Jana P, Sorarù GD (2018) Polymer-derived ceramic aerogels as sorbent materials for the removal of organic dyes from aqueous solutions. J Am Ceram Soc 101(2):821–830. https://doi.org/10.1111/jace.15241
Bruzzoniti MC, De Carlo RM, Fiorilli S, Onida B, Sarzanini C (2009) Functionalized SBA-15 mesoporous silica in ion chromatography of alkali, alkaline earths, ammonium and transition metal ions. J Chromatogr A 1216(29):5540–5547. https://doi.org/10.1016/j.chroma.2009.05.052
Bruzzoniti MC, De Carlo RM, Sarzanini C, Caldarola D, Onida B (2012) Novel insights in Al-MCM-41 precursor as adsorbent for regulated haloacetic acids and nitrate from water. Environ Sci Pollut R 19(9):4176–4183. https://doi.org/10.1007/s11356-012-0900-6
Bulut Y, Aydın H (2006) A kinetics and thermodynamics study of methylene blue adsorption on wheat shells. Desalination 194(1–3):259–267. https://doi.org/10.1016/j.desal.2005.10.032
Caldarola D, Mitev DP, Marlin L, Nesterenko EP, Paull B, Onida B, Bruzzoniti MC, De Carlo RM, Sarzanini C, Nesterenko PN (2014) Functionalisation of mesoporous silica gel with 2-[(phosphonomethyl)-amino] acetic acid functional groups. Characterisation and application. Appl Surf Sci 288:373–380. https://doi.org/10.1016/j.apsusc.2013.10.035
ChemAxon Ltd. (2016) Chemicalize, www.chemicalize.org
Colombo P (2010) Polymer derived ceramics: from Nano-structure to applications. DEStech Publications. https://doi.org/10.1002/9780470880630
Colombo P, Mera G, Riedel R, Sorarù GD (2010) Polymer-derived ceramics: 40 years of research and innovation in advanced ceramics. J Am Ceram Soc 93:1805–1837
Doğan M, Alkan M, Türkyilmaz A, Özdemir Y (2004) Kinetics and mechanism of removal of methylene blue by adsorption onto perlite. J Hazard Mater 109(1–3):141–148. https://doi.org/10.1016/j.jhazmat.2004.03.003
Dursun AY, Kalayci CS (2005) Equilibrium, kinetic and thermodynamic studies on the adsorption of phenol onto chitin. J Hazard Mater 123(1–3):151–157. https://doi.org/10.1016/j.jhazmat.2005.03.034
El-Ashtoukhy E-S, Fouad Y (2015) Liquid–liquid extraction of methylene blue dye from aqueous solutions using sodium dodecylbenzenesulfonate as an extractant. Alexandria Eng J 54(1):77–81. https://doi.org/10.1016/j.aej.2014.11.007
Fierro V, Torné-Fernández V, Montané D, Celzard A (2008) Adsorption of phenol onto activated carbons having different textural and surface properties. Micropor Mesopor Mater 111(1–3):276–284. https://doi.org/10.1016/j.micromeso.2007.08.002
Fiorilli S, Rivoira L, Calì G, Appendini M, Bruzzoniti MC, Coïsson M, Onida B (2017) Iron oxide inside SBA-15 modified with amino groups as reusable adsorbent for highly efficient removal of glyphosate from water. Appl Surf Sci 411:457–465
Gad HM, El-Sayed AA (2009) Activated carbon from agricultural by-products for the removal of rhodamine-B from aqueous solution. J Hazard Mater 168(2–3):1070–1081. https://doi.org/10.1016/j.jhazmat.2009.02.155
Ghaly A, Ananthashankar R, Alhattab M, Ramakrishnan V (2014) Production, characterization and treatment of textile effluents: a critical review. J Chem Eng Process Technol 2014
Goyal R, Sreekrishnan T, Khare M, Yadav S, Chaturvedi M (2010) Experimental study on color removal from textile industry wastewater using the rotating biological contactor. Pract Period Hazard Toxic Radioact Waste Manag 14:240–245
Gupta V (2009) Application of low-cost adsorbents for dye removal—a review. J Environ Manag 90(8):2313–2342. https://doi.org/10.1016/j.jenvman.2008.11.017
