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Environmental Science and Pollution Research

, Volume 26, Issue 2, pp 1054–1060 | Cite as

Effect of coexisting components on phosphate adsorption using magnetite particles in water

  • Won-Hee Lee
  • Jong-Oh KimEmail author
Water Industry: Water-Energy-Health Nexus
  • 303 Downloads

Abstract

In this study, we focused on the rate of adsorption of phosphate on to the surface of magnetite in the presence of coexisting anions, organic matters and heavy metals. Magnetite particles were prepared using a co-precipitation method. Iron (II) sulfate heptahydrate and iron (III) chloride hexahydrate were mixed and then a sodium hydroxide solution was added drop-wise in the mixed iron solution. Coexisting anions were found to have no effect on the decrease in phosphate adsorption. However, phosphate adsorbed on to magnetite surface decreased with increasing total organic carbon (TOC) concentration of natural organic matter (NOM) such as citric, oxalic, and humic acid. The amount of phosphate adsorbed rapidly decreased with the increase of NOM concentration; therefore, it can be noted that NOM concentration considerably affects the adsorption of phosphate due to the negative charge exiting on the surface of NOMs. Glucose and ethanol, meanwhile, were found to have no effect on the phosphate adsorption. The amount of phosphate adsorbed did not change in the presence of heavy metals, namely, Pb and Cd, under acidic conditions. However, under alkaline conditions, the amount of phosphate adsorbed decreased with increasing concentrations of Pb and Cd. In the case of coexisting As(III), the amount of phosphate adsorbed decreased at all pH levels with increasing As(III) concentrations.

Keywords

Phosphorus Coexisting components Adsorption Magnetite Anion Organic matter Heavy metal 

Notes

Acknowledgments

This study was supported by a grant from the National Research Foundation of Korea (NRF) funded by the Korean Government (NRF-2016R1A2A1A05005388). Partial support was provided by the Korea Ministry of Environment (MOE) as the Advanced Technology Program for Environmental Industry.

