Water, Air, and Soil Pollution

, Volume 192, Issue 1–4, pp 141–153

Biosorption of Methylene Blue from Aqueous Solutions by Hazelnut Shells: Equilibrium, Parameters and Isotherms

Article

Abstract

This paper presents a study on the batch adsorption of a basic dye, methylene blue (MB), from aqueous solution onto ground hazelnut shell in order to explore its potential use as a low-cost adsorbent for wastewater dye removal. A contact time of 24 h was required to reach equilibrium. Batch adsorption studies were carried out by varying initial dye concentration, initial pH value (3–9), ionic strength (0.0–0.1 mol L−1), particle size (0–200 μm) and temperature (25–55°C). The extent of the MB removal increased with increasing in the solution pH, ionic strength and temperature but decreased with increase in the particle size. The equilibrium data were analysed using the Langmuir and Freundlich isotherms. The characteristic parameters for each isotherm were determined. By considering the experimental results and adsorption models applied in this study, it can be concluded that equilibrium data were represented well by Langmuir isotherm equation. The maximum adsorption capacities for MB were 2.14 × 10−4, 2.17 × 10−4, 2.20 × 10−4 and 2.31 × 10−4 mol g−1 at temperature of 25, 35, 45 and 55°C, respectively. Adsorption heat revealed that the adsorption of MB is endothermic in nature. The results indicated that the MB strongly interacts with the hazelnut shell powder.

