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Environmental Science and Pollution Research

, Volume 21, Issue 21, pp 12305–12315 | Cite as

Annual input fluxes and source identification of trace elements in atmospheric deposition in Shanxi Basin: the largest coal base in China

  • Cong Zhong
  • Zhongfang Yang
  • Wei Jiang
  • Tao Yu
  • Qingye Hou
  • Desheng Li
  • Jianwu Wang
Research Article

Abstract

Industrialization and urbanization have led to a great deterioration of air quality and provoked some serious environmental concerns. One hundred and five samples of atmospheric deposition were analyzed for their concentrations of 13 trace elements (As, Cd, Cu, Fe, Al, Co, Cr, Hg, Mn, Mo, Pb, Se, and Zn) in Shanxi Basin, which includes six isolate basins. The input fluxes of the trace elements in atmospheric deposition were observed and evaluated. Geostatistical analysis (EF, PCA, and CA ) were conducted to determine the spatial distribution, possible sources, and enrichment degrees of trace elements in atmospheric deposition. Fe/Al and K/Al also contribute to identify the sources of atmospheric deposition. The distribution of trace elements in atmospheric deposition was proved to be geographically restricted. The results show that As, Cd, Pb, Zn, and Se mainly come from coal combustion. Fe, Cu, Mn, Hg, and Co originate mainly from interactions between local polluted soils and blowing dust from other places, while the main source of Al, Cr, and Mo are the soil parent materials without pollution. This work provides baseline information to develop policies to control and reduce trace elements, especially toxic elements, from atmospheric deposition. Some exploratory analytical methods applied in this work are also worth considering in similar researches.

Keywords

Source identification Multivariate statistics Enrichment factor Fe/Al K/Al 

Notes

Acknowledgements

This study was supported by the project of China Geological Survey “Study on Evaluation System and Integration of the Eco-geochemical Assessment for the Agricultural Ecosystem of China” (No. 1212010511218) and “Agricultural Ecological geochemical Assessment in the loess plateau basin economic belt of Shanxi” (No. 200314200020). The authors also would like to thank the two anonymous reviewers and associate editor who aided in the development and improvement of this paper.

Supplementary material

11356_2014_3052_MOESM1_ESM.pdf (1.9 mb)
(PDF 1.88 MB)

