Environmental Science and Pollution Research

, Volume 24, Issue 3, pp 2197–2204 | Cite as

Laser-induced breakdown spectroscopy for elemental characterization of calcitic alterations on cave walls

  • Léna BasselEmail author
  • Vincent Motto-Ros
  • Florian Trichard
  • Frédéric Pelascini
  • Faten Ammari
  • Rémy Chapoulie
  • Catherine Ferrier
  • Delphine Lacanette
  • Bruno Bousquet
Art and Cultural Heritage


Cave walls are affected by different kinds of alterations involving preservative issues in the case of ornate caves, in particular regarding the rock art covering the walls. In this context, coralloids correspond to a facies with popcorn-like aspect belonging to the speleothem family, mostly composed of calcium carbonate. The elemental characterization indicates the presence of elements that might be linked to the diagenesis and the expansion of the alterations as demonstrated by prior analyses on stalagmites. In this study, we report the use of laser-induced breakdown spectroscopy (LIBS) to characterize the elemental composition of one coralloid sample with a portable instrument allowing punctual measurements and a laboratory mapping setup delivering elemental images with spatial resolution at the micrometric scale, being particularly attentive to Mg, Sr, and Si identified as elements of interest. The complementarity of both instruments allows the determination of the internal structure of the coralloid. Although a validation based on a reference technique is necessary, LIBS data reveal that the external layer of the coralloid is composed of laminations correlated to variations of the LIBS signal of Si. In addition, an interstitial layer showing high LIBS signals for Fe, Al, and Si is interpreted to be a detrital clay interface between the external and the internal part of the coralloid. These preliminary results sustain a possible formation scenario of the coralloid by migration of the elements from the bedrock.


LIBS Laser-induced breakdown spectroscopy Speleothems Alterations Ornated cave Conservation 



This study has been carried out with financial support from the Conseil Régional d’Aquitaine and the French State, managed by the French National Research Agency (ANR) in the frame of “the investments for the future” Programme IdEx Bordeaux. The authors are also grateful to Mr. Delbos, landowner of the Leye cave, namely the laboratory cave.


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Copyright information

© Springer-Verlag Berlin Heidelberg 2016

Authors and Affiliations

  • Léna Bassel
    • 1
    Email author
  • Vincent Motto-Ros
    • 2
  • Florian Trichard
    • 2
  • Frédéric Pelascini
    • 3
  • Faten Ammari
    • 1
  • Rémy Chapoulie
    • 1
  • Catherine Ferrier
    • 4
  • Delphine Lacanette
    • 5
  • Bruno Bousquet
    • 6
  1. 1.IRAMAT-CRP2A, UMR CNRS 5060, Maison de l’ArchéologieUniversité Bordeaux MontaignePessac CedexFrance
  2. 2.Institut Lumière Matière, UMR 5306Université de Lyon 1 – CNRS, Université de LyonVilleurbanne CedexFrance
  3. 3.CRITT Matériaux AlsaceSchiltigheimFrance
  4. 4.PACEA, UMR CNRS 5199Université BordeauxPessac CedexFrance
  5. 5.I2M, UMR CNRS 5295Université BordeauxPessacFrance
  6. 6.CELIA, UMR CNRS 5107Université BordeauxTalence CedexFrance

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