Keywords

Biosorption Methylene blue Hazelnut shell Langmuir isotherm 

Nomenclature

qm

Monolayer capacity of the adsorbent, mol g−1

K

Adsorption constant, L mol−1

Ce

Equilibrium dye concentration in solution, mol L−1

qe

Equilibrium dye concentration on adsorbent, mol g−1

KF

Freundlich constant, mol g−1

n

Freundlich isotherm exponent

T

Temperature, K

I

Ionic strength, mol L−1

W

Mass of adsorbent, g

V

Volume of aqueous solution to be treated, L

C0

Initial dye concentration in aqueous solution, mol L−1

R2

Regression coefficient

PS

Particle size

References

  1. Aksu, Z., & Tezer, S. (2001). Equilibrium and kinetic modelling of biosorption of remazol black B by Rhizopus arrhizus in a batch system: Effect of temperature. Process Biochemistry, 36, 431–439.CrossRefGoogle Scholar
  2. Alkan, M., Çelikçapa, S., Demirbaş, Ö., & Doğan, M. (2005). Removal of reactive blue 221 and acid blue 62 anionic dyes from aqueous solutions by sepiolite. Dyes and Pigments, 65, 251–259.CrossRefGoogle Scholar
  3. Alkan, M., Demirbaş, Ö., Çelikçapa, S., & Doğan, M. (2004a). Sorption of acid red 57 from aqueous solution onto sepiolite. Journal of Hazardous Materials, B116, 135–145.CrossRefGoogle Scholar
  4. Alkan, M., Demirbaş, Ö., & Doğan, M. (2004b). Removal of acid yellow 49 from aqueous solution by adsorption. Fresenius Environmental Bulletin, 13(11a), 1112–1121.Google Scholar
  5. Alkan, M., & Doğan, M. (2003) Adsorption kinetics of Victoria blue onto perlite. Fresenius Environmental Bulletin, 12(5), 418–425.Google Scholar
  6. Allen, S. J., & Koumanova, B. (2005). Decolourisation of water/wastewater using adsorption (Review). J Univ Chem Technol Metall, 40, 175–192.Google Scholar
  7. An, H., Yi, Q., Xiasheng, G., & Tang, W. Z. (1996). Biological treatment of dye wastewaters using an anaerobiceoxic system. Chemosphere, 33, 2533–2542.CrossRefGoogle Scholar
  8. Annadurai, G. (2002). Adsorption of basic dye on strongly chelating polymer: batch kinetics studies. Iranian PolynterJournal, 11(4), 237–244.Google Scholar
  9. Annadurai, G., Juang, R. S., & Lee, D. J. (2002). Use of cellulose-based wastes for adsorption of dyes from aqueous solutions. Journal of Hazardous Materials, B92, 263–274.CrossRefGoogle Scholar
  10. Aslıhan, G., Savas, S., Sedat, B., & Ali, M. M. (2005). Adsorption and kinetic studies of cationic and anionic dyes on pyrophyllite from aqueous solutions. Journal of Colloid and Interface Science, 286, 53–60.CrossRefGoogle Scholar
  11. Banat, I. M., Nigam, P., Singh, D., & Marchant, R. (1996). Microbial decolorization of textile-dye-containing effluents: A review. Bioresource Technology, 58, 217–227.CrossRefGoogle Scholar
  12. Banerjee, S., & Dastidar, M. G. (2005). Use of jute processing wastes for treatment of wastewater contaminated with dye and other organics. Bioresource Technology, 96(17), 1919–1928.CrossRefGoogle Scholar
  13. Batzias, F. A., & Sidiras, D. K. (2004). Dye adsorption by calcium-chloride treated beech sawdust in batch and fixed-bed systems. Journal of Hazardous Materials, B114, 167–174.CrossRefGoogle Scholar
  14. Bhattacharyya, K. G., & Sharma, A. (2005). Kinetics and thermodynamics of methylene blue adsorption on Neem (Azadirachta indica) leaf powder. Dyes and Pigments, 65, 51–59.CrossRefGoogle Scholar
  15. Bulut, Y., & Aydın, H. (2006). A kinetics and thermodynamics study of methylene blue adsorption on wheat shells. Desalination, 194, 259–267.CrossRefGoogle Scholar
  16. Crini, G. (2006). Non-conventional low-cost adsorbents for dye removal: A review. Bioresource Technology, 97, 1061–1085.CrossRefGoogle Scholar
  17. Demirbaş, O., Alkan, M., & Dogan, M. (2002). The removal of Victoria blue from aqueous solution by adsorption on a low-cost material. Adsorption, 8, 341–349.CrossRefGoogle Scholar
