Field Application of In Situ Electrokinetic Remediation for As-, Cu-, and Pb-Contaminated Paddy Soil
Abstract
An electrokinetic technique was used to remediate As-, Cu-, and Pb-contaminated paddy soil in a real field on a pilot scale. A hexagonal electrode placement with one anode at the center and six cathodes at the vertices of the hexagon was installed in the field. After operation for 4 weeks, the average removal of Pb was 64.9 % in the top layer (0–0.4 m), 81.2 % in the middle layer (0.4–0.8 m), and 66.9 % in the bottom layer (0.8–1.2 m). The removal of As was 28.2 % in the top layer, 43.2 % in the middle layer, and 24.5 % in the bottom layer. The removal of Cu was 17.7 % in the middle layer and was not observed in the other layers. The relatively high removal of Pb might come from the more labile fraction of Pb in soil compared to As and Cu. However, the circulation of anolyte using an alkaline solution to enhance removal of As failed because the electrolyte leaked between the anode and surrounding soil. Effective circulation might enhance the performance of the electrokinetic process.
Keywords
Electrokinetic remediation Field application In situ Paddy soil ArsenicNotes
Acknowledgments
This work was supported by KEITI through the GAIA project.
References
- Acar, Y. B., & Alshawabkeh, A. N. (1996). Electrokinetic remediation. 1. Pilot-scale tests with lead-spiked kaolinite. Journal of Geotechnical Engineering-ASCE, 122, 173–185.CrossRefGoogle Scholar
- Alshawabkeh, A. N., Bricka, R. M., & Gent, D. B. (2005). Pilot-scale electrokinetic cleanup of lead-contaminated soils. Journal of Geotechnical and Geoenvironmental Engineering, 131, 283–291.CrossRefGoogle Scholar
- Baek, K., Kim, D. H., Park, S. W., Ryu, B. G., Bajargal, T., & Yang, J. S. (2009). Electrolyte conditioning-enhanced electrokinetic remediation of arsenic-contaminated mine tailing. Journal of Hazardous Materials, 161, 457–462.CrossRefGoogle Scholar
- Cho, J. M., Kim, K. J., Chung, K. Y., Hyun, S., & Baek, K. (2009). Restoration of saline soil in cultivated land using electrokinetic process. Separation Science and Technology, 44, 2371–2384.CrossRefGoogle Scholar
- Cho, J. M., Park, S. Y., & Baek, K. (2010). Electrokinetic restoration of saline agricultural lands. Journal of Applied Electrochemistry, 40, 1085–1093.CrossRefGoogle Scholar
- Costarramone, N., Tellier, S., Astruc, M., Grano, B., & Lecomte, D. (1998). Application of an electrokinetic technique to the reclamation of fluoride polluted soils: laboratory and pilot scale experiments. Waste Management & Research, 16, 555–563.CrossRefGoogle Scholar
- Fonseca, B., Pazos, M., Tavares, T., & Sanroman, M. A. (2012). Removal of hexavalent chromium of contaminated soil by coupling electrokinetic remediation and permeable reactive biobarriers. Environmental Science and Pollution Research, 19, 1800–1808.CrossRefGoogle Scholar
- Garcia-Rubio, A., Rodriguez-Maroto, J. M., Gomez-Lahoz, C., Garcia-Herruzo, F., & Vereda-Alonso, C. (2011). Electrokinetic remediation: the use of mercury speciation for feasibility studies applied to a contaminated soil from Almaden. Electrochimica Acta, 56, 9303–9310.CrossRefGoogle Scholar
- Gent, D. B., Bricka, R. M., Alshawabkeh, A. N., Larson, S. L., Fabian, G., & Granade, S. (2004). Bench-and field-scale evaluation of chromium and cadmium extraction by electrokinetics. Journal of Hazardous Materials, 110, 53–62.CrossRefGoogle Scholar
- Kim, S. O., Moon, S. H., Kim, K. W., & Yun, S. T. (2002). Pilot scale study on the ex situ electrokinetic removal of heavy metals from municipal wastewater sludges. Water Research, 36, 4765–4774.CrossRefGoogle Scholar
- Kim, D. H., Jeon, C. S., Baek, K., Ko, S. H., & Yang, J. S. (2009a). Electrokinetic remediation of fluorine-contaminated soil: conditioning of anolyte. Journal of Hazardous Materials, 161, 565–569.CrossRefGoogle Scholar
- Kim, D. H., Ryu, B. G., Park, S. W., Seo, C. I., & Baek, K. (2009b). Electrokinetic remediation of Zn and Ni-contaminated soil. Journal of Hazardous Materials, 165, 501–505.CrossRefGoogle Scholar
- Kim, G. N., Lee, S. S., Shon, D. B., Lee, K. W., & Chung, U. S. (2010a). Development of pilot-scale electrokinetic remediation technology to remove Co-60 and Cs-137 from soil. Journal of Industrial and Engineering Chemistry, 16, 986–991.CrossRefGoogle Scholar
