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Environmental Science and Pollution Research

, Volume 26, Issue 2, pp 1082–1093 | Cite as

Sonophotocatalytic degradation of bisphenol A and its intermediates with graphitic carbon nitride

  • Sharmini Sunasee
  • Kah Hon Leong
  • Kien Tiek Wong
  • Gooyong Lee
  • Saravanan Pichiah
  • InWook Nah
  • Byong-Hun Jeon
  • Yeomin Yoon
  • Min JangEmail author
Water Industry: Water-Energy-Health Nexus
  • 564 Downloads

Abstract

Since bisphenol A (BPA) exhibits endocrine disrupting action and high toxicity in aqueous system, there are high demands to remove it completely. In this study, the BPA removal by sonophotocatalysis coupled with nano-structured graphitic carbon nitride (g-C3N4, GCN) was conducted with various batch tests using energy-based advanced oxidation process (AOP) based on ultrasound (US) and visible light (Vis-L). Results of batch tests indicated that GCN-based sonophotocatalysis (Vis-L/US) had higher rate constants than other AOPs and especially two times higher degradation rate than TiO2-based Vis-L/US. This result infers that GCN is effective in the catalytic activity in Vis-L/US since its surface can be activated by Vis-L to transport electrons from valence band (VB) for utilizing holes (h+VB) in the removal of BPA. In addition, US irradiation exfoliated the GCN effectively. The formation of BPA intermediates was investigated in detail by using high-performance liquid chromatography-mass spectrometry (HPLC/MS). The possible degradation pathway of BPA was proposed.

Keywords

Sonophotocatalysis Bisphenol A Graphitic carbon nitride Ultrasound Visible light Intermediates 

Notes

Acknowledgements

This research was supported by a University of Malaya Research Grant (RP019B-13AET) and partly supported by the Geo-Advanced Innovative Action Project (2012000550002), funded by the Korea Ministry of Environment (MOE).

Supplementary material

11356_2017_8729_MOESM1_ESM.docx (673 kb)
Figure S1 (DOCX 673 kb)
11356_2017_8729_MOESM2_ESM.docx (55 kb)
Figure S2 (DOCX 55 kb)
11356_2017_8729_MOESM3_ESM.docx (18 kb)
Table S1 (DOCX 17 kb)
11356_2017_8729_MOESM4_ESM.docx (17 kb)
Table S2 (DOCX 16 kb)

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Copyright information

© Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  • Sharmini Sunasee
    • 1
  • Kah Hon Leong
    • 2
  • Kien Tiek Wong
    • 3
  • Gooyong Lee
    • 1
  • Saravanan Pichiah
    • 4
  • InWook Nah
    • 5
  • Byong-Hun Jeon
    • 6
  • Yeomin Yoon
    • 7
  • Min Jang
    • 3
    Email author
  1. 1.Department of Civil EngineeringFaculty of Engineering, University of MalayaKuala LumpurMalaysia
  2. 2.Faculty of Engineering and Green TechnologyUniversiti Tunku Abdul Rahman, Jalan Universiti, Bandar BaratKamparMalaysia
  3. 3.Department of Environmental EngineeringKwangwoon UniversitySeoulRepublic of Korea
  4. 4.Department of Environmental Science & EngineeringIndian Institute of Technology (ISM) DhanbadDhanbadIndia
  5. 5.Korea Institute of Science and TechnologySeoulRepublic of Korea
  6. 6.Department of Earth Resources and Environmental EngineeringHanyang UniversitySeoulRepublic of Korea
  7. 7.Department of Civil and Environmental EngineeringUniversity of South CarolinaColumbiaUSA

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