  18. Doğan, M., & Alkan, M. (2003a). Adsorption kinetics of methyl violet onto perlite. Chemosphere, 50, 517–528.CrossRefGoogle Scholar
  19. Dogan, M., & Alkan, M. (2003b). Removal of methyl violet from aqueous solutions by perlite. Journal of Colloid and Interface Science, 267, 32–41.CrossRefGoogle Scholar
  20. Doğan, M., Alkan, M., & Onganer, Y. (2000). Adsorption of methylene blue on perlite from aqueous solutions. Water, Air and Soil Pollution, 120, 229–248.CrossRefGoogle Scholar
  21. Doğan, M., Alkan, M., Türkyılmaz, A., & Özdemir, Y. (2004). Kinetics and mechanism of removal of methylene blue by adsorption onto perlite. Journal of Hazardous Materials, B109, 141–148.CrossRefGoogle Scholar
  22. Doğan, M., Özdemir, Y., & Alkan, M. (2007). Adsorption kinetics and mechanism of cationic methyl violet and methylene blue dyes onto sepiolite. Dyes and Pigments, 75(3), 701–713.CrossRefGoogle Scholar
  23. Ferrero, F. (2007). Dye removal by low cost adsorbents: Hazelnut shells in comparison with wood sawdust. Journal of Hazardous Materials, 142, 144–152.CrossRefGoogle Scholar
  24. Feryal, A. (2005). Adsorption of basic dyes from aqueous solution onto pumice powder. Journal of Colloid and Interface Science, 286, 455–458.CrossRefGoogle Scholar
  25. Garg, V. K., Amita, M., Kumar, R., & Gupta, R. (2004). Basic dye (methylene blue) removal from simulated wastewater by adsorption using Indian Rosewood sawdust: A timber industry waste. Dyes and Pigments, 63, 243–250.CrossRefGoogle Scholar
  26. German-Heins, J., & Flury, M. (2000). Sorption of brilliant blue FCF in soils as affected by pH and ionic strength. Geoderma, 97, 87–101.CrossRefGoogle Scholar
  27. Ghoreishi, S. M., & Haghighi, R. (2003). Chemical catalytic reaction and biological oxidation for treatment of non-biodegradable textile effluent. Chemical Engineering Journal, 95, 163–169.CrossRefGoogle Scholar
  28. Ghosh, D., & Bhattacharyya, K. G. (2002). Adsorption of methylene blue on kaolinite. Applied Clay Science, 20, 295–300.CrossRefGoogle Scholar
  29. Gregory, A. R., Eliot, S., & Kluge, P. (1991). Ames testing of direct black 3B parallel carcinogenecity. Journal of Applied Toxicology, 1, 308–313.CrossRefGoogle Scholar
  30. Guo, Y., Yang, S., Fu, W., Qi, J., Li, R., Wang, Z., et al. (2003). Adsorption of malachite green on micro- and mesoporous rice husk-based active carbon. Dyes and Pigments, 56, 219–229.CrossRefGoogle Scholar
  31. Gupta, V. K., Suhas, A. I., & Saini, V. K. (2004). Removal of rhodamine B, fast green, and methylene blue from wastewater using red mud, an aluminum industry waste. Industrial and Engineering Chemistry Research, 43, 1740–1747.CrossRefGoogle Scholar
  32. Gücek, A., Şener, S., Bilgen, S., & Mazmancı, M. A. (2005). Adsorption and kinetic studies of cationic and anionic dyes on pyrophyllite from aqueous solutions. Journal of Colloid and Interface Science, 286, 53–60.CrossRefGoogle Scholar
  33. Hall, K. R., Eagleton, L. C., Acrivos, A., & Vermeulen, T. (1966). Pore and solid diffusion kinetics in fixed bed adsorption under constant conditions. Industrial & Engineering Chemistry Fundamentals, 5, 212–219.CrossRefGoogle Scholar
  34. Hamdaoui, O. (2006). Batch study of liquid-phase adsorption of methylene blue using cedar sawdust and crushed brick. Journal of Hazardous Materials, B135, 264–273.CrossRefGoogle Scholar
  35. Harris, O. P., & Ramelow, G. J. (1990). Binding of metal ions by particulate biomass derived from Chlorella vulgaris and Scenedesmus quadricauda. Environmental Science and Technology, 24(2), 220–224.CrossRefGoogle Scholar
  36. Janos, P. (2003). Sorption of basic dyes onto iron humate. Environmental Science and Technology, 37, 5792–5798.CrossRefGoogle Scholar