Hai FI, Yamamoto K, Fukushi K (2007) Hybrid treatment systems for dye wastewater. Crit Rev Env Sci Technol 37:315–377
Jana P, Bruzzoniti MC, Appendini M, Rivoira L, Del Bubba M, Rossini D, Ciofi L, Sorarù GD (2016) Processing of polymer-derived silicon carbide foams and their adsorption capacity for non-steroidal anti-inflammatory drugs. Ceram Int 42(16):18937–18943. https://doi.org/10.1016/j.ceramint.2016.09.045
Jana P, Zera E, Sorarù GD (2017) Processing of preceramic polymer to low density silicon carbide foam. Mater Des 116:278–286
Kumar KV, Ramamurthi V, Sivanesan S (2005) Modeling the mechanism involved during the sorption of methylene blue onto fly ash. J Colloid Interface Sci 284:14–21
Melis M (2014) Additivi e tossici negli alimenti. libreriauniversitaria. it Edizioni
Meng L, Zhang X, Tang Y, Su K, Kong J (2015) Hierarchically porous silicon–carbon–nitrogen hybrid materials towards highly efficient and selective adsorption of organic dyes. Sci Rep 5(1). https://doi.org/10.1038/srep07910
Naeem S, Baheti V, Wiener J, Marek J (2017) Removal of methylene blue from aqueous media using activated carbon web. The J Text I 108(5):803–811. https://doi.org/10.1080/00405000.2016.1191745
Nguyen VL, Laidani NB, Sorarù GD (2015a) N-doped polymer-derived Si(N)OC: the role of the N-containing precursor. J Mater Res 30(06):770–781. https://doi.org/10.1557/jmr.2015.44
Nguyen VL, Zera E, Perolo A, Campostrini R, Li W, Sorarù GD (2015b) Synthesis and characterization of polymer-derived SiCN aerogel. J Eur Ceram Soc 35(12):3295–3302. https://doi.org/10.1016/j.jeurceramsoc.2015.04.018
Olu-Owolabi BI, Diagboya PN, Adebowale KO (2014) Evaluation of pyrene sorption-desorption on tropical soils. J Environ Manag 137:1–9. https://doi.org/10.1016/j.jenvman.2014.01.048
Ovchinnikov OV, Evtukhova AV, Kondratenko TS, Smirnov MS, Khokhlov VY, Erina OV (2016) Manifestation of intermolecular interactions in FTIR spectra of methylene blue molecules. Vib Spectrosc 86:181–189. https://doi.org/10.1016/j.vibspec.2016.06.016
Patil K, Pawar R, Talap P (2000) Self-aggregation of methylene blue in aqueous medium and aqueous solutions of Bu 4 NBr and urea. Phys Chem Chem Phys 2:4313–4317
Pereira R, Pereira M, Alves M, Pereira L (2014) Carbon based materials as novel redox mediators for dye wastewater biodegradation. Appl Catal B 144:713–720. https://doi.org/10.1016/j.apcatb.2013.07.009
Randhawa N, Das N, Jana R (2014) Adsorptive remediation of Cu (II) and Cd (II) contaminated water using manganese nodule leaching residue. Desal Water Treat 52(22-24):4197–4211. https://doi.org/10.1080/19443994.2013.801324
Richardson M (2008) Chemical safety: international reference manual. John Wiley & Sons
Rivoira L, Appendini M, Fiorilli S, Onida B, Del Bubba M, Bruzzoniti MC (2016) Functionalized iron oxide/SBA-15 sorbent: investigation of adsorption performance towards glyphosate herbicide. Environ Sci Pollut R 23(21):21682–21691. https://doi.org/10.1007/s11356-016-7384-8
Singh K, Arora S (2011) Removal of synthetic textile dyes from wastewaters: a critical review on present treatment technologies. Crit Rev Environ Sci Technol 41(9):807–878. https://doi.org/10.1080/10643380903218376
Spagni A, Grilli S, Casu S, Mattioli D (2010) Treatment of a simulated textile wastewater containing the azo-dye reactive orange 16 in an anaerobic-biofilm anoxic–aerobic membrane bioreactor. Int Biodeter Biodegradation 64(7):676–681. https://doi.org/10.1016/j.ibiod.2010.08.004
