Environmental Science and Pollution Research

, Volume 20, Issue 6, pp 3900–3909 | Cite as

Removal of toxic heavy metal ions from waste water by functionalized magnetic core–zeolitic shell nanocomposites as adsorbents

Research Article

Abstract

Functionalized magnetic core–zeolitic shell nanocomposites were prepared via hydrothermal and precipitation methods. The products were characterized by vibrating sample magnetometer, X-ray powder diffraction, Fourier transform infrared spectroscopy, nitrogen adsorption–desorption isotherms, and transmission electron microscopy analysis. The growth of mordenite nanocrystals on the outer surface of silica-coated magnetic nanoparticles at the presence of organic templates was well approved. The removal performance and the selectivity of mixed metal ions (Pb2+ and Cd2+) in aqueous solution were investigated via the sorption process. The batch method was employed to study the sorption kinetic, sorption isotherms, and pH effect. The removal mechanism of metal ions was done by chem–phys sorption and ion exchange processes through the zeolitic channels and pores. The experimental data were well fitted by the appropriate kinetic models. The sorption rate and sorption capacity of metal ions could be significantly improved by optimizing the parameter values.

Keywords

Magnetic core–zeolitic shell Toxic heavy metal ions Sorption 

References

  1. Ali I (2010) The quest for active carbon adsorbent substitutes: inexpensive adsorbents for toxic metal ions removal from wastewater. Sepn Purfn Rev 39:95–171CrossRefGoogle Scholar
  2. Ali I (2012) New generation adsorbents for water treatment. Chem Revs 112:5073–5091CrossRefGoogle Scholar
  3. Ali I, Asim M, Khan TA (2012) Low cost adsorbents for the removal of organic pollutants from wastewater. J Environ Manag 113:170–183CrossRefGoogle Scholar
  4. Alvarez-Ayuso E, Garcia-Sanchez A (2003) Removal of heavy metals from waste waters by natural and Na-exchanged bentonites. Clays Clay Miner 51:475–480CrossRefGoogle Scholar
  5. Alvarez-Ayuso E, Garcia-Sanchez A, Querol X (2003) Purification of metal electroplating waste waters using zeolites. Water Res 37:4855–4862CrossRefGoogle Scholar
  6. Arruebo M, Galan M, Navascues N, Tellez C, Marquina C, Ibarra MR (2006) Development of magnetic nanostructured silica-based materials as potential vectors for drug-delivery applications. Chem Mater 18:1911–1919CrossRefGoogle Scholar
  7. Badillo-Almaraz V, Trocellier P, Davila-Rangel I (2003) Adsorption of aqueous Zn(II) species on synthetic zeolites. Nucl Instrum Meth B 210:424–428CrossRefGoogle Scholar
  8. Beyazit N, Ergun QN, Peker I (2003) Cu(II) removal from aqueous solution using Dogantepe (Amasya) zeolites. Int J Environ Pollut 19:150–159CrossRefGoogle Scholar
  9. Cincotti A, Lai N, Orru R, Cao G (2001) Sardinian natural clinoptilolite for heavy metals and ammonium removal: experimental and modeling. Chem Eng J 84:275–282CrossRefGoogle Scholar
  10. Deng YH, Qi DW, Deng CH, Zhang XM, Zhao DY (2008) Superparamagnetic highmagnetization micropheres with a Fe3O4@SiO2 core and perpendicularly aligned mesoporous SiO2 shell for removal of microcystins. J Am Chem Soc 130:28–29CrossRefGoogle Scholar
  11. Erdem E, Karapinar N, Donat R (2004) The removal of heavy metal cations by natural zeolites. J Colloid Interface Sci 280:309–314CrossRefGoogle Scholar
  12. Fu F, Wang Q (2011) Removal of heavy metal ions from wastewaters: a review. J Environ Manage 92:407–418CrossRefGoogle Scholar
  13. Giri S, Trewyn BG, Stellmaker MP, Lin VSY (2005) Stimuli-responsive controlledrelease delivery system based on mesoporous silica nanorods capped with magnetic nanoparticles. Angew Chem Int Ed 44:5038–5044CrossRefGoogle Scholar
  14. Goyal RN, Gupta VK, Oyama M, Bachheti N (2007) Voltammetric determination of adenosine and guanosine using fullerene-C60-modified glassy carbon electrode. Talanta 71:1110–1117CrossRefGoogle Scholar
  15. Guo J, Yang WL, Wang CC, He J, Chen JY (2006) Poly(N-isopropylacrylamide)-coated luminescent/magnetic silica microspheres: preparation, characterization, and biomedical applications. Chem Mater 18:5554–5562CrossRefGoogle Scholar