  37. Kapoor, A., Viraraghavan, T., & Cullimore, D. R. (1999). Removal of heavy metals using the fungus Aspergillus niger. Bioresource Technology, 70(1), 95–104.CrossRefGoogle Scholar
  38. Kavitha, D., & Namasivayam, C. (2007). Experimental and kinetic studies on methylene blue adsorption by coir pith carbon. Bioresource Technology, 98(1), 14–21.CrossRefGoogle Scholar
  39. Legrouri, K., Khouyab, E., Ezzinea, M., Hannachea, H., Denoyelc, R., Pallierd, R., et al. (2005). Production of activated carbon from a new precursor molasses by activation with sulphuric acid. Journal of Hazardous Materials, B118, 259–263.CrossRefGoogle Scholar
  40. Liakou, S., Pavlou, S., & Lyberatos, G. (1997). Ozonation of azo dyes. Water Science and Technology, 35, 279–286.CrossRefGoogle Scholar
  41. Lorenc-Grabowska, E., & Gryglewicz, G. (2007). Adsorption characteristics of Congo Red on coal-based mesoporous activated carbon. Dyes and Pigments, 74, 34–40.CrossRefGoogle Scholar
  42. Maurya, N. S., Mittal, A. K., Cornel, P., & Rother, E. (2006). Biosorption of dyes using dead macro fungi: Effect of dye structure, ionic strength and pH. Bioresource Technology, 97, 512–521.CrossRefGoogle Scholar
  43. McKay, G., Otterburn, M. S., & Aga, D. A. (1985). Fullers earth and fired clay as adsorbent for dye stuffs, equilibrium and rate constants. Water, Air, and Soil Pollution, 24, 307–322.CrossRefGoogle Scholar
  44. McKay, G., Otterburn, M. S., & Sweeney, A. G. (1980). Water Research, 14, 21–27.CrossRefGoogle Scholar
  45. McMullan, G., Meehan, C., Conneely, A., Kirby, N., Robinson, T., Nigam, P., et al. (2001). Microbial decolourisation and degradation of textile dyes. Applied Microbiology and Biotechnology, 56, 81–87.CrossRefGoogle Scholar
  46. Mittal, A. (2006). Adsorption kinetics of removal of a toxic dye, Malachite Green, from wastewater by using hen feathers. Journal of Hazardous Materials, B33, 196–202.CrossRefGoogle Scholar
  47. Namasivayam, C., Kumar, M. D., & Begum, R. A. (2001). ‘Waste’ coir pith—a potential biomass for the treatment of dyeing wastewaters. Biomater. Bioenerg., 21, 477–483.CrossRefGoogle Scholar
  48. Narine, D. R., & Guy, R. D. (1981). Interactions of some large organic cations with bentonite in dilute aqueous systems. Clays Clay Miner, 29, 205–212.CrossRefGoogle Scholar
  49. Nassem, R., & Tahir, S. (2001). Removal of Pb(II) from aqueous/acidic solutions by using bentonite as an adsorbent. Water Research, 35, 3982–3986.CrossRefGoogle Scholar
  50. Ozacar, M., & Sengil, I. A. (2005). Adsorption of metal complex dyes from aqueous solutions by pine sawdust. Bioresource Technology, 96, 791–795.CrossRefGoogle Scholar
  51. Özdemir, Y., Doğan, M., & Alkan, M. (2006). Adsorption of cationic dyes from aqueous solutions by sepiolite. Microporous and Mesoporous Materials, 96(1–3), 419–427.CrossRefGoogle Scholar
  52. Pavel, J., Pavel, S., Milena, R., & Sylvie, G. (2005). Sorption of basic and acid dyes from aqueous solutions onto oxihumolite. Chemosphere, 59, 881–886.CrossRefGoogle Scholar
  53. Pearce, C. I., Lloyd, J. R., & Guthrie, J. T. (2003). The removal of colour from textile wastewater using whole bacterial cells: A review. Dyes and Pigments, 58, 179–196.CrossRefGoogle Scholar
  54. Ravi Kumar, M. N. V., Sridhari, T. R., Bhavani, K. D., & Dutta, P. K. (1998). Trends in color removal from textile mill effluents. Colorage, 40, 25–34.Google Scholar
  55. Renmin, G., Yingzhi, S., Jian, C., Huijun, L., & Chao, Y. (2005). Effect of chemical modification on dye adsorption capacity of peanut hull. Dyes and Pigments, 67, 175–181.CrossRefGoogle Scholar