References

  1. Acosta J, Faz A, Martínez-Martínez S, Zornoza R, Carmona D, Kabas S (2011) Multivariate statistical and GIS-based approach to evaluate heavy metals behavior in mine sites for future reclamation. J Geochem Explor 109:8–17CrossRefGoogle Scholar
  2. Bermudez G, Jasan R, Pla R, Pignata M (2012) Heavy metals and trace elements in atmospheric fall-out: their relationship with topsoil and wheat element composition. J Hazard Mater 213–214:447–56CrossRefGoogle Scholar
  3. Buat-Menard P, Chesselet R (1979) Variable influence of the atmospheric flux on the trace metal chemistry of oceanic suspended matter. Earth Planet Sc Lett 42:399–411CrossRefGoogle Scholar
  4. CGS (2005a) Ecological Geochemical Sample Analysis Technical Requirements(for Trial Implementation)(DD2005-03) (in Chinese)Google Scholar
  5. CGS (2005b) Specification of Regional Eco-geochemical Assessment (DD2005-02) (in Chinese)Google Scholar
  6. Cong Z, Kang S, Zhang Y, Li X (2010) Atmospheric wet deposition of trace elements to central Tibetan Plateau. Appl Geochem 25:1415–1421CrossRefGoogle Scholar
  7. Connan O, Maro D, Hébert D, Roupsard P, Goujon R, Letellier B, Le Cavelier S (2013) Wet and dry deposition of particles associated metals (Cd, Pb, Zn, Ni, Hg) in a rural wetland site, Marais Vernier, France. Atmos Environ 67:394–403CrossRefGoogle Scholar
  8. Conrad C, Chisholm-Brause C (2004) Spatial survey of trace metal contaminants in the sediments of the Elizabeth River, Virginia. Mar Pollut Bull 49:319–324CrossRefGoogle Scholar
  9. Đorđević D, Mihajlidi-Zelić A, Relić D (2005) Differentiation of the contribution of local resuspension from that of regional and remote sources on trace elements content in the atmospheric aerosol in the Mediterranean area. Atmos Environ 39:6271–6281CrossRefGoogle Scholar
  10. Gandois L, Nicolas M, VanderHeijden G, Probst A (2010) The importance of biomass net uptake for a trace metal budget in a forest stand in north-eastern France. Sci Total Environ 408:5870–7CrossRefGoogle Scholar
  11. Han Y, Du P, Cao J, Eric S. P (2006) Multivariate analysis of heavy metal contamination in urban dusts of Xi’an, Central China. Sci Total Environ 355:176–186CrossRefGoogle Scholar
  12. Hou Q, Yang Z, Ji J, Yu T, Chen G, Li J, Xia X, Zhang M, Yuan X (2014) Annual net input fluxes of heavy metals of the agro-ecosystem in the Yangtze River delta, China. J Geochem Explor 139:68–84CrossRefGoogle Scholar
  13. Hu D, Zhang W, Chen L, Chen C, Ou L, Tong Y, Wei W, Long W, Wang X (2012) Mercury emissions from waste combustion in China from 2004 to 2010. Atmos Environ 62:359–366CrossRefGoogle Scholar
  14. Huang S, Tu J, Liu H, Hua M, Liao Q, Feng J, Weng Z, Huang G (2009) Multivariate analysis of trace element concentrations in atmospheric deposition in the Yangtze River Delta, East China. Atmos Environ 43:5781–5790CrossRefGoogle Scholar
  15. Jiang W, Hou Q, Yang Z, Yu T, Zhong C, Yang Y, Fu Y (2014) Annual input fluxes of heavy metals in agricultural soil of Hainan Island, China. Environ Sci Pollut R.  10.1007/s11356-014-2679-0 Google Scholar
  16. Kabata-Pendias A, Mukherjee A (2007) Trace elements from soil to human. SpringerGoogle Scholar
  17. Loska K, Wiechuła D (2003) Application of principal component analysis for the estimation of source of heavy metal contamination in surface sediments from the Rybnik Reservoir. Chemosphere 51:723–733CrossRefGoogle Scholar
  18. Luo L, Ma Y, Zhang S, Wei D, Zhu Y (2009) An inventory of trace element inputs to agricultural soils in China. J Environ Manage 90:2524–2530CrossRefGoogle Scholar
  19. Mishra V, Kim K, Kang C, Choi K (2004) Wintertime sources and distribution of airborne lead in Korea. Atmos Environ 38:2653–2664CrossRefGoogle Scholar
  20. Nicholson F, Smith S, Alloway B, Carlton-Smith C, Chambers B (2003) An inventory of heavy metals inputs to agricultural soils in England and Wales. Sci Total Environ 311:205–219CrossRefGoogle Scholar
  21. Nicholson F, Smith S, Alloway B, Carlton-Smith C, Chambers B (2006) Quantifying heavy metal inputs to agricultural soils in England and Wales. Water Environ J 20 (2):87–95CrossRefGoogle Scholar
  22. Rossini P, Guerzoni S, Molinaroli E, Rampazzo G, De Lazzari A, Zancanaro A (2005) Atmospheric bulk deposition to the lagoon of Venice: Part I. Fluxes of metals, nutrients and organic contaminants. Environ Int 31:959–974CrossRefGoogle Scholar