  16. Gupta VK, Rastogi A (2009) Biosorption of hexavalent chromium by raw and acid-treated green alga Oedogonium hatei from aqueous solutions. J Hazard Mater 163:396–402CrossRefGoogle Scholar
  17. Gupta VK, Sharma S (2003) Removal of Zinc from Aqueous Solutions Using Bagasse Fly Ash − a Low Cost Adsorbent. Ind Eng Chem Res 42:6619–6624CrossRefGoogle Scholar
  18. Gupta VK, Srivastava SK, Tyagi R (2000) Design parameters for the treatment of phenolic wastes by carbon columns (obtained from fertilizer waste material). Water Res 34:1543–1550CrossRefGoogle Scholar
  19. Gupta VK, Mittal A, Krishnan L, Mittal J (2006a) Adsorption treatment and recovery of the hazardous dye, Brilliant Blue FCF, over bottom ash and de-oiled soya. J Colloid Interface Sci 293:16–26CrossRefGoogle Scholar
  20. Gupta VK, Mitall A, Kurup L, Mittal J (2006b) Adsorption of a hazardous dye, erythrosine, over hen feathers. J Colloid Interface Sci 304:52–57CrossRefGoogle Scholar
  21. Gupta VK, Jain R, Mittal A, Mathur M, Sikarwar S (2007a) Photochemical degradation of the hazardous dye Safranin-T using TiO2 catalyst. J Colloid Interface Sci 309:464–469CrossRefGoogle Scholar
  22. Gupta VK, Jain R, Varshney S (2007b) Removal of Reactofix golden yellow 3 RFN from aqueous solution using wheat husk—An agricultural waste. J Hazard Mater 142:443–448CrossRefGoogle Scholar
  23. Gupta VK, Singh AK, Gupta B (2007c) Schiff bases as cadmium(II) selective ionophores in polymeric membrane electrodes. Anal Chim Acta 583:340–348CrossRefGoogle Scholar
  24. Gupta VK, Ali I, Saini VK (2007d) Defluoridation of wastewaters using waste carbon slurry. Water Res 41:3307–3316CrossRefGoogle Scholar
  25. Gupta VK, Jain R, Varshney S (2007e) Electrochemical removal of the hazardous dye Reactofix Red 3 BFN from industrial effluents. J Colloid Interface Sci 312:292–296CrossRefGoogle Scholar
  26. Gupta VK, Khayat MA, Singh AK, Pal MK (2009a) Nano level detection of Cd(II) using poly(vinyl chloride) based membranes of Schiff bases. Anal Chim Acta 634:36–43CrossRefGoogle Scholar
  27. Gupta VK, Goyal RN, Sharma RA (2009b) Novel PVC Membrane Based Alizarin Sensor and its application; Determination of Vanadium, Zirconium and Molybdenum. Int J Electrochem Sci 4:156–172Google Scholar
  28. Gupta VK, Rastogi A, Nayak A (2010) Adsorption studies on the removal of hexavalent chromium from aqueous solution using a low cost fertilizer industry waste material. J Colloid Interface Sci 342:135–141CrossRefGoogle Scholar
  29. Hui KS, Chao CYH, Kot SC (2005) Removal of mixed heavy metal ions in wastewater by zeolite 4A and residual products from recycled coal fly ash. J Hazard Mater 127:89–101CrossRefGoogle Scholar
  30. Jain AK, Gupta VK, Khurana U, Singh LP (1997) A new membrane sensor for UO ions based on 2-hydroxyacetophenoneoxime-thiourea-trioxane resin. Electroanalysis 9:857–860CrossRefGoogle Scholar
  31. Jain AK, Gupta VK, Jain S (2004) Removal of Chlorophenols Using Industrial Wastes. Environ Sci Technol 38:1195–1200CrossRefGoogle Scholar
  32. Jal PK, Patel S, Mishra BK (2004) Chemical modification of silica surface by immobilization of functional groups for extractive concentration of metal ions. Talanta 62:1005–1028CrossRefGoogle Scholar
  33. Kim JS, Park JC, Yi J (2000) Zinc ion removal from aqueous solutions using modified silica impregnated with 2-ethylhexyl 2-ethylhexyl phosphoric acid. Sep Sci Technol 35:1901–1916CrossRefGoogle Scholar
  34. Kim J, Lee JE, Lee J, Yu JH, Kim BC, An K (2006) Magnetic fluorescent delivery vehicle using uniform mesoporous silica spheres embedded with monodisperse magnetic and semiconductor nanocrystals. J Am Chem Soc 128:688–689CrossRefGoogle Scholar
  35. Langella A, Pansini M, Cappelletti P, Gennaro B, Gennaro M, Colella C (2000) NH4+, Cu2+, Zn2+, Cd2+ and Pb2+ exchange for Na+ in a sedimentary clinoptilolite, North Sardinia, Italy. Microporous and Mesoporous Mater 37:337–343CrossRefGoogle Scholar
  36. Langmuir I (1918) Adsorption of gases on plain surface of glass mica platinum. J Am Chem Soc 40:1361–1403CrossRefGoogle Scholar
  37. Levy L, Sahoo Y, Kim K-S, Bergey EJ, Prasad PN (2002) Nanochemistry: synthesis and characterization of multifunctional nanoclinics for biological applications. Chem Mater 14:3715–3721CrossRefGoogle Scholar