  56. Robinson, T., McMullan, G., Marchant, R., & Nigam, P. (2001). Remediation of dyes in textile effluent: A critical review on current treatment technologies with a proposed alternative. Bioresource Technology, 77, 247–255.CrossRefGoogle Scholar
  57. Sampa, C., & Binay, K. D. (2005). On the adsorption and diffusion of methylene blue in glass fibers. Journal of Colloid and Interface Science, 286, 807–811.CrossRefGoogle Scholar
  58. Sanghi, R., & Bhattacharya, B. (2002). Review on decolorisation of aqueous dye solutions by low cost adsorbents. Coloration Technology, 118, 256–269.CrossRefGoogle Scholar
  59. Sarasa, J., Roche, M. P., Ormad, M. P., Gimeno, E., Puig, A., & Ovelleiro, J. L. (1998). Treatment of a wastewater resulting from dyes manufacturing with ozone and chemical coagulation. Water Research, 32, 2721–2727.CrossRefGoogle Scholar
  60. Schiewer, S., & Volesky, B. (1995). Modelling of proton–metal ion exchange in biosorption. Environmental Science and Technology, 29(12), 3049–3058.CrossRefGoogle Scholar
  61. Shaobin, W., Zhua, Z. H., Anthony, C., Haghseresht, F., & Luc, G. Q. (2005). The physical and surface chemical characteristics of activated carbons and the adsorption of methylene blue from wastewater. Journal of Colloid and Interface Science, 284, 440–446.CrossRefGoogle Scholar
  62. Singh, K. P., Mohan, D., Sinha, S., Tondon, G. S., & Gosh, D. (2003). Color removal from wastewater using low-cost activated carbon derived from agricultural waste material. Industrial and Engineering Chemistry Research, 42, 1965–1976.CrossRefGoogle Scholar
  63. Singh, D. K., & Srivastava, B. (1999). Removal of basic dyes from aqueous solutions by chemically treated Psidium Guyava leaves. Indian Journal of Environmental Health, 41, 333–345.Google Scholar
  64. Summers, R. S., & Roberts, P. V. (1988). GAC adsorption of humic substances II. Size exclusion and electrostatic interactions. Journal of Colloid and Interface Science, 122, 382–397.CrossRefGoogle Scholar
  65. Sun, Q., & Yang, L. (2003). The adsorption of basic dyes from aqueous solution on modified peat-resin particle. Water Research, 37, 1535–1544.CrossRefGoogle Scholar
  66. Tokiwa, F. (1983). Surfactants pp. 17–25. Tokyo, Japan: Kao Co.Google Scholar
  67. Tsai, W. T., Yang, J. M., Lai, C. W., Cheng, Y. H., Lin, C. C., & Yeh, C. W. (2006). Characterization and adsorption properties of eggshells and eggshell membrane. Bioresource Technology, 97(3), 488–493.CrossRefGoogle Scholar
  68. Vadivelan, V., & Vasanth Kumar, K. (2005). Equilibrium, kinetics, mechanism, and process design for the sorption of methylene blue onto rice husk. Journal of Colloid and Interface Science, 286, 90–100.CrossRefGoogle Scholar
  69. Wang, S., Boyjoo, Y., & Choueib, A. (2005). A comparative study of dye removal using fly ash treated by different methods. Chemosphere, 60(10), 1401–1407.CrossRefGoogle Scholar
  70. Weng, C.-H., & Pan, Y.-F. (2006). Adsorption characteristics of methylene blue from aqueous solution by sludge ash. Colloids and Surfaces A: Physicochem. Eng. Aspects, 274, 154–162.CrossRefGoogle Scholar
  71. Wu, F. C., Tseng, R.-L., & Hu, C.-C. (2005). Comparisons of pore properties and adsorption performance of KOH-activated and steam-activated carbons. Microporous and Mesoporous Materials, 80, 95–106.CrossRefGoogle Scholar
  72. You, L., Wu, Z., Kim, T., & Lee, K. (2006). Kinetics and thermodynamics of bromophenol blue adsorption by a mesoporous hybrid gel derived from tetraethoxysilane and bis(trimethoxysilyl)hexane. Journal of Colloid and Interface Science, 300, 526–535.CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2008

Authors and Affiliations

  1. 1.Faculty of Science and Literature, Department of ChemistryBalikesir UniversityBalikesirTurkey

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