- Kim, K. J., Cho, J. M., Baek, K., Yang, J. S., & Ko, S. H. (2010b). Electrokinetic removal of chloride and sodium from tidelands. Journal of Applied Electrochemistry, 40, 1139–1144.CrossRefGoogle Scholar
- Kim, B.-K., Baek, K., Ko, S.-H., & Yang, J.-W. (2011a). Research and field experiences on electrokinetic remediation in South Korea. Separation and Purification Technology, 79, 116–123.CrossRefGoogle Scholar
- Kim, G. N., Shon, D. B., Park, H. M., Lee, K. W., & Chung, U. S. (2011b). Development of pilot-scale electrokinetic remediation technology for uranium removal. Separation and Purification Technology, 80, 67–72.CrossRefGoogle Scholar
- Kim, K.-J., Kim, D.-H., Yoo, J.-C., & Baek, K. (2011c). Electrokinetic extraction of heavy metals from dredged marine sediment. Separation and Purification Technology, 79, 164–169.CrossRefGoogle Scholar
- Kim, W. S., Park, G. Y., Kim, D. H., Jung, H. B., Ko, S. H., & Baek, K. (2012a). In situ field scale electrokinetic remediation of multi-metals contaminated paddy soil: influence of electrode configuration. Electrochimica Acta, 86, 89–95.CrossRefGoogle Scholar
- Kim, Y. H., Kim, D. H., Jung, H. B., Hwang, B. R., Ko, S. H., & Baek, K. (2012b). Pilot scale ex-situ electrokinetic remediation of arsenic-contaminated soil. Separation Science and Technology, 47, 2230–2234.CrossRefGoogle Scholar
- Li, G., Guo, S. H., Li, S. C., Zhang, L. Y., & Wang, S. S. (2012). Comparison of approaching and fixed anodes for avoiding the ‘focusing’ effect during electrokinetic remediation of chromium-contaminated soil. Chemical Engineering Journal, 203, 231–238.CrossRefGoogle Scholar
- Lima, A. T., Ottosen, L. M., & Ribeiro, A. B. (2012). Assessing fly ash treatment: remediation and stabilization of heavy metals. Journal of Environmental Management, 95, S110–S115.Google Scholar
- Lu, P., Feng, Q. Y., Meng, Q. J., & Yuan, T. (2012). Electrokinetic remediation of chromium- and cadmium-contaminated soil from abandoned industrial site. Separation and Purification Technology, 98, 216–220.CrossRefGoogle Scholar
- Marceau, P., Broquet, P., & Baticle, P. (1999). Electrokinetic remediation of cadmium-spiked clayey medium. Pilot test. Comptes Rendus De L Academie Des Sciences Serie Ii Fascicule a-Sciences De La Terre Et Des Planetes, 328, 37–43.Google Scholar
- Park, S. W., Lee, J. Y., Yang, J. S., Kim, K. J., & Baek, K. (2009). Electrokinetic remediation of contaminated soil with waste-lubricant oils and zinc. Journal of Hazardous Materials, 169, 1168–1172.CrossRefGoogle Scholar
- Park, S. Y., Park, G. Y., Kim, D. H., Yang, J. S., & Baek, K. (2010). Electrokinetic separation of heavy metals from wastewater treatment sludge. Separation Science and Technology, 45, 1982–1987.CrossRefGoogle Scholar
- Paz-Garcia, J. M., Baek, K., Alshawabkeh, I. D., & Alshawabkeh, A. N. (2012). A generalized model for transport of contaminants in soil by electric fields. Journal of Environmental Science and Health Part a-Toxic/Hazardous Substances & Environmental Engineering, 47, 308–318.CrossRefGoogle Scholar
- Pazos, M., Alcantara, M. T., Cameselle, C., & Sanroman, M. A. (2009). Evaluation of electrokinetic technique for industrial waste decontamination. Separation Science and Technology, 44, 2304–2321.CrossRefGoogle Scholar
- Ryu, B. G., Park, S. W., Baek, K., & Yang, J. S. (2009). Pulsed electrokinetic decontamination of agricultural lands around abandoned mines contaminated with heavy metals. Separation Science and Technology, 44, 2421–2436.CrossRefGoogle Scholar
- Ryu, B. G., Yang, J. S., Kim, D. H., & Baek, K. (2010). Pulsed electrokinetic removal of Cd and Zn from fine-grained soil. Journal of Applied Electrochemistry, 40, 1039–1047.CrossRefGoogle Scholar
- Ryu, B.-G., Park, G.-Y., Yang, J.-W., & Baek, K. (2011). Electrolyte conditioning for electrokinetic remediation of As, Cu, and Pb-contaminated soil. Separation and Purification Technology, 79, 170–176.CrossRefGoogle Scholar
- Yuan, S. H., Long, H. Y., Xie, W. J., Liao, P., & Tong, M. (2012). Electrokinetic transport of CMC-stabilized Pd/Fe nanoparticles for the remediation of PCP-contaminated soil. Geoderma, 185, 18–25.CrossRefGoogle Scholar