  23. Sheppard S C, Grant C A, Sheppard M I, de Jong R Long J (2009) Risk indicator for agricultural inputs of trace elements to canadian soils. J Environ Qual 38:919–932CrossRefGoogle Scholar
  24. Shi C, Zhao L, Guo X, Gao S, Yang J, Li J (1996) Distribution and impact factors of soil background value in Shanxi province (in Chinese). Agro-Environ Protect 15 (1):24–28Google Scholar
  25. Shi R, Lv J, Cai Y, Liu Y, Wang Z, Feng J, Zhao M (2010) Levels, spatial distribution and possible sources of heavy metals contamination of suburban soils in Tianjin, China. B Environ Contam Tox 85:287–90CrossRefGoogle Scholar
  26. Song Y, Xie S, Zhang Y, Zeng L, Salmon L G, Zheng M (2006) Source apportionment of PM2. 5 in Beijing using principal component analysis/absolute principal component scores and UNMIX. Sci Total Environ 372:278–286CrossRefGoogle Scholar
  27. Sutherland R (2000) Bed sediment-associated trace metals in an urban stream, Oahu, Hawaii. Environ Geo 39:611–627CrossRefGoogle Scholar
  28. Wei F, Chen J, Wu Y (1990) The background values of Chinese soils. Environmental Science Press of China, Beijing. (in Chinese)Google Scholar
  29. Wen Q (1989) Loess geochemistry in China. Science Press, Beijing. (in Chinese)Google Scholar
  30. Wong C, Li X, Zhang G, Qi S, Peng X (2003) Atmospheric deposition of heavy metals in the Pearl River Delta, China. Atmos Environ 37:767–776CrossRefGoogle Scholar
  31. Wong S, Li X, Zhang G, Qi S, Min Y (2002) Heavy metals in agricultural soils of the Pearl River Delta, South China. Environ Pollut 119:33–44CrossRefGoogle Scholar
  32. Xia X, Yang Z, Cui Y, Li Y, Hou Q, Yu T (2014) Soil heavy metal concentrations and their typical input and output fluxes on the southern Song-nen Plain, Heilongjiang Province, China. J Geochem Explor 139:85–96CrossRefGoogle Scholar
  33. Xu L, Yu Y, Yu J, Chen J, Niu Z, Yin L, Zhang F, Liao X, Chen Y (2013) Spatial distribution and sources identification of elements in PM 2.5 among the coastal city group in the Western Taiwan Strait region, China. Sci Total Environ 442:77–85CrossRefGoogle Scholar
  34. Yang Z, Hou Q, Yu T, Chen J, Xia X, Huang Y, Li K (2008) Eco-geochemical assessment of agroecosystems: Cd in the Chengdu Economical Region, Sichuan, China. Earth Sci Front 15:23–35CrossRefGoogle Scholar
  35. Yatin M, Tuncel S, Aras N K, Olmez I, Aygun S, Tuncel G (2000) Atmospheric trace elements in Ankara, Turkey: 1. Factors affecting chemical composition of fine particles. Atmos Environ 34:1305–1318CrossRefGoogle Scholar
  36. Yuan G, Sun T, Han P, Li J (2013) Environmental geochemical mapping and multivariate geostatistical analysis of heavy metals in topsoils of a closed steel smelter: Capital Iron & Steel Factory, Beijing, China. J Geochem Explor 130:15–21CrossRefGoogle Scholar
  37. Yuan G, Sun T, Han P, Li J, Lang X (2014) Source identification and ecological risk assessment of heavy metals in topsoil using environmental geochemical mapping: Typical urban renewal area in Beijing, China. J Geochem Explor 136:40–47CrossRefGoogle Scholar
  38. Zhang C, Qiao Q, Appel E, Huang B (2012) Discriminating sources of anthropogenic heavy metals in urban street dusts using magnetic and chemical methods. J Geochemical Explor 119:60– 75CrossRefGoogle Scholar
  39. Zhang D, Wang J, Zhang X (1991) The synoptic dynamic condition and the features of chemical elements of the dustfall event in April 1990 in Beijing. Quater nary sciences 3:204–212. (in Chinese)Google Scholar
  40. Zhang H, Yin R, Feng X, Sommar J, Anderson C, Sapkota A, Fu X, Larssen T (2013) Atmospheric mercury inputs in montane soils increase with elevation: evidence from mercury isotope signatures. Sci Rep 3:3322Google Scholar
  41. Zhang J, Zheng C, Ren D, Chou C, Liu J, Zeng R, Wang Z, Zhao F, Ge Y (2004) Distribution of potentially hazardous trace elements in coals from Shanxi province, China. Fuel 83:129– 135CrossRefGoogle Scholar
  42. Zhao Y, Zhang J, Chou C, Li Y, Wang Z, Ge Y, Zheng C (2008) Trace element emissions from spontaneous combustion of gob piles in coal mines, Shanxi, China. Int J Coal Geo 73:52–62CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2014

Authors and Affiliations

  1. 1.School of Earth Sciences and ResourcesChina University of GeosciencesBeijingChina
  2. 2.Shanxi Institute of Geological SurveyTaiyuanChina

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