  38. Li Y, Yan B, Deng CH, Yu WJ, Xu XQ, Yang PY (2007) Efficient on-chip proteolysis system based on functionalized magnetic silica microspheres. Proteomics 7:2330–2339CrossRefGoogle Scholar
  39. Liu CX, Liu Q, Guo CC (2010) Synthesis and Catalytic Abilities of Silica-coated Fe3O4 Nanoparticle Bonded Metalloporphyrins with Different Saturation Magnetization. Catal Lett 138:96–103CrossRefGoogle Scholar
  40. Lu X, Zhang HP, Leng Y, Fang L, Qu S, Feng B, Weng J, Huang N (2010) The effects of hydroxyl groups on Ca adsorption on rutile surfaces: a first-principles study. J Mater Sci Mater Med 21:1–10CrossRefGoogle Scholar
  41. Mittal A, Krishnan L, Gupta VK (2005) Use of waste materials—Bottom Ash and De-Oiled Soya, as potential adsorbents for the removal of Amaranth from aqueous solutions. J Hazard Mater 117:171–178CrossRefGoogle Scholar
  42. Murray CB, Norris DJ, Bawendi MG (1993) Synthesis and characterization of nearly monodisperse CdE (E = sulfur, selenium, tellurium) semiconductor nanocrystallites. J Am Chem Soc 115:8706–8715CrossRefGoogle Scholar
  43. Namasivayam C, Yamuna RT (1999) Studies on chromium (III) removal from aqueous solution by adsorption onto biogas residual slurry and its application to tannery wastewater treatment. Water Air Soil Pollut 113:371–384CrossRefGoogle Scholar
  44. Namasivayam C, Jeyakumar R, Yamuna RT (1994) Dye removal from waste-water by adsorption on waste Fe(III)/Cr(III) hydroxide. Waste Manage 14:643–648CrossRefGoogle Scholar
  45. Namasivayam C, Yamuna RT, Jayanthi J (2003) Removal of methylene blue from wastewater by adsorption on cellulosic waste, orange peel. Cell Chem Technol 37:333–339Google Scholar
  46. Ngah WSW, Hanafiah MAKM (2008) Removal of heavy metal ions from wastewater by chemically modified plant wastes as adsorbents: a review. Bioresource Technol 99:3935–3948CrossRefGoogle Scholar
  47. Peric J, Trgo M, Vukojevic-Medvidovic N (2004) Removal of zinc, copper and lead by natural zeolite – a comparison of adsorption isotherms. Water Res 38:1893–1899CrossRefGoogle Scholar
  48. Piaoping Y, Zewei Q, Zhiyao H, Chunxia L, Xiaojiao K, Ziyong C, Jun L (2009) A magnetic, luminescent and mesoporous core–shell structured composite material as drug carrier. Biomaterials 30:4786–4795CrossRefGoogle Scholar
  49. Reddad Z, Gerente C, Andres Y, Le-Cloirec P (2002) Adsorption of several metal ions onto a low-cost biosorbent: kinetic and equilibrium studies. Environ Sci Technol 36:2067–2073CrossRefGoogle Scholar
  50. Sharma P, Rajaram P, Tomar R (2008) Synthesis and morphological studies of nanocrystalline MOR type zeolite material. J Colloid Interface Sci 325:547–557CrossRefGoogle Scholar
  51. Shriver DF, Atkins PW, Langford CH (1990) Inorganic Chemistry, 1st edn. Freeman, New YorkGoogle Scholar
  52. Srivastava NK, Majumder CB (2008) Novel biofiltration methods for the treatment of heavy metals from industrial wastewater. J Hazard Mater 151:1–8CrossRefGoogle Scholar
  53. Srivastava SK, Gupta VK, Dwivedi MK, Jain S (1995) Caesium PVC–crown (dibenzo-24-crown-8) based membrane sensor. Anal Proc 32:21–23CrossRefGoogle Scholar
  54. Taty-Costodes VC, Fauduet H, Porte C, Delacroix A (2003) Removal of Cd(II) and Pb(II) ions, from aqueous solutions, by adsorption onto sawdust of Pinus sylvestris. J Hazard Mater 105:121–142CrossRefGoogle Scholar
  55. Yang PP, Quan ZW, Lu LL, Huang SS, Lin J (2008) Bioactive, luminescent andmesoporous europium-doped hydroxyapatite as a drug carrier. Biomaterials 29:4341–4347CrossRefGoogle Scholar
  56. Zhao WR, Gu JL, Zhang LX, Chen HR, Shi JL (2005) Fabrication of uniform magnetic nanocomposite spheres with a magnetic core/mesoporous silica shell structure. J Am Chem Soc 127:8916–8917CrossRefGoogle Scholar
  57. Zhiya M, Yueping G, Huizhou L (2006) Superparamagnetic silica nanoparticles with immobilized metal affinity ligands for protein adsorption. J Magn Magn Mater 301:469–477CrossRefGoogle Scholar

Copyright information

© Springer-Verlag Berlin Heidelberg 2012

Authors and Affiliations

  1. 1.Department of ChemistrySharif University of TechnologyTehranIran

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