References

  1. Choi J, Ide A, Truong YB, Kyratzis IL, Caruso RA (2013) High surface area mesoporous titanium–zirconium oxide nanofibrous web: a heavy metal ion adsorbent. J Mater Chem A 1:5847–5853CrossRefGoogle Scholar
  2. Choi J, Chung J, Lee W, Kim J-O (2016) Phosphorous adsorption on synthesized magnetite in wastewater. J Ind Eng Chem 34:198–203CrossRefGoogle Scholar
  3. Cordell D (2010) The story of phosphorus: sustainability implications of global phosphorus scarcity for food securityGoogle Scholar
  4. Cordell D, Drangert J-O, White S (2009) The story of phosphorus: global food security and food for thought. Glob Environ Chang 19:292–305CrossRefGoogle Scholar
  5. Guan X-H, Shang C, Chen G-H (2006) Competitive adsorption of organic matter with phosphate on aluminum hydroxide. J Colloid Interface Sci 296:51–58CrossRefGoogle Scholar
  6. Hong K-H, Yoo I-S, Kim S-H, Chang D, Sunwoo Y, Kim D-G (2015) Application of brass scrubber filter with copper hydroxide nanocomposite structure for phosphate removal. Environ Eng Res 20:199–204CrossRefGoogle Scholar
  7. Huang H, Liu J, Zhang P, Zhang D, Gao F (2017) Investigation on the simultaneous removal of fluoride, ammonia nitrogen and phosphate from semiconductor wastewater using chemical precipitation. Chem Eng J 307:696–706CrossRefGoogle Scholar
  8. Jin Z, Gao H, Hu L (2015) Removal of Pb (ii) by nano-titanium oxide investigated by batch. XPS and model techniques Rsc Advances 5:88520–88528CrossRefGoogle Scholar
  9. Kawai M, Nagao N, Kawasaki N, Imai A, Toda T (2016) Improvement of COD removal by controlling the substrate degradability during the anaerobic digestion of recalcitrant wastewater. J Environ Manag 181:838–846CrossRefGoogle Scholar
  10. Kim J-H, Park J-A, Kang J-K, Kim S-B, Lee C-G, Lee S-H, Choi J-W (2015) Phosphate sorption to quintinite in aqueous solutions: kinetic, thermodynamic and equilibrium analyses. Environ Eng Res 20:73–78CrossRefGoogle Scholar
  11. Lee W-H, Chung J, Kim J-O (2015) Characteristics of phosphate adsorption using prepared magnetic iron oxide (MIO) by co-precipitation method in water. Journal of Korean Society of Water and Wastewater 29:609–615CrossRefGoogle Scholar
  12. Li W, Loyola-Licea C, Crowley DE, Ahmad Z (2016) Performance of a two-phase biotrickling filter packed with biochar chips for treatment of wastewater containing high nitrogen and phosphorus concentrations. Process Saf Environ Prot 102:150–158CrossRefGoogle Scholar
  13. Liu H, Sun X, Yin C, Hu C (2008a) Removal of phosphate by mesoporous ZrO2. J Hazard Mater 151:616–622Google Scholar
  14. Liu G, Zhang X, Talley JW, Neal CR, Wang H (2008b) Effect of NOM on arsenic adsorption by TiO 2 in simulated As (III)-contaminated raw waters. Water Res 42:2309–2319CrossRefGoogle Scholar
  15. Mähler J, Persson I, Herbert RB (2013) Hydration of arsenic oxyacid species. Dalton Trans 42:1364–1377CrossRefGoogle Scholar
  16. Nur T, Loganathan P, Kandasamy J, Vigneswaran S (2016) Phosphate adsorption from membrane bioreactor effluent using Dowex 21K XLT and recovery as struvite and hydroxyapatite. Int J Environ Res Public Health 13:277CrossRefGoogle Scholar
  17. Prasad AS, Satyanarayana B (2012) Synthesis of aryl 2-oxazolines from aromatic nitriles and aminoalcohols using magnetically recoverable Pd/Fe3O4. Der Pharma Chemica 4:93–99Google Scholar
  18. Su Y, Cui H, Li Q, Gao S, Shang JK (2013) Strong adsorption of phosphate by amorphous zirconium oxide nanoparticles. Water Res 47:5018–5026Google Scholar
  19. Su Y, Yang W, Sun W, Li Q, Shang JK (2015) Synthesis of mesoporous cerium–zirconium binary oxide nanoadsorbents by a solvothermal process and their effective adsorption of phosphate from water. Chem Eng J 268:270–279Google Scholar
  20. Tang G et al (2015) Phosphate glass-clad tellurium semiconductor core optical fibers. J Alloys Compd 633:1–4CrossRefGoogle Scholar
  21. Thomas A, Sridhar S, Aghyarian S, Watkins-Curry P, Chan JY, Pozzi A, Rodrigues DC (2016) Corrosion behavior of zirconia in acidulated phosphate fluoride. J Appl Oral Sci 24:52–60CrossRefGoogle Scholar
  22. Wang Z, Nie E, Li J, Yang M, Zhao Y, Luo X, Zheng Z (2012) Equilibrium and kinetics of adsorption of phosphate onto iron-doped activated carbon. Environ Sci Pollut Res 19:2908–2917Google Scholar
  23. Xie F, Wu F, Liu G, Mu Y, Feng C, Wang H, Giesy JP (2013) Removal of phosphate from eutrophic lakes through adsorption by in situ formation of magnesium hydroxide from diatomite. Environ Sci Technol 48:582–590CrossRefGoogle Scholar
  24. Yang S, Jin P, Wang X, Zhang Q, Chen X (2016) Phosphate recovery through adsorption assisted precipitation using novel precipitation material developed from building waste: behavior and mechanism. Chem Eng J 292:246–254CrossRefGoogle Scholar
  25. Yu S-H, Dong X-L, Gong H, Jiang H, Liu Z-G (2012) Adsorption kinetic and thermodynamic studies of phosphate onto tantalum hydroxide. Water Environ Res 84:2115–2122Google Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2017

Authors and Affiliations

  1. 1.Department of Civil and Environmental EngineeringHanyang UniversitySeoulRepublic of Korea

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