Tafulo P, Queirós R, González-Aguilar G (2009) On the “concentration-driven” methylene blue dimerization. Spectrochim Acta Mol Biomol Spectrosc 73(2):295–300. https://doi.org/10.1016/j.saa.2009.02.033
Tian Y, Cui G, Liu Y, Li H, Sun Z, Yan S (2016) Self-assembly synthesis of hollow double silica@ mesoporous magnesium silicate magnetic hierarchical nanotubes with excellent performance for fast removal of cationic dyes. Appl Surf Sci 387:631–641. https://doi.org/10.1016/j.apsusc.2016.06.158
Tsai WT, Yang JM, Lai CW, Cheng YH, Lin CC, Yeh CW (2006) Characterization and adsorption properties of eggshells and eggshell membrane. Bioresour Technol 97(3):488–493. https://doi.org/10.1016/j.biortech.2005.02.050
Umoren S, Etim U, Israel A (2013) Adsorption of methylene blue from industrial effluent using poly (vinyl alcohol). J Mater Environ Sci 4:75–86
Vadivelan V, Kumar KV (2005) Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk. Journal Colloid Interface Sci 286(1):90–100. https://doi.org/10.1016/j.jcis.2005.01.007
Vallachira Warriam Sasikumar P, Zera E, Graczyk-Zajac M, Riedel R, Sorarù GD, Dunn B (2016) Structural design of polymer-derived SiOC ceramic aerogels for high-rate li ion storage applications. J Am Ceram Soc 99(9):2977–2983. https://doi.org/10.1111/jace.14323
Verma AK, Dash RR, Bhunia P (2012) A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters. J Environ Manag 93(1):154–168. https://doi.org/10.1016/j.jenvman.2011.09.012
Weber WJ, Morris JC (1964) Kinetics of adsorption on carbon from solution. J Sanit Eng Div Am Soc Civ Eng 89:31–59
Yao Y, Xu F, Chen M, Xu Z, Zhu Z (2010) Adsorption behavior of methylene blue on carbon nanotubes. Bioresour Technol 101(9):3040–3046. https://doi.org/10.1016/j.biortech.2009.12.042
Yener J, Kopac T, Dogu G, Dogu T (2008) Dynamic analysis of sorption of methylene blue dye on granular and powdered activated carbon. Chem Eng J 144(3):400–406. https://doi.org/10.1016/j.cej.2008.02.009
Yu Z, Feng Y, Li S, Pei Y (2016) Influence of the polymer–polymer miscibility on the formation of mesoporous SiC(O) ceramics for highly efficient adsorption of organic dyes. J Eur Ceram Soc 36(15):3627–3635. https://doi.org/10.1016/j.jeurceramsoc.2016.02.003
Zera E, Campostrini R, Aravind PR, Blum Y, Sorarù GD (2014) Novel SiC/C aerogels through pyrolysis of polycarbosilane precursors. Adv Eng Mater 16:814–819
Acknowledgements
MCB would like to express her gratitude to Dr. Francesca Orzi for her technical support.
Funding
The authors greatly acknowledge the financial support of “Fondazione Cassa di Risparmio di Trento e Rovereto” under the contract: polymer-derived ceramics with hierarchical porosity for water filtration/purification (grant number 2015.0174). Financial support from Ministero dell’Istruzione e della Ricerca (MIUR, Italy) is also acknowledged.
Author information
Authors and Affiliations
Corresponding author
Additional information
Responsible editor: Philippe Garrigues
Electronic supplementary material
ESM 1
(DOCX 179 kb)
Rights and permissions
About this article
Cite this article
Bruzzoniti, M.C., Appendini, M., Onida, B. et al. Regenerable, innovative porous silicon-based polymer-derived ceramics for removal of methylene blue and rhodamine B from textile and environmental waters. Environ Sci Pollut Res 25, 10619–10629 (2018). https://doi.org/10.1007/s11356-018-1367-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11356-018-1367-x